Features of the Magnesium Alloys Corrosion in the Chloride-Containing Media

Abstract:

A greater corrosion stability of the MA8 (Mg-Mn-Се) alloy as compared to that of VMD10 (Mg-Zn-Zr-Y) magnesium alloy in the chloride-containing solution has been demonstrated using the scanning vibrating probe method (SVP) as well as the methods of optical microscopy, gravimetry and volumetry. It has been established that the crucial factor of the corrosion activity of the samples under study consists in the occurrence of the micro galvanic couples at the samples surface. MA8 alloy contains less amount of the secondary phases (cathodic parts) relative to VMD10. The corrosion rate of the samples with coatings formed by the plasma electrolytic oxidation (PEO) method and composite polymer-containing coatings at the surface of various magnesium alloys has been measured. It has established, that PEO-coating decrease the values of the corrosion rate in several times (more than one order of magnitude for MA8 and more than 2 times for VMD10) in comparison with bare alloys.

• Periodical: Solid State Phenomena (Volume 213)
• Pages: 143-148
• DOI: https://doi.org/10.4028/www.scientific.net/SSP.213.143
• Online since: March 2014
• Authors: Andrey S. Gnedenkov*, Sergey L. Sinebryukhov, Dmitry V. Mashtalyar, Sergey V. Gnedenkov
• Keywords: Corrosion Rate, Electrochemistry, Gravimetry, Magnesium Alloy, Scanning Vibrating Probe Technique, Volumetry

References

[1] S.L. Sinebryukhov, A.S. Gnedenkov, D.V. Mashtalyar, S.V. Gnedenkov, Surf. Coat. Technol. 205 (2010) 1697-1701.

DOI: 10.1016/j.surfcoat.2010.05.048

[2] A.S. Gnedenkov, S.L. Sinebryukhov, D.V. Mashtalyar, S.V. Gnedenkov, Physics Procedia 23 (2012) 98-101.

DOI: 10.1016/j.phpro.2012.01.025

[3] G. Song, A. Atrens, Adv. Eng. Mater. 5 (2003) 837-858.

[4] G. Williams, R. Grace, Electrochim. Acta 56 (2011) 1894-(1903).