Alternative Feedstocks for Biodiesel Production

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The increasing in the world population has continuously increased the energy demand. As an effective fuel, petroleum has been serving the world to meet its energy needs. Continued use of petroleum sourced fuels is widely recognized as unsustainable because of depleting supplies and all the environmental issues around its use could be responsible for a major deficit in the future. Thus, the development of alternative energy sources, are to be welcomed. Biodiesel, as an alternative fuel, has many benefits. It is biodegradable, non-toxic and compared to petroleum-based diesel, has a more favorable combustion emission profile, such as low emissions of carbon monoxide, particulate matter and unburned hydrocarbons. In brief, these merits make biodiesel a good alternative to petroleum based fuel. The use of alternative feedstock as waste cooking oils (WCO), bovine fats and microalgae oil for biodiesel production has some advantages. It is cheaper than edible vegetable oils and it is a way to valorize a sub-product. Nevertheless, these oils has some contaminants, which can reduce the quality of biodiesel, a problem that was solved by testing different operating conditions and equipment designs for each stage of processing. The technological assessment of this process was carried out to evaluate their technical benefits, limitations and quality of final product. In this work biodiesel was produced by an alkali-catalyzed transesterification, a reaction involving the WCO feedstock and an alcohol to yield fatty acid alkyl esters (biodiesel) and glycerol. The evaluation of quality from raw materials and final biodiesel was performed according to standard EN 14214. Results show that all parameters analyzed meet the standard and legislation requirements. This evidence proves that in those operating conditions the biodiesel produced from WCO, bovine fats and microalgae can substitute petroleum-based diesel.

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Materials Science Forum (Volumes 730-732)

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623-629

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November 2012

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© 2013 Trans Tech Publications Ltd. All Rights Reserved

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[1] I.M. Atadashi, M.K. Aroua, A. A. Aziz, High quality biodiesel and its diesel engine application: A review, Renewable and Sustainable Energy Reviews 14 (2010) 1999–2008.

DOI: 10.1016/j.rser.2010.03.020

Google Scholar

[2] N. Chand, Plant oils—Fuel of the future, J. Sci. Ind. Res. 61(2002) 7–16.

Google Scholar

[3] M. Balat, Current alternative engine fuels. Energy Sources 27 (2005) 569–77.

Google Scholar

[4] K. Gunvachai, M.G. Hassan, G. Shama, C. Hellgardt, A new solubility model to describe biodiesel formation kinetics, I.Chem.E. 85(B5) (2007) 383–389.

DOI: 10.1205/psep07033

Google Scholar

[5] D. Puppan. Environmental evaluation of biofuels, Periodica Polytechnica Series Social and Management Sciences 10 (2002) 95–116.

Google Scholar

[6] J.V. Gerpen, Biodiesel processing and production, Fuel Processing Technology 86 (2005) 1097–107.

DOI: 10.1016/j.fuproc.2004.11.005

Google Scholar

[7] L.C. Meher, D.V. Sagar, S.N. Naik, Technical aspects of biodiesel production by transesterification—a review, Renewable and Sustainable Energy Reviews 10 (2006) 248–268.

DOI: 10.1016/j.rser.2004.09.002

Google Scholar

[8] A. Banerjee, R. Chakraborty, Parametric sensitivity in transesterification of waste cooking oil for biodiesel production—A review, Resources, Conservation and Recycling 53 (2009) 490–497.

DOI: 10.1016/j.resconrec.2009.04.003

Google Scholar

[9] C.C. Enweremadu, M.M. Mbarawa, Technical aspects of production and analysis of biodiesel from used cooking oil—A review, Renewable and Sustainable Energy Reviews 13 (2009) 2205–2224.

DOI: 10.1016/j.rser.2009.06.007

Google Scholar

[10] M. Zabeti, W.M. Daud, M.K. Aroua, Activity of solid catalysts for biodiesel production: A review, Fuel Processing Technology 90 (2009) 770–777.

DOI: 10.1016/j.fuproc.2009.03.010

Google Scholar

[11] A. Amin, Review on biofuels oil and gas production process from microalgae, Energy Conversion and Management 50 (2009) 1834-1840.

DOI: 10.1016/j.enconman.2009.03.001

Google Scholar

[12] Patil PD, Deng S. Optimization of biodiesel production from edible and nonedible vegetable oils. Fuel 2009;88:1302–6.

DOI: 10.1016/j.fuel.2009.01.016

Google Scholar

[13] J. Janaun, N. Ellis, Perspectives on biodiesel as a sustainable fuel, Renewable and Sustainable Energy Reviews 14 (2010) 1312–1320.

DOI: 10.1016/j.rser.2009.12.011

Google Scholar

[14] D.Y.C. Leung, X. Wu, M.K.H. Leung, A review on biodiesel production using catalyzed transesterification, Applied Energy 87 (2010) 1083–1095.

DOI: 10.1016/j.apenergy.2009.10.006

Google Scholar

[15] J. Kansedo, K.T. Lee, S. Bhatia, Cerbera odollam (sea mango) oil as a promising non-edible feedstock for biodiesel production, Fuel 88 (2009) 1148–50.

DOI: 10.1016/j.fuel.2008.12.004

Google Scholar

[16] FAO, The State of Food and Agriculture, Biofuels: prospects, risks and opportunities. Rome: Food and Agriculture Organization of the United Nations (2008).

DOI: 10.18356/75039ff9-en

Google Scholar

[17] L. Brennan, P. Owende, Biofuels from microalgae—A review of technologies for production, processing, and extractions of biofuels and co-products, Renewable and Sustainable Energy Reviews (2009).

DOI: 10.1016/j.rser.2009.10.009

Google Scholar

[18] T.M. Mata, A.A. Martins, N.S. Caetano, Microalgae for biodiesel production and other applications: A Review, Renewable and Sustainable Energy Reviews 14 (2010) 217-232.

DOI: 10.1016/j.rser.2009.07.020

Google Scholar

[19] F. Pedro, J.N. Correia, R. Idalina, M. João, R. Berkemeier, J.M. Bordado, Production of biodiesel from waste frying oils, Waste Management 26 (2006) 487–94.

DOI: 10.1016/j.wasman.2005.02.025

Google Scholar

[20] F.F.P. Santos, J.Q. Malveira, M.G.A. Cruz, F.A.N. Fernandes, Production of biodiesel byultrasound assisted esterification of Oreochromis niloticus oil, Fuel 2009.

DOI: 10.1016/j.fuel.2009.05.030

Google Scholar

[21] J.W. Goodrum, D.P. Geller, T.T. Adams. Rheological characterization of animal fats and their mixtures with 2 fuel oil, Biomass Bioenergy 24 (2003) 249–56.

DOI: 10.1016/s0961-9534(02)00136-8

Google Scholar

[22] L.S.G. Teixeira, J.C.R. Assis, D.R. Mendonça, I.T.V. Santos, P.R.B. Guimarães, L.A.M. Pontes, J.S.R. Teixeira, Comparison between conventional and ultrasonic preparation of beef tallow biodiesel, Fuel Processing Technology 90 (2009) 1164–1166.

DOI: 10.1016/j.fuproc.2009.05.008

Google Scholar

[23] S. Saraf, B. Thomas, Influence of feedstock and process chemistry on biodiesel quality, Process Saf. Environ. Prot. 85 (2007) 360–4.

DOI: 10.1205/psep07025

Google Scholar

[24] H. N. Bhatti, M.A. Hanif, M. Qasim, A. Rehman, Biodiesel production from waste tallow, Fuel 87 (2008) 2961–2966.

DOI: 10.1016/j.fuel.2008.04.016

Google Scholar

[25] A. Demirbas, Biodiesel fuels from vegetable oils via catalytic and non-catalytic supercritical alcohol transesterifications and other methods: a survey, Energy Convers. Manage 44 (2003) 093–109.

DOI: 10.1016/s0140-6701(03)92567-7

Google Scholar