The Effects of Alkaline Earth Metals on the Structure of Sodium Borosilicate Glasses: ¹¹B and ²⁹Si NMR Study

Abstract:

The effect of substitution of alkaline earth metals for sodium on the structure of alkali borosilicate glasses had been studied using the solid-state ¹¹B and ²⁹Si NMR spectroscopy. NMR spectra enable to evaluate the relative mole fractions of different silicon and boron structural units in studied samples. The obtained results demonstrate that alkaline earth metals increase the polymerization degree of the silicon structural units at the expense of de-polymerization of the boron units. The reason for these changes is preferential coordination of sodium and alkaline earth metals to the boron units, that increases strongly for the studied alkaline earth metals.

• Periodical: Materials Science Forum (Volume 989)
• Pages: 192-198
• DOI: https://doi.org/10.4028/www.scientific.net/MSF.989.192
• Online since: May 2020
• Authors: Viacheslav E. Eremyashev*, Leyla M. Osipova, Ilya Shenderovich
• Keywords: Alkaline Earth Metals, Borosilicate Glass, Glass Structure, NMR

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