Bio Adsorbent from Modified Jackfruit Wood Sawdust for Removal of Lead Ions

Abstract:

The adsorption of Pb (II) ions from aqueous solution by bio adsorbent from jackfruit wood sawdust treated with phosphoric acid was studied in a batch adsorption system. Characteristics of bio adsorbent investigated by Fourier transform infrared (FTIR). The functional group which involved in Pb (II) binding during adsorption process were amine N-H, amide C=O, alkyl C-H, and nitrile C≡N. The effects of phosphoric acid ratio to distilled water and soaking time on the adsorption capacity were investigated. Maximum adsorption of Pb (II) ions was carried out by bio adsorbent which modified by phosphoric acid with ratio to water 0.33. The experiment data of Pb (II) adsorption correlated well with pseudo second order kinetic model with correlation coefficient value 0.9988 and resulted adsorption capacity at equilibrium 1.4382 mg/g.

• Periodical: Materials Science Forum (Volume 934)
• Pages: 159-164
• DOI: https://doi.org/10.4028/www.scientific.net/MSF.934.159
• Online since: October 2018
• Authors: Tintin Mutiara*, Iman Rofiki, Muhammad Abu Dzar Al Ghifari
• Keywords: Adsorption, Bio Adsorbent, Jackfruit Wood, Lead Ions, Phosphoric Acid

References

[1] N.K. Srivastava and C.B. Majumder: Novel biofiltration methods for the treatment of heavy metals from industrial wastewater., J. Hazard. Mater. 151, 1-8, (2008).

[2] Manzoor, Q., Nadeem, R., Iqbal, M., Saeed, R., Ansari, T.M.: Organic acids pretreatment effect on Rosa bourbonia phyto-biomass for removal of Pb(II) and Cu (II) from aqueous media, Bioresour. Technol. 132, 446–452, (2013).

DOI: 10.1016/j.biortech.2013.01.156

[3] National Center for Biotechnology Information. PubChem Compound Database; CID=5352425, https://pubchem.ncbi.nlm.nih.gov/compound/5352425 (accessed Feb. 8, 2018).

[4] Rashmi Verma and Pratima Dwivedi: Heavy metal water pollution - A case study, Recent Research in Science and Technology, 5(5), 98-99, (2013).

[5] Fenglian Fu and Qi Wang: Removal of heavy metal ions from wastewaters: A review, Journal of Environmental Management 92, 407-418, (2011).

DOI: 10.1016/j.jenvman.2010.11.011

[6] R. Naseem and S. S. Tahir: Removal Of Pb(II) From Aqueous/Acidic Solutions by Using Bentonite As an Adsorbent, Water Res. 35, 3982-3986, (2001).

DOI: 10.1016/s0043-1354(01)00130-0

[7] Ashutosh Tripathi and Manju Rawat Ranjan: Heavy Metal Removal from Wastewater Using Low Cost Adsorbents, Journal of Bioremediation & Biodegradation, 6:6, (2015).

DOI: 10.4172/2155-6199.1000315

[8] Jusoha, A., Lam, S.S., Noraaini, A., Noor, M.J.M.M.: A simulation study of the removal efficiency of granular activated carbon on cadmium and lead, Desalination 206, 9–16, (2007).

DOI: 10.1016/j.desal.2006.04.048

[9] Gaballah I, Goy D, Allain E, Kilbertus G, Thauront J.: Recovery of copper through decontamination of synthetic solutions using modified barks, Met Metall Trans.B 28: 13-23, (1997).

DOI: 10.1007/s11663-997-0122-3

[10] Nakajima A and Sakaguchi T: Recovery and removal of uranium by using plant wastes, Biomass 21: 55-63, (1990).

DOI: 10.1016/0144-4565(90)90047-n

[11] Jain, K.C., Malik, D.S., Yadav, A.K.: Applicability of plant based biosorbents in the removal of heavy metals: a review. Environ. Process. 3, 495–523 (2016).

DOI: 10.1007/s40710-016-0143-5

[12] de Melo, D.Q., de Sousa Neto, V.O., de Barros, F.C.F., Raulino, G.S.C., Vidal, C.B., Nascimento, R.F.: Chemical modifications of lignocellulosic materials and their application for removal cations and anions from aqueous solutions. J. Appl. Polym. Sci. 43, 43286 (2016).

DOI: 10.1002/app.43286

[13] Wang, J., Le, J., Wei, J.: Adsorption characteristics of noble metal ions onto modified straw bearing amine and thiol groups. J. Mater. Chem. A 3, 18163–18170 (2015).

DOI: 10.1039/c5ta05371d

[14] Jeon, C. and Kim, J.H.: Removal of lead ions using phosphorylated sawdust, Journal of Industrial and Engineering Chemistry 15: 910–913, (2009).

DOI: 10.1016/j.jiec.2009.09.023

[15] Masato Igura and Masanori Okazaki: Cadmium sorption characteristics of phosphorylated sago starch-extraction residue, Journal of Hazardous Materials, Volume 178, Issues 1–3, Pages 686-692, (2010).

DOI: 10.1016/j.jhazmat.2010.01.142

[16] Jeon, C., Cha, J.H., Choi, J.Y.: Adsorption and recovery characteristics of phosphorylated sawdust bead for indium(III) in industrial wastewater, Journal of Industrial and Engineering Chemistry Volume 27, Pages 201-206, (2015).

DOI: 10.1016/j.jiec.2014.12.036

[17] Pari and Roliadi: Alternative technology for the utilization of biomass waste from wood industries, Proceeding of the international workshop on better utilization of forest biomass for local community and environments, Research and Development Center for Forest Products Technology, (2004).

[18] Qin Li, Jianping Zhai, Wenyi Zhang, Mingmei Wang, Jun Zhou: kinetic studies of adsorption of Pb(II), Cr(III) and Cu(II) from aqueous solution by sawdust and modified peanut husk, Journal of Hazardous Materials 141, 163–167, (2007).

DOI: 10.1016/j.jhazmat.2006.06.109

[19] Ningchuan Feng and Fengyuan Zhang: Untreated Chinese ephedra residue as biosorbents for the removal of Pb2+ ions from aqueous solutions, Proceeding Enviromental Science, 18, 794-799, (2013).

DOI: 10.1016/j.proenv.2013.04.107

[20] Naiya, T.K., Chowdhury, P., Bhattacharya, A.K., Das, S.K.: Saw dust and neem bark as low-cost natural biosorbent for adsorptive removal of Zn(II) and Cd(II) ions from aqueous solutions, Chemical Engineering Journal 148, 68–79 (2009).

DOI: 10.1016/j.cej.2008.08.002