Facile Fabrication of N-Methyl-D-Glucamine Grafted HDPE Particle as Adsorbent for Boron Removal from Aqueous Solution

Ji Fu Du; Zhen Dong; Xin Yang; Long Zhao

doi:10.4028/www.scientific.net/MSF.953.198

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HomeMaterials Science ForumMaterials Science Forum Vol. 953Facile Fabrication of N-Methyl-D-Glucamine Grafted...

Facile Fabrication of N-Methyl-D-Glucamine Grafted HDPE Particle as Adsorbent for Boron Removal from Aqueous Solution

Abstract:

Glycidyl methacrylate (GMA) was grafted onto the surface of HDPE particles by radiation grafting and emulsion graft copolymerization. And subsequent ring-opening reaction of expoxy groups in poly-GMA graft chains with N-methylglucamine (NMG) was conducted to synthesis the boron adsorbent. The synthesis condition (radiation dose and NMG concentration) was optimized and characterized by IR and SEM. Adsorption behaviors of the boron adsorbent for boron removal presented that adsorption kinetics was well described by pseudo-second-order kinetic mode. The adsorption isothermal was well fitted with both Langmuir and Freundlich isotherm models. The adsorption capacity for boron reached 15.63 mg/g at optimal pH 8. Dynamic experiment revealed that boron could be efficiently adsorbed by the boron adsorbent and fully desorbed using 13 BV of 1 mol/L HCl.

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Materials Science Forum (Volume 953)

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198-205

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https://doi.org/10.4028/www.scientific.net/MSF.953.198

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Online since:

May 2019

Authors:

Ji Fu Du, Zhen Dong, Xin Yang, Long Zhao*

Keywords:

Boron Adsorbent, Emulsion Graft Copolymerization, HDPE, Radiation Grafting

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References

[1] B. Wang, X.H. Guo, P. Bai, Romoval technology of boron dissolved in aqueous solutions—A review. Colloid Surfaces A. 444(2014)338-344.

Google Scholar

[2] Y. Xu, J.Q. Jiang, Technologies for Boron Removal. Ind. Eng. Chem. Res.47(2015) 16-24.

Google Scholar

[3] J.Kang, Y. Tang, S. Gao, L. Liu,. One-dimensional controllable crosslinked polymers grafted with N-methyl-D-glucamine for effective boron adsorption. New J. Chem. 42(2018) 11334-11340.

DOI: 10.1039/c8nj00461g

Google Scholar

[4] N. B. Darwish, V. Kochkodan, N. Hilal, Boron removal from water with fractionized Amberlite IRA 743 resin. Desalination, 370(2015)1-6.

DOI: 10.1016/j.desal.2015.05.009

Google Scholar

[5] H. Hoshina, N. Seko, Y. Ueki, M. Tamada, Synthesis of Graft Adsorbent with N-Methyl- D-glucamine for Boron Adsorption. J. ion exchange18 (2007). 236–239.

DOI: 10.5182/jaie.18.236

Google Scholar

[6] M.M. Nasef, T.M. Ting, A. Abbasi, A. Layeghi-Moghaddam, S.S. Alinezhad, Radiation grafted adsorbents for newly emerging environmental applications. Radiat. Phys. Chem. 118(2016)55-60.

DOI: 10.1016/j.radphyschem.2015.02.025

Google Scholar

[7] T.M. Ting, M.M. Nasef, Modification of Polyethylene-polypropylene Fibers by Emulsion and Solvent Radiation Grafting Systems for Boron Removal. Fiber Polym 18(6) (2017)1048-1055.

DOI: 10.1007/s12221-017-6840-5

Google Scholar

[8] M.R. Saeb, H. Garmabi, Investigation of styrene-assisted free-radical grafting of glycidyl methacrylate onto high-density polyethylene using response surface method. J. Appl. Polym. Sci., 111 (2009) 1600–1605.

DOI: 10.1002/app.29123

Google Scholar

[9] M.M. Nasef, T.M. Ting, K. Hashim, Tuning N-methyl-D-glucamine density in a new radiation grafted poly (vinyl benzyl chloride)/nylon-6 fibrous boron-selective adsorbent using the response surface method. RSC Adv. 5(2015) 37869-37880.

DOI: 10.1039/c5ra00427f

Google Scholar

[10] M. Tagliabue, A.P. Reverberi, R. Bagatin, Boron removal from water: needs, challenges and perspectives.J. Clean Prod. 77 (2014)56-64.

DOI: 10.1016/j.jclepro.2013.11.040

Google Scholar

[11] X. Li, R. Liu, S. Wu, J. Liu, S.S. Cai, D.S. Chen, Efficient removal of boron acid by N-methyl-D-glucamine functionalized silica-polyallylamine composites and its adsorption mechanism. J. Colloin Interf Sci.361 (2011)232-237.

DOI: 10.1016/j.jcis.2011.05.036

Google Scholar

[12] M. Shaban, M.R. Abukhadra, AAP. Khan, B.M. Jibali, Removal of Congo red, methylene blue and Cr (VI) ions from water using natural serpentine. J. Taiwan Inst. Chem. E. 82 (2018) 102-116.

DOI: 10.1016/j.jtice.2017.10.023

Google Scholar

[13] Ting T.M., Hoshina H., Seko N., Tamada M. (2013) Removal of boron by boron-selective adsorbent prepared using radiation induced grafting technique. Desalination and Water Treatment, 51, 2602–2608.

DOI: 10.1080/19443994.2012.749054

Google Scholar

[14] S. Nishihama, Y. Sumiyoshi, T. Ookubo, K. Yoshizuka. Adsorption of boron using glucamine- based chelate adsorbents. Desalination, 310 (2013) 81-86.

DOI: 10.1016/j.desal.2012.06.021

Google Scholar