Deposition of Ag 2~6 mol%-Doped ZnO Photocatalyst Thin Films by Thermal Spray Coating Method for E.coli Bacteria Degradation

Article Preview

Abstract:

ZnO doped with 2~6 mol% Silver (Ag) photocatalyst thin films has been deposited on glass substrate by thermal spray coating with temperature deposition of 250°C. A gel of ZnO:Ag precursor has been synthesized by sol-gel route from aqueous/alcoholic solution of zinc acetate dehydrate and silver nitrate mixture at room temperature. The morphology of ZnO:Ag films were investigated scanning electron microscopy (SEM). 3D SEM images of ZnO:Ag thin films show the rough morphology with roughness mean square (rms) of 150 to 195 nm. The grain size of ZnO:Ag films were found in the range 76,5 to 304,8 nm. The photoactivity examination of ZnO:Ag photocatalyst films show the E. Coli bacteria degraded up to 99.99% under sunlight irradiation for 4 hours.

You might also be interested in these eBooks

Info:

Periodical:

Pages:

3-6

Citation:

Online since:

August 2015

Export:

Price:

Permissions CCC:

Permissions PLS:

Сopyright:

© 2015 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

* - Corresponding Author

[1] S. Baruah, and J. Dutta, Nanotechnology applications in pollution sensing and segradation in agriculture, a review. Environ. Chem. Lett. 7 (2009) 1-14.

Google Scholar

[2] L. Chen, T. ThanhThuyn, C. Huang, J. Li, L. Yuan, and C. Qing Yun, Synthesis and photocatalytic application of Au/Ag nanoparticle-sensitized ZnO films, Appl. Surface Science 273 (2013) 82-88.

DOI: 10.1016/j.apsusc.2013.01.184

Google Scholar

[3] A. Fujishima, T.N. Rao, and D.A. Tryk, Titanium dioxide photo catalysis, Journal of Photochemistry and Photobiology, C: Photochemistry Reviews 1 (2000) 1-21.

DOI: 10.1016/s1389-5567(00)00002-2

Google Scholar

[4] J. Zhi-Gang, P. Kuan-Kuan, L. Yan-Hua, and Z. Rong-Sun, Preparation and photocatalytic performance of porous ZnO Micro rods Loaded with Ag, Journal of Trans. Nonferrous Met. Soc. 22 (2012) 873-878.

Google Scholar

[5] R. Chauhan, A. Kumar, and R.P. Chaudary, Synthesis and characterization of silver doped ZnO nanoparticles, Journal of Scholar Research Library 2 (2010) 378-385.

Google Scholar

[6] J. S. Kim, E. Kuk, K. N. Yu, K. Jong-Ho, S. J. Park, L. H. Jang, K. S. Hyun, P. Y. Kyung, P. Y. Ho, H. Cheol-Yong, K. Yong-Kwon, L. Yoon-Sik, J. D. Hong, and C. Myung- Cho, Antimicrobial effects of silver nanoparticles, Nanomedicine: Nanotechnology, Biology, and Medicine 3 (2007).

DOI: 10.1109/dac.1998.724580

Google Scholar

[7] N. L. Tarwal, and P.S. Patil, Enhanced photo electrochemical performance of Ag–ZnO thin films synthesized by spray pyrolysis technique, Electrochemical Acta. 56 (2011) 6510-6516.

DOI: 10.1016/j.electacta.2011.05.001

Google Scholar

[8] S. K. Panda, and C. Jacob, Preparation of transparent ZnO thin films and their application in UV sensor devices, Solid-State Electronics 73 (2012) 44-50.

DOI: 10.1016/j.sse.2012.03.004

Google Scholar

[9] M. H. Habibi, and R. Sheibani, Nanostructure silver-doped zinc oxide films coating on glass prepared by sol–gel and photochemical deposition process: Application for Removal of Mercaptan, Journal of Industrial and Engineering Chemistry 19 (2013).

DOI: 10.1016/j.jiec.2012.07.019

Google Scholar

[10] C. Y. Tsay, and W. C. Lee, Effect of dopants on the structural, optical and electrical properties of sol-gel derived ZnO semiconductor thin films, Journal of Current Applied Physics 13 (2013) 60-65.

DOI: 10.1016/j.cap.2012.06.010

Google Scholar

[11] J. B. You, X.W. Zhang, Y. M. Fan, Z. G. Yin, P. F. Cai, and N. F. Chen, Effect of the morphology of ZnO/Ag interface on the surface-plasmon-enhanced emission of ZnO films, J. Phys. D: Appl. Phys. 41 (2008) 205101C.

DOI: 10.1088/0022-3727/41/20/205101

Google Scholar

[12] J. C. Chang, M.H. Hsu, Y. C. Weng, C. Y. Tsay, and C. K. Lin, Hierarchical ZnO nanorod-array Films with enhanced photocatalytic performance, Journal of Thin Solid Films 528 (2013) 167-174.

DOI: 10.1016/j.tsf.2012.09.083

Google Scholar

[13] C. Wang, L. L. Liu, A. T. Zhang, P. Xie, J. J. Lu, and X. T. Zou, Antibacterial effects of zinc oxide nanoparticles on E. coli K88, African Journal of Biotechnology 11 (2012) 10248-10254.

Google Scholar