Grain Boundary Engineering and Alterations in Anisotropy of Interfacial Properties

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Abstract:

Literature data on grain boundary properties show surprisingly in some cases reversed courses of the structural dependences than expected, or directly prove their qualitative changes with changing temperature. This “reversed anisotropy” is demonstrated for example of grain boundary segregation. It is shown that this reversed anisotropy of grain boundary properties can be explained by the enthalpy–entropy compensation effect. Serious consequences of altered structural dependence of grain boundary properties for Grain Boundary Engineering are discussed.

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Materials Science Forum (Volumes 654-656)

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2350-2353

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June 2010

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© 2010 Trans Tech Publications Ltd. All Rights Reserved

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