Enhanced Dielectric and Electrical Properties in Polyurethane Composites with Graphene Nanosheets

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The Electrical properties of polyurethane (PU) filled with graphene nanosheets (GRN) at low frequency is investigated. In last decade, polyurethane elastomers have attracted attention in transducer and actuator applications. The dielectric constant is one of the key factors for increasing actuator ability. Graphene nanosheets as conducting fillers have to be filled to increase the dielectric constant. In order to prove this idea, polyurethane composites with various graphene contents have been characterized by SEM and DSC. And their electrical capability has been measured at various frequencies of 101-104 by using LCR meter. To gain the films, polyurethane composites filled with various graphene contents were prepared by solution casting method. The results showed a well homogenous dispersion of the graphene filler in the polyurethane matrix. In addition, it was found that the glass transition temperature (Tg) of the PU/GRN increase as the content of filler increased and it can be affected the interfacial polarization between PU matrix with the GRN fillers. Therefore, it is found that graphene in the polyurethane matrix exhibit high enhanced the electrical properties and the optimal dielectric constant at 2wt% graphene of 9.74.

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117-121

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March 2018

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© 2018 Trans Tech Publications Ltd. All Rights Reserved

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[1] P, -J, Cottinet, D. Guyomar, B. Guiffard, L. Lebrun and C. Putson: Electrostrictive Polymer Composite for Energy harvesters and Actuators. J Polymer Eng 31 (2011) 133-140.

DOI: 10.1515/polyeng.2011.030

Google Scholar

[2] M. Lallart, P, -J, Cottinet, D. Guyomar, B. Guiffard and L. Lebrun: Electrostrictive Polymers for Mechanical Energy Harvesting. Journal of Polymer Science Part B: Polymer Physics 50 (2012) 523-535.

DOI: 10.1002/polb.23045

Google Scholar

[3] D. Jaaoh, C. Putson and N. Meunsit: Enhanced strain response and energy harvesting capabilities of electrostrictive polyurethane composites filled with conducting polyaniline. Composites Science and Technology 122 (2016) 97-103.

DOI: 10.1016/j.compscitech.2015.11.020

Google Scholar

[4] L. Lebrun, D. Guyomar, B. Guiffard, P. -J. Cottinet and C. Putson: The Characterisation of the harvesting capabilities of an electrostrictive polymer composite. Sensors and Actuators A 153 (2009) 251–25.

DOI: 10.1016/j.sna.2009.05.009

Google Scholar

[5] Z. Wang, T. Wang, M. Fang, C. Wang, Y. Xiao, Y. Pu: Enhancement of dielectric and electrical properties in BFN/Ni/PVDF three-phase composites. Composites Science and Technology 146 (2017) 139-146.

DOI: 10.1016/j.compscitech.2017.04.023

Google Scholar

[6] M. Rahaman, T.K. Chaki, D. Khastgir: Consideration of interface polarization in the modelling of dielectric property for ethylene vinyl acetate (EVA)/polyaniline conductive composites prepared through in-situ polymerization of aniline in EVA matrix. European Polymer Journal 48 (2012).

DOI: 10.1016/j.eurpolymj.2012.04.016

Google Scholar

[7] G. Wang, Enhanced dielectric properties of three-phase-percolative composites based on thermoplastic-ceramic matrix (BaTiO+PVDF) and ZnO radial nanostructures, ACS Appl. Mater. Interfaces 2 (2010) 1290-1293.

DOI: 10.1021/am100296u

Google Scholar

[8] M. Bera and P.K. Maji: Effect of structural disparity of graphene-based materials on thermomechanical and surface properties of thermoplastic polyurethane nanocomposites. Polymer 119 (2017) 118-133.

DOI: 10.1016/j.polymer.2017.05.019

Google Scholar