Piperazinediium Diselenatohexaaquacobaltate(II) Dihydrate (C₄H₁₂N₂)[Co(SeO₄)₂(H₂O)₄]·2H₂O

Abstract:

The new hybrid material, (C₄H₁₂N₂)[Co(H₂O)₄(SeO₄)₂]·2H₂O, has been synthesized by the slow evaporation method at room temperature and crystallographically characterized. It crystallizes in the monoclinic system, space group P21 /n. The crystal structure of this compound consists of transition metal, Co(II), octahedrally coordinated by four water molecules and two selenate groups forming the [Co(H₂O)₄(SeO₄)₂]^2- anions, water molecules and piperazinediium cations (C₄H₁₂N₂)²⁺ linked together by two types of hydrogen bonds, OW–H…O and N–H…O.

• Periodical: Solid State Phenomena (Volume 194)
• Pages: 171-174
• DOI: https://doi.org/10.4028/www.scientific.net/SSP.194.171
• Online since: November 2012
• Authors: Nouha Loulou Nkhili, Walid Rekik, Houcine Naili, Tahar Mhiri, Thierry Bataille
• Keywords: Crystal Structure, Hybrid Material, Hydrogen Bonds, Magnetic Property, Slow Evaporation, Thermal Decomposition

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