Microstructure of Directionally Solidified Mg-Zn Alloy with Different Growth Rates

Article Preview

Abstract:

The influence of withdrawal rate on the microstructure of directionally solidified Mg-x%Zn (x=2, 4, 6) alloys was investigated in this paper. It was found that with the withdrawal rates increased from 20 μm/s to 60 μm/s, the morphology of the solid-liquid interface changed from planer to cellular dendrite. When the growth rate was further increased to 120 μm/s, the solidification microstructure appeared to be the typical dendrite structure with the developed secondary dendrite arms. Meanwhile, the dendrite arm spacing decreased with the increase of growth rate. Under the same solidification conditions, the microstructure went through cell branch transformation with the increase of Zn content within a lower withdrawal rate range; while the Zn content did not affect the morphology at a higher withdrawal rate. As well, the microstructure was refined gradually with the increase of Zn content. The effects of withdrawal rate and alloying content on morphology were analyzed by constitutional supercooling and the MS theory.

You might also be interested in these eBooks

Info:

Periodical:

Pages:

411-417

Citation:

Online since:

April 2015

Export:

Price:

Permissions CCC:

Permissions PLS:

Сopyright:

© 2015 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

* - Corresponding Author

[1] R.E. Brown, Future of Magnesium Developments in 21st Century, in: Presentation at Materials Science &Technology Conference, Pittsburgh, PA, USA, October 5-9, (2008).

Google Scholar

[2] A.A. Luo, K. Sadayappan, Technology for Magnesium Castings, American Foundry Society, IL. (2011) 29-47.

Google Scholar

[3] M.M. Avedesian, H. Baker, Magnesium and Magnesium alloys, ASM International, Materials Park, OH, (1999).

Google Scholar

[4] E.L. Zhang, D.S. Yin, L.P. Xu, L. Yang, K. Yang, Microstructure, mechanical and corrosion properties and biocompatibility of Mg-Zn-Mn alloys for biomedical application, Mat. Sci. eng. C. 29 (2009) 987-993.

DOI: 10.1016/j.msec.2008.08.024

Google Scholar

[5] H. Somekawa, T. Mukai, Fracture toughness in a rolled AZ31 magnesium alloy, J. Alloy Comp. 417 (2006) 209-213.

DOI: 10.1016/j.jallcom.2005.07.073

Google Scholar

[6] D.K. Xu, L. Liu, Y.B. Xu, E.N. Han, Effect of microstructure and texture on the mechanical properties of the as-extruded Mg–Zn–Y–Zr alloys, Mater. Sci. Eng. A 443 (2007) 248-256.

DOI: 10.1016/j.msea.2006.08.037

Google Scholar

[7] N. Stanford, The effect of calcium on the texture, microstructure and mechanical properties of extruded Mg–Mn–Ca alloys, Mate. Sci. Eng. A 528 (2010) 314-322.

DOI: 10.1016/j.msea.2010.08.097

Google Scholar

[8] X. Gao, J.F. Nie, Scripta Mater. 56 (2007) 645-648.

Google Scholar

[9] X. Zeng, Y. Wang, W. Ding, A. Luo, A. Sachdev, Metall. Mater. Trans. A 37 (2006) 1333-1341.

Google Scholar

[10] X.N. Gu, Y.F. Zheng, A study on alkaline heat treated Mg–Ca alloy for the control of the biocorrosion rate, Biomaterials. 30 (2009) 484-498.

DOI: 10.1016/j.actbio.2009.01.048

Google Scholar

[11] S.X. Zhang, X.N. Zhang, Research on an Mg-Zn alloy as a degradable biomaterial, Acta Biomater. 6 (2010) 626-640.

Google Scholar

[12] H. Okamoto, Comment on Mg-Zn (magnesium-zinc). J Phase Equilibria Diffus. 15(1994) 129-130.

DOI: 10.1007/bf02667700

Google Scholar

[13] C.J. Boehlert, The microstructure, tensile properties, and creep behavior of Mg–Zn alloys containing 0–4. 4 wt. % Zn, Mater. Sci. Eng. A 417 (2006) 315-321.

DOI: 10.1016/j.msea.2005.11.006

Google Scholar

[14] Y.W. Song, E.H. Han, The effect of Zn concentration on the corrosion behavior of Mg-xZn alloys, Corros Sci. 65 (2012) 322-330.

DOI: 10.1016/j.corsci.2012.08.037

Google Scholar

[15] K. Pettersen, O. Lohne, N. Ryum, Dendrite solidification of magnesium alloys AZ91, Metall. Trans. A. 21 (1990) 221-230.

DOI: 10.1007/bf02656439

Google Scholar

[16] M. Paliwal, In-Ho Jung, The evolution of the growth morphology in Mg-Al alloys depending on the cooling rate during solidification, Acta Mater. 61 (2013) 4848-4860.

DOI: 10.1016/j.actamat.2013.04.063

Google Scholar

[17] M. Paliwal, In-Ho Jung, Microstructural evolution in Mg-Zn alloys during solidification: An experimental and simulation study, J. Cryst. Growth. 394 (2014)28–38.

DOI: 10.1016/j.jcrysgro.2014.02.010

Google Scholar

[18] M. Mabuchi, M. Kobata, Y. Chino, Tensile properties of directionally solidified AZ91 Mg alloy, Mater. Trans. 44 (2003) 436-439.

DOI: 10.2320/matertrans.44.436

Google Scholar

[19] G.W. Chang, S.Y. Chen, C. Zhou, Relationship between solid/liquid interface and crystal orientation for pure magnesium solidified in fashion of cellular crystal, Trans. Nonferrous Met. Soc. China 20 (2010) 289-293.

DOI: 10.1016/s1003-6326(09)60136-9

Google Scholar

[20] Djordje. Mirkovic, Rainer. Schmid-Fetzer, Directional Solidification of Mg-Al alloys and microsegregation study of Mg alloys AZ31 and AM50: Part Ⅰ. Methodology, Metall. Mater. Trans. A 40 (2009) 958-973.

DOI: 10.1007/s11661-009-9787-3

Google Scholar

[21] M. Chen, X.D. Hu, The microstructure prediction of magnesium alloy crystal growth in directional solidification, Comp. Mater. Sci. 79 (2013) 684–690.

DOI: 10.1016/j.commatsci.2013.07.030

Google Scholar

[22] J.W. Fu, Y.S. Yang, Formation of the solidified microstructure in Mg–Sn binary alloy, Cryst. Growth 322 (2011) 84-90.

DOI: 10.1016/j.jcrysgro.2011.03.026

Google Scholar

[23] G.X. Hu, X. Cai, Y.H. Rong (Eds. ), Fundamentals of Materials Science, Shanghai Jiao Tong University Press, Shanghai, China, 2000. pp.298-300.

Google Scholar

[24] H.Z. Fu, J.J. Guo, L. Liu (Eds. ), Directional Solidification and Processing of Advanced Materials, Sciences Press, Beijing, China, 2008. pp.224-233.

Google Scholar