Electrochemical Behavior of Electroactive PVS/PANI Films Containing Chemically Modified Cellulose

Paulo Ronaldo Sousa Teixeira; Ana Siqueira do N. Marreiro Teixeira; José Regilmar Teixeira da Silva; Emanuel Airton de Oliveira Farias; Natália de Araujo Dionisio; Edson Cavalcanti da Silva Filho; Carla Eiras

doi:10.4028/www.scientific.net/MSF.869.809

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HomeMaterials Science ForumMaterials Science Forum Vol. 869Electrochemical Behavior of Electroactive PVS/PANI...

Electrochemical Behavior of Electroactive PVS/PANI Films Containing Chemically Modified Cellulose

Abstract:

Electroactive films containing cellulose modified with cationic and anionic groups were prepared with polyaniline (PANI) and poly (vinyl sulfonic acid) (PVS). The modifications were performed with (aminomethyl) pyridine (AMP), ethylenediamine (EDA), buthylenediamine (BN), bis-(aminopropyl) piperazine (APP), maleic anhydride (MA), and phosphate PO₄^3- groups_. The films were prepared using the layer-by-layer (LbL) technique, utilizing dispersed cellulose in a PANI solution forming the PVS/PANI system (cationic or anionic cellulose). Films of unmodified microcrystalline cellulose (MC) were also prepared for comparison. The films were characterized by cyclic voltammetry. The electrochemical responses of PANI present in the film, especially in terms of current density and redox potential, were found to be influenced by the modification of the cellulose.

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21st Brazilian Conference on Materials Science and Engineering

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Materials Science Forum (Volume 869)

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809-814

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https://doi.org/10.4028/www.scientific.net/MSF.869.809

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Online since:

August 2016

Authors:

Paulo Ronaldo Sousa Teixeira*, Ana Siqueira do N. Marreiro Teixeira, José Regilmar Teixeira da Silva, Emanuel Airton de Oliveira Farias, Natália de Araujo Dionisio, Edson Cavalcanti da Silva Filho, Carla Eiras

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Electrochemical Behavior, Layer-By-Layer, Modified Cellulose, Polyaniline

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References

[1] O.N. Oliveira Jr, M. Raposo, A. Dhanabalan: Handbook of Surfaceand Interfaces of Materials. (H.S. Nalwa, ed. Academic Press, 4 2001).

Google Scholar

[2] G. Decher: Science Vol. 277 (1997), p.1232.

Google Scholar

[3] J.F. Rusling, E.G. Hvastkovsa, D.O. Hulla, J.B. Schenkmanb: Chem. Commun Vol. 14 (2) (2008), p.141.

Google Scholar

[4] L.H.C. Mattoso: Quím. Nova Vol. 19 (4) (1996), p.388.

Google Scholar

[5] A.F. Metaxa, E.K. Efthimiadou, N. Boukos, G. Kordas: Journal of Colloidand Interface Science Vol. 384 (2012), p.198.

Google Scholar

[6] W.D. Wanrosli, R. Rohaizy, A. Ghazali: Carbohydrate Polymers Vol. 84 (2011), p.262.

Google Scholar

[7] I.S. Lima, C. Airoldi. Thermochimica Acta Vol. 421(2004), p.133.

Google Scholar

[8] E.C. Silva Filho, J.C.P. Melo, Carlos Airoldi: Carbohydrate research Vol. 341 (2006), p.2842.

Google Scholar

[9] H. Devendrappa, U.V.S. Rao, M.V.N.A. Prasad: Journal Power Sources Vol. 155(2006), p.368.

Google Scholar

[10] L. Brozová, P. Holler, J. Kovárová, J. Stejskal, M. Trchová: Polymer Degradation and Stability Vol. 93 (2008), p.592.

Google Scholar

[11] E.A. Farias, N.A. Dionisio, P.V. Quelemes, S.H. Leal, J.M. Matos, E.C. Silva Filho, I.H. Bechtold, J.R. Leite, C. Eiras: Mater Sci. Eng. C. Mater. Biol. Appl. Vol. 35(2014), p.449.

Google Scholar

[12] W. Kern: Semiconductor International (1984), p.94.

Google Scholar

[13] E. C Silva Filho, S Júnior, L Sousa, M.M.F. Silva, M.G. Fonseca, S.A.A. Santana, Materials Research Vol. 16 (2013), p.79.

Google Scholar

[14] E. C Silva Filho, L.S. Silva, L.C.B. Lima, L.S. Santos Júnior, M.R.M.C. Santos, J.M.E. Matos, C. Airoldi: Separation Science and Technology Vol. 46 (2011), p.2566.

DOI: 10.1080/01496395.2011.599826

Google Scholar

[15] J.C. P Melo, E.C. Silva Filho, S.A.A. Santana, C. Airoldi. Colloidsand Surfaces A Physicochemical and Engineering Aspects Vol. 346 (2009), p.138.

Google Scholar

[16] T. Oshima, S. Taguchi, K. Ohe, Y. Baba: Carbohydrate Polymers Vol. 83 (2011), p.953.

Google Scholar

[17] E.C. Silva Filho, J.C. Melo, C. Airoldi: Carbohydrate Research Vol. 341 (2006), p.2842.

Google Scholar