Peculiar Properties of Temperature Modification of Carbonate Precipitate

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The carbonate precipitate of sugar production from sugar beet is a large-tonnage organic waste, the disposal of which is a significant problem for many agricultural regions. According to studies, the temperature of maximum combustion is 506.1 ° С for carbonate precipitate, the carbon content in TMCP600 was about 2%, CaCO3 94-95%, sand and clay impurities 3-4%. The presence of multiple bonds (modifications C8, C70 and C80) in carbon layer of TMCP600 particles is confirmed by studies of the IR spectrum and the interaction with iodine water. The internal structure of the carbon layer formed is similar to traditional carbon sorbents, such as KAD grade activated carbon. With increasing roasting temperature of a carbonate precipitate, the pH of the aqueous extract increases, which confirms the process of decomposition of the calcium salts of carboxylic acids. The specific surface area of ​​the sorption material, measured by the method of low-temperature nitrogen adsorption, was 82 ± 0.2 m2/ g.

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May 2020

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[1] I.G. Shaikhiev, K.I. Shaikhieva, Using coniferous tree components to remove pollutants from aquatic environments. 8. Araucaria, Bulletin of the technological university. 20(10) (2017) 152-154.

Google Scholar

[2] I.G. Shaikhiev, The use of components of the trees of the genus Quercus as sorption materials for the removal of pollutants from water. Literature Review, Bulletin of the Technological University. V20, №5 (2017) 151-160.

Google Scholar

[3] Zh.A. Sapronova, S.V. Sverguzova, A.V. Svyatchenko. The role of natural hydrophobicity of plants in the purification of oil-containing emulsions,Water: chemistry and ecology. 7 (2018) 85-91.

Google Scholar

[4] I.G. Shaikhiev, Thoa Nguyen Thi Kim, K.I. Shaikhieva. Use of Acacia tree species to remove pollutants from natural and waste water. 1. Heavy metal ions, Bulletin of the technological university. V. 20, No. 3 (2017) 171-179.

Google Scholar

[5] A.Tanweer, R. Mond, G. Arniza, S. Othman, H. Rokiah. Oil Palm Biomass–Based Adsorbents for the Removal of Water Pollutants—A Review,/ Journal of Environmental Science and Health, Part C. Vol 29. №3 (2011) 177-222.

DOI: 10.1080/10590501.2011.601847

Google Scholar

[6] H.I. Kelle, A.N. Eboatu, O. Ofoegbu, I.P. Udeozo. Determination of agricultural land waste; corncob as an oil spill sorbent mop, IOSR Journal of Applied Chemistry. Vol. 6. Is. 2 (2013) 30-57.

DOI: 10.9790/5736-0623057

Google Scholar

[7] Zh. Sapronova, S. Sverguzova, K. Sulim, A. Svyatchenko and E. Chebotaeva. Sewage treatment in megacities by modified chestnut tree waste, IOP Conf. Series: Materials Science and Engineering. 365 (2018). 022058.

DOI: 10.1088/1757-899x/365/2/022058

Google Scholar

[8] O.A. Galblaub, I.G. Shaikhiev, S.V. Stepanova, G.R. Timirbaeva. Oil spill cleanup of water surface by plant-based sorbents: Russian practices, /Process Safety and Environmental Protection. Vol. 101 (2016) 88–92.

DOI: 10.1016/j.psep.2015.11.002

Google Scholar

[9] T.M. Al Khusaibi, J.J. Dumaran, M.G. Devi, L.N. Rao, S. Feroz. Treatment of dairy wastewater using orange and banana peels, Journal of Chemical and Pharmaceutical Research. 7(4) (2015) 1385-1391.

Google Scholar

[10] M. Sillanpaa, Sh. Khan, K. Kamwilaisak, Sh. Wang, W.Z. Tang, Synthesis of sorbents from industrial solid wastes (ALD), Mine water and circular economy: 13th international mine association, Pauna, Lappeenranta-Finland. (2017) 43-54.

Google Scholar

[11] Zh.A. Sapronova, M.ZH. Gomez. Evaluation of the reagent properties of clays from the Kateti, Bulletin of BSTU named after V.G. Shukhov. 1 (2014) 164-167.

Google Scholar

[12] Maebh A. Grace, E. Clifford, G. Mark. The potential for the use of waste products from a variety of sectors in water treatment processes, Healy Journal of Cleaner Production. 13 (2016) 788-802.

DOI: 10.1016/j.jclepro.2016.07.113

Google Scholar

[13] L.А. Nikolaev, E.N. Boroday, M.A. Golubchikov. Sorption properties of clarifiers sludge in wastewater treatment of power plants from petroleum products, News of higher educational institutions. Energy problems. 1-2 (2011) 132-136.

Google Scholar

[14] I.V. Starostina, A.E. Nikitina, E.V. Porozhnyuk. Magnetic Petroleum Sorbent Based on Waste Kieselghur Sludge from Oil Extraction Industry for Removing Petroleum Products from Water Surface, Solid State Phenomena, 284 (2018) 754-760.

DOI: 10.4028/www.scientific.net/ssp.284.754

Google Scholar

[15] I.V. Starostina, D.V. Stolyarov, Ya. N. Anichina, E.V. Porozhnyuk. The carbonaceous sorbent based on the secondary silica-containing material from oil extraction industry, IOP Conference Series Earth and Environmental Science, 107(1) (2018) 012075.

DOI: 10.1088/1755-1315/107/1/012075

Google Scholar

[16] V. A. Nikashina P. A. Gembitskii E. M. Kats. Organomineral sorbents based on clinoptilolite-containing tuffs - 2. Study of ion-exchange and technological properties of organomineral sorbents Russian Chemical Bulletin, 43(9):1466-1468.

DOI: 10.1007/bf00697127

Google Scholar

[17] Elżbieta Vogt,Wiktor Pacura. Hydrophobization of bleaching clay used for purification of waste frying oils, IOP Conference Series Earth and Environmental Science, (2019)214:012009.

DOI: 10.1088/1755-1315/214/1/012009

Google Scholar

[18] Zh. A. Sapronova, S.V. Svergusova, E.V. Fomina, Nanocomposite carbon-bearing sorption material, Advances in Engineering Research, 133 (2017) 728-733.

Google Scholar

[19] Zh.A. Sapronova, S.V. Sverguzova, A.V. Svyatchenko, About a possibility of usage of sugar beet industrial carbonate containing byproducts in dry construction mixtures and oil paints manufacturing solid state phenomena, 284 (2018) 899-904.

DOI: 10.4028/www.scientific.net/ssp.284.899

Google Scholar

[20] G. Vaccaria, E. Tamburinia, G. Sgualdinoa, K. Urbaniecb, J. Klemesˇc. Overview of the environmental problems in beetsugar processing: possible solutions, Journal of Cleaner Production 13 (2005) 499e507.

Google Scholar

[21] A. Ippolito, D. G. Strawn, and K. G. Scheckel. Investigation of Copper Sorption by Sugar Beet Processing Lime Waste. J. Environ. Qual. (2013) 42:919–924.

DOI: 10.2134/jeq2013.01.0004

Google Scholar

[22] A.Kh. Kuptsov, G.N. Lunch. Fourier spectra of combination scattering and infrared absorption Fizmatlit, Moscow, (2001).

Google Scholar