Study on the Adsorption Behavior of Acid Dyes on Collagen Fiber

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Abstract:

The adsorption of acid black dye NT on collagen fiber (CF) was studied, and the effects of temperature, pH, initial dye concentration, adsorbent dosage and reaction time on the dye adsorption were tested, respectively. The results indicated that the optimal temperature and pH of acid black dye NT absorption were 40°C and 2.0, respectively. For a certain concentration of dyeing, the adsorption capacity decreased with the increasing of adsorbent dosage, but increased along with the extension of the contact time. In addition, the adsorption isotherms and kinetics of acid black dye NT on CF were investigated. By comparison, it was found that the Freundlich equation and Pseudosecond-order kinetic model can better describe the adsorption behavior of acidic black dye on CF. Thermodynamic parameters, such as G, H and S were determined to be-3.445 kJ/mol, 11.2 kJ/mol and 59.6 J/(mol·K), respectively. The results indicated that the adsorption was a spontaneous endothermic nature.

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Materials Science Forum (Volumes 743-744)

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759-767

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January 2013

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© 2013 Trans Tech Publications Ltd. All Rights Reserved

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[1] S.H. Lin, Adsorption of disperses dye by powdered activated carbon, Chem. Technol. Biotechnol. 57 (1993) 387-391.

Google Scholar

[2] G. McKay, Y.S. Ho, Pseudo-second-order model for sorption processes, Process Biochem. 34 (1999) 451-465.

DOI: 10.1016/s0032-9592(98)00112-5

Google Scholar

[3] Y.C. Gu, X.P. Liao, Y.L. Wang, B. Shi. Decolouration of Anionic Dye Contaminated Water by the Adsorption of Metal- ion-loaded CF from Skin Waste, Journal of basic science and engineering. 16 (2008) 647-658.

Google Scholar

[4] X.P. Liao, B. Shi, Collagen Fiber Immobilized Myricarubra Tannin and Its Adsorption to UO2, Sci. Technol. 38 (2004) 324-328.

Google Scholar

[5] X.P. Liao, B Shi, Adsorption of Fluoride on Zirconium (IV)-Impregnated Collagen Fiber, Environ. Sci. Technol. 38 (2004) 324-328.

Google Scholar

[6] H.M. Cheng, R. Wang, Preparation and Characterization of Acid Relaxed CF from Pigskin, Journal of SiChuan University (Engineering Science Edition). 39 (2007) 78-82.

Google Scholar

[7] S. Anirudhan, M. Ramachandran, Synthesis and Characterization of Amidoximated Polya- CryLo-nitrile/Organobent-onite Composite for Cu(II), Zn(II), and Cd(II) Adsorption from Aqueous Solutions and Industry Wastewaters, Ind. Eng. Chem. Res. 47 (2008).

DOI: 10.1021/ie070735d

Google Scholar

[8] Z.H. Chen, S. Chen, Adsorption Equilibrium and Kinetic of Dyes onto Aminated Chitosan Microspheres, Guangzhou Chemistry. 4 (2004) 30-33.

Google Scholar

[9] L. Zeng, D.L. Wang, L. P Wu, Absorption of anionic dyes on the Chitin, Journal of BeiHua university(Natural Science). 10 (2009) 490-493.

Google Scholar

[10] D.P. Das, J. Das, K. Parida, Physicochemical characterization and adsorption behaviour of calcined Zn/Al hydrotalcite-like compound (HTlc) towards removal of fluoride from aqueous solution, Colloid Interface Sci. 261 (2003) 213-220.

DOI: 10.1016/s0021-9797(03)00082-1

Google Scholar

[11] X.S. Wang, Z.Z. Li, S.R. Tao, Romoval of chromium(Ⅵ) from aqueous solution using walnut hull, Journal of environmental Mangement. 90 (2009) 721-729.

DOI: 10.1016/j.jenvman.2008.01.011

Google Scholar

[12] J.J. Ma, N.Z. Zhuo, Kinetic and thermodynamic studies on the adsorption of acid dyes with chitosan-montmorillonite hybrid materials, Ion exchange and adsorption. 27 (2011) 129-136.

Google Scholar

[13] H.R. Li, Y.M. Zhang, The characteristics of Cr(Ⅵ) adsorbed by walnuts shell powder, Journal of Agro-Environment science. 28 (2009) 1693-1700.

Google Scholar

[14] Y.C. Gu, X.P. Liao, Y.L. Wang, B. Shi, Adsorption of Dyes on Zr(Ⅳ)-loaded CF from Aqueous Solution, Journal of basic science and engineering. 3 (2007) 414-422.

Google Scholar

[15] Z. Aksu, Biosorption of reactive dyes by dried activated sludge: equilibrium and kinetic modeling, Biochemical Engineering Journal. 7 (2001) 79-84.

DOI: 10.1016/s1369-703x(00)00098-x

Google Scholar

[16] L.M. Zhou, C. Shang, Acid Dye Adsorption Properties of Ethylenediamine·Modified Magnetic Chitosan NanoparticIes, Acta Phys. -Chim. Sin. 27 (2011) 677-682.

Google Scholar

[17] Z.L. Wang, Y.P. Zhou, Physical chemisitry, Higher Education Press, Tianjin, (2008).

Google Scholar

[18] J.L. Zhang, L.P. Liang, L.J. Pu, L.P. Wang. Adsorption Characteristics of Cr(Ⅵ) by Wheat Straw Including Kinetic and Thermodynamics Analysis, Research of Environmental Sciences. 23 (2010) 1546-1552.

Google Scholar