Removal of Cationic Dyes by Polyphenylene Sulfide-Based Strong Acid Ion Exchange Fiber

Abstract:

PPS-based strong acid ion exchange fiber was used to absorb cationic dye basic fuchsin and methyl blue in solution. The experimental results showed that the amount of methylene blue and basic fuchsin absorbed increased respectively with increasing of initial concentration from 100 to 600 mg/L. The adsorption capacity of the fiber was up to 604.81mg/g of basic fuchsin and to 618.94mg/g of methylene blue. The removal rate of the methylene blue reached 99.9% from 100 to 500mg/L, but of basic fuchsin from 100 to 300mg/L. Adsorption kinetic equation for basic fuchsin can be expressed as a pseudo-second-order dynamic process. The fiber is to be perfect prospect for the wastewater treatment because of its high adsorptive capacity and diffusion rate.

• Periodical: Materials Science Forum (Volumes 743-744)
• Pages: 567-572
• DOI: https://doi.org/10.4028/www.scientific.net/MSF.743-744.567
• Online since: January 2013
• Authors: Dong Ju Zhou, Xian Rui Li, Hui Ni, Si Guo Yuan
• Keywords: Adsorption, Cationic Dye, Ion Exchange Fiber, Polyphenylene Sulfide

References

[1] S.B. Wang, Z.H. Zhu. Effects of acidic treatment of activated carbons on dye adsorption, Dyes and Pigments, (2007), 75: 306-314.

DOI: 10.1016/j.dyepig.2006.06.005

[2] Hui Yun Zhou, Dong Ju Zhou, Chen Jie Fan, et al. Chitosan Cellulose Acetate Microspheres Preparation for Enhancement of Water-soluble Dye Adsorption, Advanced Materials Research, 239-242 (2011): 2855-2858.

DOI: 10.4028/www.scientific.net/amr.239-242.2855

[3] Antonio R. Cestari, Eunice F.S. Vieira, Jackeline A. Mota. The removal of an anionic red dye from aqueous solutions using chitosan beads—The role of experimental factors on adsorption using a full factorial udesign, Journal of Hazardous Materials, 160(2008).

DOI: 10.1016/j.jhazmat.2008.03.004

[4] MansoorAnbia, Samira Salehi. Removal of acid dyes from aqueous media by adsorption onto amino-functionalized nanoporous silica SBA-3[J]Dyes and Pigments, 94(2012): 1-9.

DOI: 10.1016/j.dyepig.2011.10.016

[5] EmnaErrais, Joelle Duplay, FadilaDarragi, et al. Efficient anionic dye adsorption on natural untreated clay: Kinetic study and thermodynamic parameters, Desalination, 275(2011): 74-81.

DOI: 10.1016/j.desal.2011.02.031

[6] MohamadAmranMohdSalleh, Dalia Khalid Mahmoud, Wan Azlina Wan Abdul Karim, et al. Cationic and anionic dye adsorption by agricultural solid wastes: A comprehensive review, Desalination, 280(2011): 1-13.

DOI: 10.1016/j.desal.2011.07.019

[7] M.C. Somasekhara Reddy, L. Sivaramakrishna, A. Varada Reddy. The use of an agricultural waste material, Jujuba seeds for the removal of anionic dye (Congo red) from aqueous medium [J] Journal of Hazardous Materials, 203–204(2012): 118-127.

DOI: 10.1016/j.jhazmat.2011.11.083

[8] Monika Wawrzkiewicz, ZbigniewHubicki. Equilibrium and kinetic studies on the adsorption of acidic dye by the gel anion exchanger, Journal of Hazardous Materials, 172(2009): 868-874.

DOI: 10.1016/j.jhazmat.2009.07.069

[9] Monika Wawrzkiewicz. Comparison of gel anion exchangers of various basicity in direct dye removal from aqueous solutions and wastewaters, Chemical Engineering Journal, 173(2011): 773-781.

DOI: 10.1016/j.cej.2011.08.048

[10] Magdalena Greluk, ZbigniewHubicki. Sorption of SPADNS azo dye on polystyrene anion exchangers: Equilibrium and kinetic studies, Journal of Hazardous Materials, 172(2009): 289-297.

DOI: 10.1016/j.jhazmat.2009.07.007

[11] Monika Wawrzkiewicz, ZbigniewHubicki. Equilibrium and kinetic studies on the sorption of acidic dye by macroporous anion exchanger, Chemical Engineering Journal, 157(2010): 29-34.

DOI: 10.1016/j.cej.2009.10.041

[12] Feng CG, LI X, Zeng QX, et al. Adsorption properties of anion ion-exchange fiber for reactive dyes, Journal of Functional Materials, 36(2005): 1568-1571.

[13] Soldatov VS, Shunkevich AA, Sergeev GI. Synthesis, structure and properties of new fibrous ion exchangers, Reactive Polymers, Ion Exchangers, Sorbents, 7(1988): 159-172.

DOI: 10.1016/0167-6989(88)90136-5

[14] Hirotoku Y，Hironori N，Takayuki Y. Polyphenylene sulfide monofilament and woven fabric for industrial use [P]. Japanese Patent，08-219868. 1998-03-03.

[15] JiajiaHuang, XinZhang, LinglingBai, et al. Polyphenylene sulfide based anion exchange fiber: systhesis, characterization and adsorption ofCr(Ⅵ), Journal of Environmental Sciences, 24(2012): 1433-1438.

DOI: 10.1016/s1001-0742(11)60948-0

[16] XianruiLi, JiajiaHuang, SiguoYuan. Preparation of polyphenylenesulfide strong acid ion exchange fiberand the adsorption properties for Cr(Ⅲ)[J]PolymerMaterials Science and Engineering, 28(2012): 145-149.

[17] D.R. Lide, CRC Handbool of Chemistry and Physics, 76th ed., CRC Press, Boca Raton, (1995).