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HomeSolid State PhenomenaSolid State Phenomena Vol. 247Dielectric Studies of Ammonium Hydrogen Sulphate...

Dielectric Studies of Ammonium Hydrogen Sulphate (NH₄HSO₄), Embedded into Molecular Sieves SBA-15

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Abstract:

Temperature dependencies of linear dielectric permittivity and third harmonic coefficient of nanoporous matrices SBA-15 with channel pore size of 7,5 nm filled with ferroelectric NH₄HSO₄ compared to bulk ammonium hydrogen sulphate were studied. The measurements were performed in a heating and cooling mode with a temperature range from 100 K to room temperature. Low-temperature phase transition shift of 7-8 degrees to low temperatures was found for nanostructured ammonium hydrogen sulphate compared to bulk NH₄HSO₄. The experimental data were treated within the framework of the models developed for isolated small ferroelectric particles and arrays of coupled particles. The rise of the space charge polarization effects was also observed.

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Periodical:

Solid State Phenomena (Volume 247)

Pages:

85-90

DOI:

https://doi.org/10.4028/www.scientific.net/SSP.247.85

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Online since:

March 2016

Authors:

Alexey Milinskiy, Anton Anatolеvich Antonov, Sergey Vasilevich Baryshnikov

Keywords:

Ammonium Hydrogen Sulphate, Ferroelectrics, Mesoporous Matrices, Phase Transition, Third Harmonic Coefficient

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© 2016 Trans Tech Publications Ltd. All Rights Reserved

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