Preparation of Corrosion-Resistant Ti/RuO2 Composite Powders

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Abstract:

Ruthenium oxide coated titanium composite powders were prepared by precipitation of ruthenium salt to improve the resistance of titanium to corrosion. The composite powders were characterized by TEM and XPS. The results show that the ruthenium oxide is evenly deposited on the Ti powders. Corrosion test for the composite powders and Ti powders was conducted in 65% sulfuric acid (mass fraction). The composite powders exhibit good corrosion resistance. The corrosion rate decreased from 98.5% to 0.48% through modification. Ru/Ti molar ratio and annealing temperature have a major impact on the corrosion resistance.

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Materials Science Forum (Volumes 743-744)

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584-588

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January 2013

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© 2013 Trans Tech Publications Ltd. All Rights Reserved

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[1] C. Comninellis, C. Pulgarin, Electrochemical oxidation of phenol for wastewater treatment using SnO2 anodes, J. Appl. Electrochemistry. 23(2) (1993). 108-112.

DOI: 10.1007/bf00246946

Google Scholar

[2] G.H. Zhao, C. Xiao, M.C. Liu, et a1., Electrochemical degradation of refractory pollutant using a novel microstructured TiO2 nanotubes/Sb-doped SnO2 Electrode. Environ Sci. Technol. 43(5) (2009) 1480-1486.

DOI: 10.1021/es802155p

Google Scholar

[3] X. Cui, Research on the DSA electrode which suitable to the waste water treatment, Northern Environment. 23(5) (2011) 58-59.

Google Scholar

[4] Q. Lu, L.C. An, Q. Zhong, et al., Ru-Pd/Sn-Sb/Ti electrode properties characterization and its application in waste water treatment, Journal of Nanjing University of Technology. 34(5) (2010) 696-701 (in Chinese).

Google Scholar

[5] X.M. Wang, F.P. Hu, J.W. Luo, et al., Research on the high catalytic electrode in catalytic oxidation echnology, Journal of Zhongyuan University of Technology. 20(1) (2009) 15-18.

Google Scholar

[6] S. Raghu, C.A. Basha, Electrochemical treatment of procion black 5B using cylindrical flow reactor-a pilot plant study, J. Hazard. Mater. 139(2) (2007) 38l-390.

DOI: 10.1016/j.jhazmat.2006.06.082

Google Scholar

[7] Y. Yavuz, A.S. Koparal, Electrochemical oxidation of phenol in a parallel plate reactor using ruthenium mixed metal oxide electrode, J. Hazard. Mater. 136(2) (2006) 296-302.

DOI: 10.1016/j.jhazmat.2005.12.018

Google Scholar

[8] H.Z. Ma, B. Wang, Electrochemical pilot-scale plant for oil field produced wastewater by M/C/Fe electrodes for injection, J. Hazard. Mater. 132(2-3) (2006) 237-243.

DOI: 10.1016/j.jhazmat.2005.09.043

Google Scholar

[9] J. O'M. Bock, J. Kim, Effect of contact resistance between particles on the current distribution in a packed bed electrode, J. Appl. Electrochemistry. 27(8) (1997) 890-901.

Google Scholar

[10] Y. Xiong, C. He, H.T. Karlsson, et al., Performance of three-phase three-dimensional electrode reactor for the reduction of COD in simulated wastewater containing phenol, Chemosphere 50(1) (2003) 131-136.

DOI: 10.1016/s0045-6535(02)00609-4

Google Scholar

[11] G.L. Yu, Y.F. Zhong, Research on phenolic wastewater treatment with three-dimensional electrode, Chemical engineering and equipment. 12 (2009) 168-170 (in Chinese).

Google Scholar

[12] Z.M. Liu, F.P. Hu, J. Li, Research on the oxidation activity bright-red X-3B catalyzed by three-dimensional particle electrode, Environmental Science and Technology. 33(1) (2010) 31-34.

Google Scholar

[13] Y.H. Xin, G. Wei, Y.P. Wei, Preparation of composite oxide particle electrode, Journal of Beijing University of Chemical Technology(Natural Science) 37(2) (2010) 54-58 (in Chinese).

Google Scholar

[14] T.R. Jow, J.P. Zheng, Electrochemical capacitors using hydrous ruthenium oxide and hydrogen inserted ruthenium oxide, J Electrochem Soc 145(1) (1998) 49-52.

DOI: 10.1149/1.1838209

Google Scholar

[15] X.N. Fan, Determination of Ti in flotation tailing with dantipyrylmethane monohydrate, China Molybdenum Industry. 19(6) (1995) 54-55 (in Chinese).

Google Scholar

[16] P.F. Campbell, M.H. Ortner, C.J. Anderson, Differential thermal analysis and thermogravimetric analysis of fission product oxides and nitrates to 1500°C, Anal. Chem. 33(1) (1961) 58–61.

DOI: 10.1021/ac60169a016

Google Scholar