Paper Titles

The Research and Simulation (Modelling) of the Destruction of a Single Abrasive Particle during Waterjet Cutting
p.235

Study of the Adhesion Strength of the Coating with Different Coating Methods to the Surface of Parts of «Shaft» Type
p.242

The Identification of the Mineralogical Composition of Converter Slags on the Basis of Testing and Diagnostics
p.248

Effect of Chemical Composition of Glassy Phase of Porcelain Stoneware on Product Brittleness
p.254

Effect of Hydrogen Absorption on the Composition of the Amorphous Alloys Surface Layers
p.260

Investigation of CaSO₄-KPO₃-Na₂B₄O₇ System as a Basis for Synthesis of Low-Melting Glasses Used as a Glass-Solder Material
p.265

The Influence of Temperature and Deformation Ratio on Structure Formation and Physico-Mechanical Properties of Powder Materials
p.270

Experimental and Numerical Investigation of the Catalytic Gas Carburization of Steel
p.276

The Study of the Complex Mechanical Properties of Rolled Bars of VT6 Alloy as a Function of Chemical Composition and Structure Type
p.283

HomeMaterials Science ForumMaterials Science Forum Vol. 989Effect of Hydrogen Absorption on the Composition...

Effect of Hydrogen Absorption on the Composition of the Amorphous Alloys Surface Layers

Article Preview

Abstract:

Hydrogen absorption leads to redistribution of the components of the surface layer of the amorphous alloy Fe_73.8Si_12.7B_9.4Nb_3.2Cu noncontact side, while the amorphous structure of this layer is preserved. The type of the micro-groups Fe_y Si_x changes in such a way that the ratio y: x decreases (to less than 1) and the chemical bond polarity decreases, as well. After degassing, the surface layer composition becomes similar to those before hydrogenation. The loss of the mechanical stability of the amorphous ribbon is accompanied by the formation of the micro-groups Fe_y Si_x with a decreased ratio of y: x.

You might also be interested in these eBooks

Materials Science and Metallurgical Technology II

Info:

Periodical:

Materials Science Forum (Volume 989)

Pages:

260-264

DOI:

https://doi.org/10.4028/www.scientific.net/MSF.989.260

Citation:

Cite this paper

Online since:

May 2020

Authors:

V.I. Lad’yanov, N.E. Skryabina, Olga M. Kanunnikova*

Keywords:

Amorphous Alloys, Hydrogen, Surface Layer, XPS

Export:

RIS, BibTeX

Price:

Permissions CCC:

Request Permissions

Permissions PLS:

Request Permissions

Сopyright:

© 2020 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

* - Corresponding Author

[1] G.G. Libowitz, A.J. Maeland, Interactions of hydrogen with metallic glass alloys, J. Less Common Met. 101(1984) 131-143.

DOI: 10.1016/0022-5088(84)90091-2

[2] A.J. Maeland, Hydrogen in crystalline and non-crystalline metals and alloys: similarities and differences in: Rapidly Quenched Metals, ed. by S. Steub and H. Warlimont (Elsevier, Amsterdam, 1985) 1507-1514.

[3] V.V. Roschupkin et al. in Thermophysics in condensed media. Ed. by I.I. Novikov, Moscow, Nauka, (1995).

[4] U. Koster, H. Schroeder, in Glass - Current Issues (Proc. NATO ASI, Ser. E, No. 92, Eds A F Wright, J Dupuy) (Dordrecht: Martinus Nÿhoff Publ., 1985), (1986).

[5] L.V. Spivak, N.Ye. Skryabina, Effect of hydrogen on the properties of amorphous alloys finemet, type: PEN-X effect. International Journal of Hydrogen Energy, 24(1999) 795-799.

DOI: 10.1016/s0360-3199(98)00148-7

[6] L.V. Spivak, V.A. Khonik, N.Ye. Skryabina, et al., Hydrogen induced deformation of amorphous alloys, Letters in Journal of Technical Physics, 19(17) (1993) 39-43.

[7] L.V. Spivak, Synergy effects in the deformation response of thermodynamically open metal hydrogen systems, Uspekhi Fizicheskikh Nauk, 178(2008) 897–922.

DOI: 10.1070/pu2008v051n09abeh006506

[8] W.J. Botta, J.E. Berger, C.S. Kiminami, V. Roche, R.P. Nogueira, C. Bolfarini, Corrosion resistance of Fe-based amorphous alloys, J. Alloys Compd. 586(2014) S105-S110.

DOI: 10.1016/j.jallcom.2012.12.130

[9] K. Mondal, U.K. Chatterjee, B.S. Murty, Surface oxides and their effect on the oxidation behavior of amorphous and nanoquasicrystalline Zr–Pd and Zr–Pt alloys, J. Mater. Res. 21(2006) 639-646.

DOI: 10.1557/jmr.2006.0084

[10] N.A. Skulkina, O.A. Ivanov, I.O. Pavlova, Interaction of the surface of ribbons of amorphous soft-magnetic iron-based alloys with water and their magnetic properties, Phys. Metal. Metall. 112(2011) 457-465.

DOI: 10.1134/s0031918x11050292

[11] F.Z. Gilmutdinov, O.M. Kanunnikova, Prediction of changes in the composition of the surface of multicomponent alloys under thermal conditions, Phys. Metal. Metall. 84(2) (1997) 78-88.

[12] H.M. Naguib, R. Kelly, Criteria for bombardment-induced structural changes in non-metallic solids. Radiat. Eff. 25(1975) 1-12.

DOI: 10.1080/00337577508242047

[13] P.H. Holloway, P. Bhattacharia, Limitation of ion etching for interface analysis, Surf. Interface Anal. 3 (No3) (1981), 118-125.

DOI: 10.1002/sia.740030305

[14] R. Kelly, On the problem of whether mass of chemical bonding is more important to bombardment-induced compositional changes in alloys and oxide, Surf. Sci. 100 (1980), 85-107.

DOI: 10.1016/0039-6028(80)90446-x

[15] G.K. Wolf, Chemical effects of ion bombardment, Instr. Inorg. Chem. 85 (1979), 1-88.

[16] S. Hoffmann, Quantitative depth profiling in surface analysis: a review, Surf. Interface Anal. 2(4) (1988) 148-160.

[17] О.М. Kanunnikova, О.Yu. Goncharov, V.I. Ladyanov, Assessment of the structural state of the amorphous alloys thin surface layers, Mater. Sci. Forum, 946(2019) 174-181.

DOI: 10.4028/www.scientific.net/msf.946.174

[18] О.М. Kanunnikova, N.Ye. Skryabina, F.Z. Gilmutdinov, A.S. Petrov, V.Ya. Bayankin, The segregation processe in the surface layers of amorphous alloy Fe73.8Si12.7B9.4Nb3.2Cu as a result of electrolytic hydrogen absorption, Bull. Univers. Non-ferrous metallurgy. 4 (2000) 57-59.