Tungsten Carbide Decarburization by Electrical Discharges

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Abstract:

Electrospark deposition (ESD) was employed to clad WC-10%Co hard alloy on steel 1035 and the tribological properties of the coatings obtained were examined. The influence of the duration and frequency of discharges, the nature of the environment, and the carbon concentration in the electrode materials on the decarburization of tungsten carbide was studied. It is shown that the degree of tungsten carbide degradation can be reduced by decreasing the discharge frequency and increasing the concentration of carbon in the WC-Co electrode materials and also that the WC decarburization reaction is reversible on annealing.

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Solid State Phenomena (Volume 213)

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131-136

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March 2014

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© 2014 Trans Tech Publications Ltd. All Rights Reserved

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[1] X. -Q. Zhao, H. -D. Zhou, J. -M. Chen, Comparative study of the friction and wear behavior of plasma sprayed conventional and nanostructured WC–12%Co coatings on stainless steel, Mater. Sci. Eng. A. 431 (2006) 290–297.

DOI: 10.1016/j.msea.2006.06.009

Google Scholar

[2] E.I. Zamulaeva, E.A. Levashov, A.E. Kudryashov, P.V. Vakaev, M.I. Petrzhik, Electrospark coatings deposited onto an Armco iron substrate with nano- and microstructured WC–Co electrodes: Deposition process, structure, and properties, Surf. Coat. Technol. 202 (2008).

DOI: 10.1016/j.surfcoat.2008.01.008

Google Scholar

[3] M. Guilemany, S. Dosta, J. Nin, J.R. Miguel, Study of the Properties of WC-Co Nanostructured Coatings Sprayed by High-Velocity Oxyfuel, J. Therm. Spray Technol. 14 (2005) 405–413.

DOI: 10.31399/asm.cp.itsc2005p0530

Google Scholar

[4] Q. Yang, T. Senda, A. Ohmori, Effect of carbide grain size on microstructure and sliding wear behavior of HVOF-sprayed WC-12% Co coatings, Wear. 254 (2003) 23–34.

DOI: 10.1016/s0043-1648(02)00294-6

Google Scholar

[5] M. Jalali Azizpour, S. Norouzi, H. Mohammadi Majd, H. Talebi, A. Ghamari, Application of HVOF Thermal Spraying in High Speed Gas Compressor Shafts, Sci., Eng. Technol. 69 (2010) 360–362.

Google Scholar

[6] J. Liu, R. Wang, Y. Qian, Formation of a single-pulse electrospark deposition spot, Surf. Coat. Technol. 200 (2005) 2433–2437.

DOI: 10.1016/j.surfcoat.2004.07.104

Google Scholar

[7] J. Wang, H. Meng, H. Yu, Z. Fan, D. Sun, Wear. Characteristics of Spheroidal Graphite Roll WC-8Co. Coating Produced by Electro-Spark Deposition, Rare Met. 29 (2) (2010) 174–179.

DOI: 10.1007/s12598-010-0030-6

Google Scholar

[8] V.S. Panov, A.M. Chuvilin, Technology and properties of sintered hard alloys, MISA, Moscow, 2001, p.452 (in Russian).

Google Scholar

[9] Y. Kusano, K V. Acker, I.M. Hutchings, Methods of data analysis for the micro-scale abrasion test on coated substrates, Surf. Coat. Technol. 183 (2004) 312–327.

DOI: 10.1016/j.surfcoat.2003.10.010

Google Scholar

[10] W. Żórawski, The microstructure and tribological properties of liquid-fuel HVOF sprayed nanostructured WC–12Co coatings, Surf. Coat. Technol. 220 (2013) 276–281.

DOI: 10.1016/j.surfcoat.2012.11.007

Google Scholar

[11] C. Bartuli, T. Valente, F. Cipri, E. Bemporad, M. Tului, Parametric study of an HVOF process for the deposition of nanostructured WC-Co coatings, J. Therm. Spray Technol. 14 (2005) 187–195.

DOI: 10.1361/10599630523746

Google Scholar

[12] M. Wang, R. Pan, S. Li, X. Lei. Effect of freezing point and surface roughness on coating by electro-spark deposition, Proc. 2012 Int. Conf. Mechanical Engineering and Material Science (MEMS 2012), Atlantis Press, p.21–24.

DOI: 10.2991/mems.2012.7

Google Scholar

[13] T. Sudaprasert, P.H. Shipway, D.G. McCartney, Sliding wear behaviour of HVOF sprayed WC–Co coatings deposited with both gas-fuelled and liquid-fuelled systems, Wear 255 (2003) 943–949.

DOI: 10.1016/s0043-1648(03)00293-x

Google Scholar