Microstructure and Mechanical Properties of the Alloy Mg61Cu28Gd11 in Submicrovolumes

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We studied the microstructure and nanomechanical properties of cast samples of the alloy Mg61Cu28Gd11, obtained by the original method. The alloy Mg61Cu28Cd11 is distinguished by a particularly high glass transition property. In this study samples with a diameter of 16 mm were obtained an inert atmosphere with a cooling rate of 1K/s. Liquid alloy Mg61Cu28Gd11 before crystallization was heated to 780 °C. It was previously installed that, with such heating, irreversible structural changes occur in the melt, which increase the tendency of the metal to glass transition. A metallographic study of the microstructure was performed using a scanning electron microscope and EDS-analysis. Nanohardness HV and Young's modulus E Mg2CuCd and Mg2Cu were measured using the nanoindentation method.The microstructure of the Mg61Cu28Cd11 alloy in the cast state consists mainly of Mg2Cu dendrites; the interdendritic space is represented by the Mg2CuCd phase. The presence of exogenous nonmetallic inclusions of a complex composition CdO + CuO + MgO was also established by the method of micro X-ray spectral analysis.Analysis of the measurement data of HV(GPa), E (GPa) gave a conclusion about the same degree of homogeneity of the mechanical properties of dendrites and interdendritic space.

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177-181

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May 2020

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[1] Q. Zheng, S. Cheng, J.H. Strader, E. Ma, J. Xu, Critical size and strength of the best bulk metallic glass former in the Mg-Cu-Gd ternary system, ScriptaMaterialia, 56(2) (2007) 161-164.

DOI: 10.1016/j.scriptamat.2006.09.023

Google Scholar

[2] Y.D. Sun, P. Shen, Z.Q. Li, J.S. Liu, M.Q. Cong, M. Jiang, Kinetics of crystallization process of Mg-Cu-Gd based bulk metallic glasses, Journal of Non-Crystalline Solids,358(8) (2012) 1120-1127.

DOI: 10.1016/j.jnoncrysol.2012.02.002

Google Scholar

[3] H. Men, D.H. Kim, Fabrication of ternary Mg-Cu-Gd bulk metallic glass with high glass-forming ability under air atmosphere, Journal of Materials Research,18(7) (2003) 1502-1504.

DOI: 10.1557/jmr.2003.0207

Google Scholar

[4] V. Konashkov, V. Vyukhin, V. Tsepelev, Viscosity and density of Co-B liquid fusions, 6th International Conference on Key Engineering Materials, ICKEM 2016; Hong Kong; China; 12-14 March 2016; Key Engineering Materials, 705 (2016) 209-213.

DOI: 10.4028/www.scientific.net/kem.705.209

Google Scholar

[5] P.S. Popel, O.A. Chikova, V.M. Matveev, Metastable colloidal states of liquid metallic solutions, High Temp. Mater. Proc. 14(4) (1995) 219-233.

DOI: 10.1515/htmp.1995.14.4.219

Google Scholar

[6] F.-Q.Zu, Temperature induced liquid-liquid transition in metallic melts: A brief review on the physical phenomenon, Metals,5(1)(2015) 395-417.

DOI: 10.3390/met5010395

Google Scholar

[7] Li J.Z. John, W.K. Rhim, C.P. Kim, K. Samwer, W.L. Johnson, Evidence for a liquid–liquid phase transition in metallic fluids observed by electrostatic levitation, Acta Materialia, 59 (2011) 2166–2171.

DOI: 10.1016/j.actamat.2010.12.017

Google Scholar

[8] Caiwei Wang, Lina Hu, Chen Wei, Xu Tong, Chao Zhou, Qijing Sun, Xidong Hui, Yuanzheng Yue Sub-Tg relaxation patterns in Cu-based metallic glasses far from equilibrium, The journal of chemical physics, 141(2014) 164507.

DOI: 10.1063/1.4898695

Google Scholar

[9] Chao Zhou, Lina Hu, Qijing Sun, Jingyu Qin, Xiufang Bian, Yuanzheng Yue Indication of liquid-liquid phase transition in CuZr-based melts, Appl. Phys. Lett., 103(2013) 171904.

DOI: 10.1063/1.4826487

Google Scholar

[10] V. Tsepelev, Y. Starodubtsev, V. Konashkov, Melt Viscosity of the Soft Magnetic Nanocrystalline Fe72.5Cu1Nb2Mo1.5Si14B9 Alloy.EPJ Web of Conferences. 16th International Conference on Liquid and Amorphous Metals (LAM), 151 (2017)UNSP 04006.

DOI: 10.1051/epjconf/201715104006

Google Scholar

[11] Nanohardness testers. NanoScan-4D. Specification 4271-049-48786949-2014.

Google Scholar

[12] W.C. Oliver, G.M. Pharr, An improved technique for determining hardness and elastic modulus using load and displacement sensing indentation experiments, J. Mater. Research, 7(6)(1992) 1564-1583.

DOI: 10.1557/jmr.1992.1564

Google Scholar

[13] I.I. Maslenikov, V.N. Reshetov, A.S. Useinov, Mapping the elastic modulus of a surface with a NanoScan 3D scanning microscope, Instruments and Experimental Techniques, 58(5) (2015) 711-717.

DOI: 10.1134/s0020441215040223

Google Scholar

[14] A. Useinov, K. Gogolinskiy, V. Reshetov, Mutual consistency of hardness testing at micro-and nanometer scales,International Journal of Materials Research, 100(7) (2009) 968-972.

DOI: 10.3139/146.110138

Google Scholar

[15] K.V. Gogolinskii, K.L. Gubskii, A.P. Kuznetsov, V.N. Reshetov, I.I. Maslenikov, S.S. Golubev, V.G. Lysenko, S.I. Rumyantsev, Investigation of the metrological characteristics of a scanning probe measuring microscope using TGZ type calibration gratings optophysical measurements, Measurement Techniques, 55(4) (2012) 400-405.

DOI: 10.1007/s11018-012-9972-4

Google Scholar

[16] L. Cheng, G. Chen, W. Zhao, Z.Z. Wang, Z.W. Zhang Correlation of the glass formation and phase selection of the Mg-Cu-Gd bulk metallic glass forming alloys, Journal of Non-Crystalline Solids, 472(2017) 61-64.

DOI: 10.1016/j.jnoncrysol.2017.07.015

Google Scholar

[17] F.H. Chen, K.F. Chang, C.Y.A. Tsao, M.L.T. Guo, J.C. Huang, J.S.C. Jang, Microstructures and mechanical behaviors of Mg58Cu31Gd11 and Mg65Cu25Gd10 amorphous alloys synthesized by injection casting and melt spinning, Journal of Alloys and Compounds, 483(1-2)(2009) 32-36.

DOI: 10.1016/j.jallcom.2008.08.101

Google Scholar

[18] Y.Li, D.Gu, Parametric analysis of thermal behavior during selective laser melting additive manufacturing of aluminum alloy powder, Materials and Design, 63(2014) 856-867.

DOI: 10.1016/j.matdes.2014.07.006

Google Scholar

[19] O.A. Chikova, P.L. Reznik, B.V. Ovsyannikov, Structure and nanomechanical characteristics of Al-Cu-Mg-Si alloy with partly liquated grain boundaries upon heat treatment Physics of Metals and Metallography, 117(12)(2016) 1245-1250.

DOI: 10.1134/s0031918x16120036

Google Scholar

[20] O.A. Chikova, A.B. Finkel'shtein, A.A. Shefer, Structure and Nanomechanical Properties of the Al–Si–Fe Alloy Produced by Blowing the Melt with Oxygen, Physics of Metals and Metallography, 119(7) (2018) 685-690.

DOI: 10.1134/s0031918x18070037

Google Scholar

[21] O.A. Chikova, E.V. Shishkina, A.N. Petrova, I.G. Brodova, Measuring the nanohardness of commercial submicrocrystalline aluminum alloys produced by dynamic pressing, Physics of Metals and Metallography, 115(5) (2014) 523-528.

DOI: 10.1134/s0031918x14050044

Google Scholar