High Anionic Conductivity of Solids with Different Structure

Anatoly B. Podgorbunsky; Sergey L. Sinebryukhov; Sergey V. Gnedenkov

doi:10.4028/www.scientific.net/SSP.213.200

Paper Titles

Protective Properties of the Nanocomposite Coatings on Mg Alloy
p.176

Study of Biopolymer Chitosan as Resist for Submicron Electronic Lithography
p.180

Photodynamic Effects in Nanocomposites Based on Quantum Dots of Cadmium Sulfide Embedded in a Silicate Matrix, in their Interaction with the Laser Beam
p.186

Сurrent Source Based on Photoelectric Effect with Enhanced Efficiency
p.192

High Anionic Conductivity of Solids with Different Structure
p.200

Near-Field Optical Probe Based on the Fiber Fabry-Perot Interferometer with Protruding Evanescent Light Source
p.204

Optical Dielectric Apertureless Probe for Surface Laser Modification with λ/15 Lateral Resolution
p.210

The Structural Characteristics Features of the Nanocomposite Systems of CdS Quantum Dots in the Gel Matrix Obtained by the Method of Small-Angle X-Ray Scattering
p.216

Nonlinear Optics with Backward Waves: Extraordinary Features, Materials and Applications
p.222

HomeSolid State PhenomenaSolid State Phenomena Vol. 213High Anionic Conductivity of Solids with Different...

High Anionic Conductivity of Solids with Different Structure

Abstract:

Impedance spectroscopy data for a several materials with high ionic conductivity at the intermediate temperature range (296-473 K) were obtained and analyzed. Investigated systems including pure CsSb₂F₇, KSb₂F₇, related solid solutions Cs_(1-x)K_xSb₂F₇ (0.1≤x≤0.65) and some ionic materials with fluorite structure PbF₂-BiF₃-K[Na]F were studied. The values of the dc conductivity and activation energies are estimated from the analysis of the conductivity spectra. The role of cation substitution influencing on conductivity values, phase transitions and activation energies in the given systems have been discussed.

You might also be interested in these eBooks

Physics and Technology of Nanostructured Materials II

View Preview

Info:

Periodical:

Solid State Phenomena (Volume 213)

Pages:

200-203

DOI:

https://doi.org/10.4028/www.scientific.net/SSP.213.200

Citation:

Cite this paper

Online since:

March 2014

Authors:

Anatoly B. Podgorbunsky, Sergey L. Sinebryukhov, Sergey V. Gnedenkov

Keywords:

Anion Conductivity, Fluorine Materials, Impedance Spectroscopy, Superionic Conductors

Export:

RIS, BibTeX

Price:

Permissions CCC:

Request Permissions

Permissions PLS:

Request Permissions

Сopyright:

Citation:

References

[1] U.Y. Gurevich, Solid electrolytes. Nauka, Moskow, 1986 [in russian].

Google Scholar

[2] A.K. Ivanov-Schitz, I.V. Murin, Solid State Ionics, vol. 2, SPb University press, 2010 [in russian].

Google Scholar

[3] C. Lucat, A. Rhandour, J.M. Reau, J. Portier, P. Hagenmuller, Fast ionic conduction of fluorides with the fluorite-type structure, J. Solid State Chem. 29 (1979).

DOI: 10.1016/0022-4596(79)90194-4

Google Scholar

[4] V. Ya. Kavun, A.I. Ryabov, I.A. Telin, A.B. Podgorbunskiy, S.L. Sinebrukhov, S.V. Gnedekov, V.K. Goncharuk, Ionic mobility and conductivity in PbSnF4 doped alkali metal fluoride – obtained by NMR and Impedance spectroscopy, J. Struct. Chem. 53 (2012).

DOI: 10.1134/s0022476612020126

Google Scholar

[5] N.F. Uvarov, E.F. Hairetdinov, J.M. Réau et al., Determination of the influence of the NaF rate on the charge carriers parameters in some fluoride glasses containing the NaF alkali fluoride, Solid State Ionics. 74 (1994) 195–204.

DOI: 10.1016/0167-2738(94)90210-0

Google Scholar

[6] V. Ya. Kavun, L.A. Zemnukhova, A.I. Ryabov, A.B. Podgorbunskiy, S.V. Gnedekov, S.L. Sinebrukhov, V.I. Sergienko, Ionic mobility, phase transitions and electroconductivity data of the crystalline phases in KF–CsF–SbF3-H2O system obtained using NMR and impedance spectroscopy, Russ. J. Electrochem. 48 (2012).

DOI: 10.1134/s1023193512010090

Google Scholar

[7] V. Ya. Kavun, V.I. Sergienko, Diffusive mobility and ionic transport in the crystal and amorphous fluorides of IV groups elements and antimony(III). Vladivostok: Dalnauka, 2004 [in russian].

Google Scholar