Effects of Paste Composition and Sintering Process on Performance of Silver Paste for Silicon Solar Cells

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In order to study the effects of composition ratio of silver paste and the sintering process on the properties of the silver film after sintering, the effects of different ratios of silver powders, glass powders and organic carrier in silver paste and different sintering temperatures and sintering time on the adhesion force and square resistance of the silver film were studied. The morphology of the sintered silver film was observed by SEM. The results showed that the silver film sintered at 760°C for 6 seconds had better properties after sintering when the ratio of silver powders, glass powders and organic carrier in silver paste was 80:5:15 and the silver powders was composed of spherical silver powders and flake silver powders at the ratio of 94:6. The adhesion force and square resistance of the silver film were 8.25 N and 3.47mΩ /□, respectively.

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852-859

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March 2016

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© 2016 Trans Tech Publications Ltd. All Rights Reserved

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[1] Rita Faddoul, Nadege Reverdy-bruas, Josephine Bourel. Silver content effect on rheological and electrical properties of silver paste. J Mater Sci: Mater Electron 2012, 23: 1415-1426.

DOI: 10.1007/s10854-011-0607-3

Google Scholar

[2] Hu XD, Chen FC, Li ZR, et al. Fabrication of lead-free frit and Si-based silver conductive paste. Electronic components and Materials 2011, 30: 53-56.

Google Scholar

[3] Liu Z, Qi XL, Wang H. Synthesis and characterization of spherical and mono-disperse micro-silver powder used for silicon solar cell electronic paste. Advanced Powder Technology 2012, 23: 250-255.

DOI: 10.1016/j.apt.2011.03.004

Google Scholar

[4] S. Thibert, J. Jourdan, B. Bechevet, et al. Influence of silver paste rheology and screen parameters on the front side metallization of silicon solar cell. Materials science in semiconductor processing 2014, 27: 790-799.

DOI: 10.1016/j.mssp.2014.08.023

Google Scholar

[5] Tsai J. T, Lin S. T, Silver powder effectiveness and mechanism of silver paste on silicon solar cells. Journal of Alloys and Compounds 2013, 548: 105-109.

DOI: 10.1016/j.jallcom.2012.09.018

Google Scholar

[6] Peng J, Deng J G, Huang YG. Research Progress and Market Situation of Conductive Silver Paste in Solar Cells, Materials Review 2012, 26: 141-150.

Google Scholar

[7] Zhang YH, Yan B, Huang YG. Recent Progress and Development Trends of Silver Slurry, Metallic Functional Materials, 2012, 19: 36-40.

Google Scholar

[8] Yang H, Chen C K, Wang H, et al., Impact of interface microstructure on adhesion force between silver paste and silicon solar cells' emitter. Clean Techn. Environ. Policy, 2014, 16: 655-659.

DOI: 10.1007/s10098-013-0661-z

Google Scholar

[9] Rane S B, Khanna P K, Seth T. Firing and processing effects on microstructure of fritted silver thick film electrode materials for solar cells. Materials Chemistry and Physics 2003, 82 : 237–245.

DOI: 10.1016/s0254-0584(03)00236-0

Google Scholar

[10] Ketkar S A, Umarji G G, Phatak G J. Effect of glass content variation on properties of photo-image able silver conductor paste. Materials Chemistry and Physics 2006, 96 : 145-153.

DOI: 10.1016/j.matchemphys.2005.06.054

Google Scholar

[11] Che QD, Yang HX, Liu L, et al. A new environmental friendly silver front contact paste for crystalline silicon solar cells. Journal of Alloys and Compounds 2013, 549: 221–225.

DOI: 10.1016/j.jallcom.2012.09.080

Google Scholar

[12] You NK, Hye YK, Jung HK, et al. Characteristics of silver–glass composite powders as the silver electrode for Si solar cells. Journal of Alloys and Compounds 2010, 491: 584–588.

DOI: 10.1016/j.jallcom.2009.11.008

Google Scholar

[13] Jiang C S, Li Z G, Moutinho H R, et al., The effect of front side silver metallization an underlying n+-p junction in multicrystalline silicon solar cells. IEEE photovoltaic specialists conference 2012, 42(11): 003365-003370.

DOI: 10.1109/pvsc.2012.6318293

Google Scholar

[14] Chen Z Q. The effect of peak firing temperature on sheet resistivity for Ru-based thick film resistor. Electron Devices 1995, 18: 239-248.

Google Scholar