Paper Titles

Structural and Optical Properties of Zn_1-XCr_XO Thin Films Deposited by Magnetron Sputtering
p.750

Structure and Magnetic Properties of CoFe₂O₄ Nanocrystal Thin Films Prepared by Sol-Gel Method
p.756

Study on Tribological Performance of the TiNi Modified Layer on the Surface of the Ti6Al4V Alloy
p.759

Synthesis of Porous TiO₂ Thin Films via Sol-Gel Method and their Phototocatalyst Performances
p.765

The Microstructure, Resistivity and Infrared Emissivity of ITO Film with O/Ar Ratio Variation in Al₂O₃ Buffer Layer
p.771

Transparency of Hybrid Films Based on (γ-Methacrylpropyl)- Trimethoxysilane and its Validation by Computing Energy-Band Structure
p.778

Tribological Properties of Hydrogenated Amorphous Carbon (a-C:H) Films on Aluminium Alloy Substrate under Different Substrate Bias Voltages
p.784

VO₂ Films by Polymer-Assisted Deposition: Investigation of Thermal Decomposition of Precursor Gel and Control of Phase Transition Temperatures
p.791

Gas Sensing Properties of ZnO Thin Film/Si Heterojunction to Alcohols
p.798

HomeMaterials Science ForumMaterials Science Forum Vol. 687VO2 Films by Polymer-Assisted Deposition:...

VO₂ Films by Polymer-Assisted Deposition: Investigation of Thermal Decomposition of Precursor Gel and Control of Phase Transition Temperatures

Article Preview

Abstract:

Polymer-assisted deposition (PAD) can be employed to prepare metal oxide films by coordination between metal ions and polymers instead of hydrolysis and condensation reactions, providing a cheap and scalable alternative for sol-gel process. This work involves a TG/DTA-MS study on the thermal decomposition of the precursor gel to form VO2 films. The results show that polymers influence effectively the achievement of thermochromic VO2, supporting the film-forming mechanism we proposed in a previous work. W-doping shifted the MIT temperature from 58 to 33 °C while remained 73% of the modulating ability in infrared transmittance at 2000 nm.

You might also be interested in these eBooks

Functional and Electronic Materials, IUMRS-ICA2010

Info:

Periodical:

Materials Science Forum (Volume 687)

Pages:

791-797

DOI:

https://doi.org/10.4028/www.scientific.net/MSF.687.791

Citation:

Cite this paper

Online since:

June 2011

Authors:

Li Tao Kang, Yan Feng Gao, Hong Jie Luo

Keywords:

Smart Windows, Thermal Decomposition, Thermochromic Properties, Vanadium Dioxide, W Doping

Export:

RIS, BibTeX

Price:

Permissions CCC:

Request Permissions

Permissions PLS:

Request Permissions

Сopyright:

© 2011 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

[1] F.J. Morin: Phys. Rev. Lett. Vol. 3 (1959), p.34.

[2] F.C. Case: J. Vac. Sci. Technol. A Vol. 2 (1984), p.1509.

[3] M. Gurvitch, S. Luryi, A. Polyakov, A. Shabalov, M. Dudley, G. Wang, S. Ge, V. Yakovlev: J. Appl. Phys. Vol. 102 (2007), p.033504.

DOI: 10.1063/1.2764245

[4] S.H. Chen, H. Ma, J. Dai, X.J. Yi: Appl. Phys. Lett. Vol. 90 (2007), p.101117.

[5] M. -H. Lee, J. -S. Cho: Thin Solid Films Vol. 365 (2000), p.5.

[6] J. Narayan, V.M. Bhosle: J. Appl. Phys. Vol. 100 (2006), p.103524.

[7] Y.L. Wang, X.K. Chen, M.C. Li, R. Wang, G. Wu, J.P. Yang, W.H. Han, S.Z. Cao, L.C. Zhao: Surf. Coat. Tech. Vol. 201 (2007), p.5344.

[8] R. Lopez, L.A. Boatner, T.E. Haynes, R.F. Haglund, L.C. Feldman: Appl. Phys. Lett. Vol. 79 (2001), p.3161.

[9] L.A. Gea, J.D. Budai, L.A. Boatner: J. Mater. Res. Vol. 14 (1999), p.2602.

[10] B.G. Chae, H.T. Kim, S.J. Yun, B.J. Kim, Y.W. Lee, D.H. Youn, K.Y. Kang: Electrochem. Solid St. Vol. 9 (2006), p. C12.

[11] N.Y. Yuan, J.H. Li, C.L. Lin: Appl. Surf. Sci. Vol. 191 (2002), p.176.

[12] H.K. Chen, H.C. Hung, T.C.K. Yang, S.F. Wang: J. Non-Cryst. Solids Vol. 347 (2004), p.138.

[13] H. Kozuka, T. Kishimoto: Chem. Lett. Vol. 11 (2001), p.1150.

[14] T. Kishimoto, H. Kozuka: J. Mater. Res. Vol. 18 (2003), p.466.

[15] S.S. Kalagi, D.S. Dalavi, R.C. Pawar, N.L. Tarwal, S.S. Mali, P.S. Patil: J. Alloy. Compd. Vol. 493 (2010), p.335.

[16] H.M. Luo, M. Jain, T.M. McCleskey, E. Bauer, A.K. Burrell, Q.X. Jia: Adv. Mater. Vol. 19 (2007), p.3604.

[17] Y. Lin, H. Wang, M.E. Hawley, S.R. Foltyn, Q.X. Jia, G.E. Collis, A.K. Burrell, T.M. McCleskey: Appl. Phys. Lett. Vol. 85 (2004), p.3426.

DOI: 10.1063/1.1806265

[18] H.M. Luo, Y. Lin, H.Y. Wang, S.A. Baily, J.H. Lee, M.E. Hawley, T.M. McCleskey, A.K. Burrell, E. Bauer, L. Civale, Q.X. Jia: Angew. Chem. -Int. Edit. Vol. 47 (2008), p.5768.

DOI: 10.1002/anie.200801064

[19] H.M. Luo, H.Y. Wang, Z.X. Bi, G.F. Zou, T.M. McCleskey, A.K. Burrell, E. Bauer, M.E. Hawley, Y.Q. Wang, Q.X. Jia: Angew. Chem. -Int. Edit. Vol. 48 (2009), p.1490.

DOI: 10.1002/anie.200805394

[20] A.K. Burrell, T.M. McCleskey, Q.X. Jia: Chem. Commun. Vol. 11 (2008), p.1271.

[21] L.T. Kang, Y.F. Gao, H.J. Luo: ACS Appl. Mater. & Interfaces Vol. 1 (2009), p.2211.

[22] L.T. Kang, Y.F. Gao, Z.T. Zhang, J. Du, C.X. Cao, Z. Chen, H.J. Luo: J. Phys. Chem. C Vol. 114 (2010), p. (1901).

[23] J.Q. Shi, S.X. Zhou, B. You, L.M. Wu: Sol. Energy Mater. Sol. Cells Vol. 91 (2007). p.1856.

[24] Q.X. Jia, T.M. McCleskey, A.K. Burrell, Y. Lin, G.E. Collis, H. Wang, A.D.Q. Li, S.R. Foltyn: Nature Mater. Vol. 3 (2004), p.529.

[25] Z.T. Zhang, Y.F. Gao, Z. Chen, J. Du, C.X. Cao, L.T. Kang, H.J. Luo: Langmuir Vol. 26 (2010), p.10738.

[26] R. Binions, G. Hyett, C. Piccirillo, I.P. Parkin: J. Mater. Chem. Vol. 17 (2007), p.4652.

[27] E.U. Donev, R. Lopez, L.C. Feldmant, R.F. Haglund: Nano Lett. Vol. 9 (2009), p.702.

[28] L.Q. Mai, B. Hu, T. Hu, W. Chen, E.D. Gu: J. Phys. Chem. B Vol. 110 (2006), p.19083.