Photosensitized Polystyrene Film for Dye TX under Different Radiation Sources

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The polystyrene (PS) has a variety of applications. Many mechanisms have been proposed for the degradation of the polymer, but a consistent mechanism does not exist yet in the literature due to the complexity of the kinetics and formation of photoproducts that depend on various conditions photodegradation. The aim of this study was to investigate the kinetic behavior of the photodegradation of PS films photosensitized by thioxanthone (TX) under UV, Vis and xenon radiation. Changes in chemical structure caused by photo-oxidation in the films were verified by FT-IR. The photodegradation of polystyrene films sensitized by thioxanthone showed greater efficiency in the formation of carbonyl group under Vis radiation and xenon when compared to pure PS. However, in the ultraviolet films system PS and PS / TX exhibited similar kinetic behavior.

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820-823

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August 2016

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© 2016 Trans Tech Publications Ltd. All Rights Reserved

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[1] N. Grassie, G. Scott: Polymer Degradation and Stabilization. (Cambridge University Press Cambridge, 1985).

Google Scholar

[2] M.D. Millan et al: Polymer. Vol. 46 (2005), p.5556.

Google Scholar

[3] M.V. Encinas et al.: Polymer. Vol. 43 (2002), p.3909.

Google Scholar

[4] H. Kaczmarek, A. Kaminska, S. S. Swiatek: Eur. Polym. J. Vol. 36 (2000), p.1167.

Google Scholar

[5] J.F. Rabek, Experimental Methods in Photochemistry and Photophysics: (John Wiley & Sons Ltda Part 2, 1982).

Google Scholar

[6] J. Kubica, B. Waligóra: Eur. Polym. J. Vol. 13 (1997), p.325.

Google Scholar

[7] L.F.A. Pinto et al: J. Res. Upd. Polym. Sci. Vol. 2 (2013), p.39.

Google Scholar

[8] N.S. Allen: Polym. Degrad. Stab. Vol. 44 (1994), p.357.

Google Scholar

[9] M.I. Felisberti, C. Saron: Quím. Nova Vol. 29 (2006), p.124.

Google Scholar

[10] N.S. Allen, M. Edge: Fundamentals of Polymer Degradation and Stabilization. (Applied Science, Elsevier London, 1992).

Google Scholar