Performance and Characterization of Resistance to Ultraviolet Radiation of Vi-POSS-TiO2/EP Nanocomposites

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Improving the mechanical properties and ultraviolet resistant properties of epoxy resin (EP) is attracting the scientists’ increasing interest in engineering industries at present. For this reason, novel Vi-POSS-TiO2/EPnanocomposites were prepared by incorporating nanotitanium dioxide (TiO2) and PSS-Octavinyl substituted (Vi-POSS) organic-inorganic hybridparticles into the epoxy resin. Filling up with TiO2 and Vi-POSS may create an inherent ultraviolet (UV) absorption property and mechanical property, respectively. The obtained composites were characterized by some standard analytical techniques such as UV-vis spectroscopy, Scanning electron microscope (SEM), and Thermal gravity analysis (TGA). When the content of TiO2was 1.5wt%, UV-vis absorption spectra showed that the excellent absorption properties of EP composites can be achieved. When the content of Vi-POSS was 6wt%, the values of bend strength and impact strength were improved 14.75%and37.94%, respectively. The TGA result showed that the thermal stability of EP composites varied in a small range before and after adding 6wt% Vi-POSS.

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411-416

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April 2016

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[1] Thomas R, Yumei D, Yuelong H, Le Y, Moldenaers P, Weimin Y, et al. Miscibility, morphology, thermal, and mechanical properties of a DGEBA based epoxy resin toughened with a liquid rubber. Polym. 49(2008)278-294.

DOI: 10.1016/j.polymer.2007.11.030

Google Scholar

[2] Saw LN, Mariatti M, Azura AR, Azizan A, Kim JK. Transparent, electrically conductive, and flexible films made from multiwalled carbon nanotube/epoxy composites. Compos Par B-Eng. 43(2012)2973-2979.

DOI: 10.1016/j.compositesb.2012.05.048

Google Scholar

[3] Voo R, Mariatti M, Sim LC. Flexibility improvement of epoxy nanocomposites thin films using various flexibilizing additives. Compos Par B-Eng. 43(2012)3037-3043.

DOI: 10.1016/j.compositesb.2012.05.032

Google Scholar

[4] Chruściel JJ, Leśniak E. Modification of epoxy resins with functional silanes, polysiloxanes, silsesquioxanes, silica and silicates. Prog Polym Sci. 41(2015)67-121.

DOI: 10.1016/j.progpolymsci.2014.08.001

Google Scholar

[5] Chen D, Yi S, Wu W, Zhong Y, Liao J, Huang C, et al. Synthesis and characterization of novel room temperature vulcanized (RTV) silicone rubbers using Vinyl-POSS derivatives as cross linking agents. Polym. 51(2010)3867-3878.

DOI: 10.1016/j.polymer.2010.06.028

Google Scholar

[6] Misra R, Alidedeoglu AH, Jarrett WL, Morgan SE. Molecular miscibility and chain dynamics in POSS/polystyrene blends: Control of POSS preferential dispersion states. Polym. 50(2009)2906-2918.

DOI: 10.1016/j.polymer.2009.03.057

Google Scholar

[7] Musto P, Abbate M, Pannico M, Scarinzi G, Ragosta G. Improving the photo-oxidative stability of epoxy resins by use of functional POSS additives: A spectroscopic, mechanical and morphological study. Polym. 53(2012)5016-5036.

DOI: 10.1016/j.polymer.2012.08.063

Google Scholar

[8] Strachota A, Whelan P, Kříž J, Brus J, Urbanová M, Šlouf M, et al. Formation of nanostructured epoxy networks containing polyhedral oligomeric silsesquioxane (POSS) blocks. Polym. 48(2007)3041-3058.

DOI: 10.1016/j.polymer.2007.03.052

Google Scholar

[9] Jiao J, Wang L, Lv P, Cui Y, Miao J. Improved dielectric and mechanical properties of silica/epoxy resin nanocomposites prepared with a novel organic–inorganic hybrid mesoporous silica: POSS–MPS. Mater Lett. 129(2014)16-19.

DOI: 10.1016/j.matlet.2014.05.010

Google Scholar

[10] Rosu D, Rosu L, Mustata F, Varganici C-D. Effect of UV radiation on some semi-interpenetrating polymer networks based on polyurethane and epoxy resin. Polym Degrad Stab. 97(2012)1261-1269.

DOI: 10.1016/j.polymdegradstab.2012.05.035

Google Scholar

[11] Decker C, Biry S, Zahouily K. Photostabilisation of organic coatings. Polym Degrad Stab. 49(1995)111-119.

DOI: 10.1016/0141-3910(95)00068-w

Google Scholar

[12] Aloui F, Ahajji A, Irmouli Y, George B, Charrier B, Merlin A. Inorganic UV absorbers for the photostabilisation of wood-clearcoating systems: Comparison with organic UV absorbers. Appl Surf Sci. 253(2007)3737-3745.

DOI: 10.1016/j.apsusc.2006.08.029

Google Scholar

[13] Jia H, Wang H, Chen W. The combination effect of hindered amine light stabilizers with UV absorbers on the radiation resistance of polypropylene. Radiat Phys Chem. 76(2007)1179-1188.

DOI: 10.1016/j.radphyschem.2006.12.008

Google Scholar

[14] Broasca G, Borcia G, Dumitrascu N, Vrinceanu N. Characterization of ZnO coated polyester fabrics for UV protection. Appl Surf Sci. 279(2013)272-278.

DOI: 10.1016/j.apsusc.2013.06.071

Google Scholar

[15] Wong T-t, Tam W-y, Etches JA, Wang W-x, Leng J, Lau K-t. Feasibility of using ZnO/epoxy filled hollowed glass fibres (HGFs) for UV resistant polymer composites. Mater Lett. 128(2014)220-223.

DOI: 10.1016/j.matlet.2014.04.083

Google Scholar

[16] Florea NM, Lungu A, Badica P, Craciun L, Enculescu M, Ghita DG, et al. Novel nanocomposites based on epoxy resin/epoxy-functionalized polydimethylsiloxane reinforced with POSS. Compos Par B-Eng. 75(2015)226-234.

DOI: 10.1016/j.compositesb.2015.01.043

Google Scholar

[17] Assanvo EF, Gogoi P, Dolui SK, Baruah SD. Synthesis, characterization, and performance characteristics of alkyd resins based on Ricinodendron heudelotii oil and their blending with epoxy resins. Ind Crop Prod. 65(2015)293-302.

DOI: 10.1016/j.indcrop.2014.11.049

Google Scholar

[18] Chattopadhyay DK, Panda SS, Raju KVSN. Thermal and mechanical properties of epoxy acrylate/methacrylates UV cured coatings. Prog Org Coat. 54(2005)10-19.

DOI: 10.1016/j.porgcoat.2004.12.007

Google Scholar

[19] Luda MP, Balabanovich AI, Camino G. Thermal decomposition of fire retardant brominated epoxy resins. J Anal Appl Pyrol. 65(2002)25-40.

DOI: 10.1016/s0165-2370(01)00175-9

Google Scholar

[20] Wang Q, Shi W. Kinetics study of thermal decomposition of epoxy resins containing flame retardant components. Polym Degrad Stab. 91(2006)1747-1754.

DOI: 10.1016/j.polymdegradstab.2005.11.018

Google Scholar