Hydrothermal Synthesis and Characterization of (Na0.8K0.2)0.5Bi0.5TiO3 Perovskite-Type Oxides with Cubic Morghology

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The (Na0.8K0.2)0.5Bi0.5TiO3 perovskite-type solid solution was prepared under mild condition at 160°C using Ti(OC4H9)4, Bi(NO3)3•5H2O as Bi and Ti sources by a mechanical hydrothermal method. It is suggested that mineralizer plays an important role in facilitating the crystallization of obtained products and promoting the formation of perovskite phase. The crystallized products were characterized by means of XRD, SEM and DSC-TG. The results show that the well-developed crystallite with a pure pervoskite structure has been formed. The powders with regular cubic morphology exhibit low agglomeration and narrow particles size distribution in the range of 3~6μm.

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283-286

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June 2011

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© 2011 Trans Tech Publications Ltd. All Rights Reserved

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[1] G.A. Smolenskii, V.A. Isupov and A.I. Agranovskaya: J. Sov. Phys. Sol. Stat. Vol. 2 (1961), p.2651.

Google Scholar

[2] T. Takanaka, K.I. Maruyama and K. Sakata: Jpn. J. Appl. Phys. Vol. 30 (1991) , p.2236.

Google Scholar

[3] J. Suvhanicz: Ferroelectrics Vol. 172 (1995) , p.455.

Google Scholar

[4] A. Herabut, A. Safari: J. Am. Ceram. Soc. Vol. 80 (1997) , p.2954.

Google Scholar

[5] A. Sasaki, T. Chiba and Y. Mamiya: Jpn. J. Appl. Phys. Vol. 38 (1999) , p.5564.

Google Scholar

[6] T.B. Wang, L.E. Wang and Y.K. Lu: J. Chin. Ceram. Soc. Vol. 14 (1986) , p.14.

Google Scholar

[7] Z.G. Zhao, H.M. Cheng and J.M. Ma: Chem. J. Chin. U. Vol. 15 (1994) , p.1063.

Google Scholar

[8] C.Y. Kim, T. Sekino and K. Niihara: J. Am. Ceram. Soc. Vol. 86 (2003) , p.1464.

Google Scholar

[9] S.B. Cho, M. Oledzka and R.E. Riman: J. Cryst. Growth. Vol. 226 (2001) , p.313.

Google Scholar

[10] W.J. Dawson: Ceram. Bull. Vol. 67 (1988) , p.1673.

Google Scholar

[11] M.M. Lencka, M. Oledzka and R.E. Riman: Chem. Mater. Vol. 12 (2000) , p.1323.

Google Scholar

[12] X.Z. Jing, Y.X. Li and Q.R. Yin: Mater. Sci. Eng. B. Vol. 99 (2003) , p.506.

Google Scholar

[13] T. Lopez, E. Sanchez and P. Bosch: Mater. Chem. Phys. Vol. 32 (1992) p.141.

Google Scholar