Paper Titles

Microstructure and Tempering Behaviour of 28Cr-2.5C-1W Cast Irons
p.116

Morphology of Bi₂O₃ Nanowires and Nanoflowers in the Synthesis of MnBi Alloys
p.124

Physical, Dielectric Properties and Micro-Hardness of the (Ba_0.90Ca_0.10)_0.90(Na_0.50Bi_0.50)_0.10TiO₃ Ceramics Prepared by Molten Salt Method
p.132

Plant-Derived Polyphenols as Potential Cross-Linking Agents for Methylcellulose-Chitosan Biocomposites
p.140

Structure and Electrical Properties of BNKT-Based Ceramics
p.147

Synthesis of Copper Oxide Nanopowder by Microwave Method
p.154

The Effect of Lithium on Crystallization and Microstructure of Glass-Ceramics in Soda-Lime Silicate System
p.160

Titanium Dioxide Doped with Nitrogen Nanopowder Prepared by Hydrothermal Method
p.167

Surface Hardening of Stainless Steel by Coating Graphene Using Thermal Chemical Vapor Deposition
p.173

HomeSolid State PhenomenaSolid State Phenomena Vol. 283Synthesis of Copper Oxide Nanopowder by Microwave...

Synthesis of Copper Oxide Nanopowder by Microwave Method

Article Preview

Abstract:

Copper oxide nanopowder was successfully synthesized by microwave method. Copper acetate and sodium hydroxide were used as the starting precursors. The microwave power was set to 800 Watt for 2-6 min and fine black nanopowder was obtained. The nanopowder was milled and dried at 80 °C for 12 h. The structure was identified by X-ray diffractometer (XRD). A monoclinic single phase of CuO nanopowder structure was obtained without calcination steps. The morphology was investigated by scanning electron microscope (FESEM). The particle was irregular in shape and agglomerated. The chemical composition was determined by energy dispersive X-ray spectrometer (EDXS). The chemical compositions showed the characteristic X-ray energy of copper (K_α=8.048 keV) and oxygen (K_α=0.525 keV), respectively. The functional group was investigated by fourier transform infrared spectrometer (FTIR). The functional groups of the vibration Cu-O bending showed the wavenumber at 491-615 cm^-1.

You might also be interested in these eBooks

Microscopy in the Field of Materials Research

Info:

Periodical:

Solid State Phenomena (Volume 283)

Pages:

154-159

DOI:

https://doi.org/10.4028/www.scientific.net/SSP.283.154

Citation:

Cite this paper

Online since:

September 2018

Authors:

Pusit Pookmanee, Pimpaka Sangthep*, Jiratchaya Tafun, Viruntachar Kruefu, Suchanya Kojinok, Sukon Phanichphant

Keywords:

Copper Oxide, Microwave Method

Export:

RIS, BibTeX

Price:

Permissions CCC:

Request Permissions

Permissions PLS:

Request Permissions

Сopyright:

© 2018 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

* - Corresponding Author

[1] T.H. Tran, V.T. Nguyen, Copper oxide nanomaterials prepared by solution methods, Some Properties, and potential applications: A Brief Review. Hindawi Publishing corporation international scholarly research notices. 2014 (2014) 1-14.

DOI: 10.1155/2014/856592

[2] Y. Yecheskel, I. Dror, B. Berkowitz, Catalytic degradation of brominated flame retardants by copper oxide nanoparticles, Chemosphere 93 (2012) 172–177.

DOI: 10.1016/j.chemosphere.2013.05.026

[3] A. Aslani, V. Oroojpour, CO gas sensing of CuO nanostructures, synthesized by an assisted solvothermal wet chemical route, Physica B. 406 (2011) 144-149.

DOI: 10.1016/j.physb.2010.09.038

[4] Y. Li, J. Liang, Z. Tao, J. Chen, CuO particles and plates: synthesis and gas-sensor application, Mater. Res. Bull. 43 (2008) 2380-2385.

DOI: 10.1016/j.materresbull.2007.07.045

[5] X. Wang and X. Xu, Thermal conductivity of nanoparticle-fluid mixture, J. Thermophys. Heat Tr. 13, (1999) 474–480.

[6] S. Ishio, T. Narisawa, S. Takahashi, Y. Kamata, S. Shibata, T. Hasegawa, Z. Yan, X. Liu, H. Yamane, Y. Kondo, J. Ariake, L10 FePt thin films with [001] crystalline growth fabricated by SiO2 addition-rapid thermal annealing and dot patterning of the films, J. Magn. Magn. Mater. 324 (2012) 295–302.

DOI: 10.1016/j.jmmm.2010.12.014

[7] V. Kumar, S. M-Panah, C.C. Tan, T.K.S. Wong, D.Z. Chi, G.K. Dalapati, Copper oxide based low cost thin film solar cells, in Proceedings of the IEEE 5th International Nanoelectronics Conference (INEC '13). (2013) 443-445.

DOI: 10.1109/inec.2013.6466072

[8] C. Ma, L. Zhu, S. Chen, Y. Zhao, Simple and rapid preparation of CuO nanowires and their optical properties, Mater. Lett. 108 (2013) 114˗117.

DOI: 10.1016/j.matlet.2013.06.101

[9] Y. Xu, D. Chen, X. Jiao, Fabrication of CuO pricky microspheres with tunable size by a simple solution route, J. Phys. Chem. B. 109 (2005) 13561˗13566.

DOI: 10.1021/jp051577b

[10] N. Ba, L. Zhu, H. Li, G. Zhang, J. Li, J. Sun, 3D rod-like copper oxide with nanowire hierarchical structure: Ultrasound assisted synthesis from Cu2(OH)3NO3 precursor, optical properties and formation mechanism, Solid State Sci. 53 (2016) 23˗29.

DOI: 10.1016/j.solidstatesciences.2016.01.004

[11] S. Cho, Optical, electrical properties of CuO thin films deposited at several growth temperatures by reactive RF magnetron sputtering, Met. Mater. Int. 19 (2013) 1327˗1331.

DOI: 10.1007/s12540-013-6030-y

[12] X.-D. Yang, L.-L. Jiang, C.-J. Mao, H.-L. Niu, J.-M. Song, S.-Y. Zhang, Sonochemical synthesis and nonlinear optical property of CuO hierarchical superstructures, Mater. Lett. 115 (2014) 121–124.

DOI: 10.1016/j.matlet.2013.10.037

[13] M.A. Dar, Q. Ahsanulhaq, Y.S. Kim, J.M. Sohn, W.B. Kim, H.S. Shin, Versatile synthesis of rectangular shaped nanobat-like CuO nanostructures by hydrothermal method; structural properties and growth mechanism, Appl. Surf. Sci. 255 (2009).

DOI: 10.1016/j.apsusc.2009.02.002

[14] B. Toboonsung, P. Singjai, Formation of CuO nanorods and their bundles by an electrochemical dissolution and deposition process, J. Alloy. Compd. 509 (2011) 4132–4137.

DOI: 10.1016/j.jallcom.2010.12.180

[15] K. Han, M. Tao, Electrochemically deposited p-n homojunction cuprous oxide solar cells, Sol. Energy. Mat. Sol. Cells. 93 (2009) 153–157.

DOI: 10.1016/j.solmat.2008.09.023

[16] W.-W. Wang, Y.-J. Zhu, G.-F. Cheng, Y.-H. Huang, Microwave-assisted synthesis of cupric oxide nanosheets and nanowhiskers, Mater. Lett. 60 (2006) 609˗612.

DOI: 10.1016/j.matlet.2005.09.056

[17] X. Xu, M. Zhang, J. Feng, M. Zhang, Shape-controlled synthesis of single-crystalline cupric oxide by microwave heating using an ionic liquid, Mater. Lett. 62 (2008) 2787˗2790.

DOI: 10.1016/j.matlet.2008.01.046

[18] L. Guo, F. Tong, H. Liu, H. Yang, J. Li, Shape-controlled synthesis of self-assembly cubic CuO nanostructures by microwave, Mater. Lett. 71 (2012) 32–35.

DOI: 10.1016/j.matlet.2011.11.105

[19] S.K. Sharma, R. Ghose, Synthesis of nanocrystalline copper oxide with dandelion-like morphology by homogeneous precipitation method, J. Mol. Struct. 1076 (2014) 651–657.

DOI: 10.1016/j.molstruc.2014.07.064

[20] R.A. Kӧppel, C. Stӧcker, A. Baiker, Copper-and silver-zirconia aerogels: Preparation, structural properties and catalytic behaviour in methanol synthesis from carbon dioxide, J. Catal. 179 (1998) 515–527.

DOI: 10.1006/jcat.1998.2252

[21] T. Yu, X. Zhao, Z.X. Shen, Y.H. Wu, W.H. Su, Investigation of individual CuO nanorods by polarized micro-Raman scattering, J. Cryst. Growth. 268 (2004) 590–595.

DOI: 10.1016/j.jcrysgro.2004.04.097

[22] G. Varughese, V. Rini, S.P. Suraj, K.T. Usha, Characterisation and optical studies of copper oxide nanostructures doped with lanthanum ions, Advances in materials science 14 (2014) 49-60.

DOI: 10.2478/adms-2014-0021

[23] B. Lefez, R. Souchet, K. Kartouni, M. Lenglet, Infrared reflection study of CuO in thin oxide films, Thin Solid Films. 268 (1995) 45–48.

DOI: 10.1016/0040-6090(95)06872-4