Paper Titles

The Conditions and Results of Ferrite Based on Multicomponent Crystal Formation in High Entropic Oxide Systems
p.246

Ceramic Bricks of Semi-Dry Pressing with the Use of Fusible Loams and Non-Traditional Mineral Raw Materials
p.252

The Use of Hard Alloy Waste in Composite Galvanic Coatings for the Restoration of Car Parts
p.258

Regulation of Electrical, Thermal and Physical Properties of Composites Based on Carbon-Modified Portland Cement Materials
p.264

Simple Universal Kelvin Equation Valid in Critical Point Vicinity, External-Internal State Correction, and their Application in Understanding of Oxygen Capillary Evaporation and Condensation in Mesoporous Silica MCM-41
p.270

Preparation of Poly-Substituted Crystals with M-Type Hexa-Ferrite Structure Using Melts of the BaO-PbO-SrO-CaO-ZnO-Fe₂O₃-Mn₂O₃-Al₂O₃ System
p.275

Thermal Stability of Nano-Crystalline Nickel Electrodeposited into Porous Alumina
p.281

Heat-Resistant Composite Materials Based on Secondary Material Resources
p.287

Production of Foam Glass Materials from Silicate Raw Materials by Hydrate Mechanism
p.293

HomeSolid State PhenomenaSolid State Phenomena Vol. 299Simple Universal Kelvin Equation Valid in Critical...

Simple Universal Kelvin Equation Valid in Critical Point Vicinity, External-Internal State Correction, and their Application in Understanding of Oxygen Capillary Evaporation and Condensation in Mesoporous Silica MCM-41

Article Preview

Abstract:

A new simple universal form of the Kelvin equation, which can be used near the gas-liquid phase transition critical point, and the correction of the pressure and density for gas phase fluid outside the porous medium are taken into account for the oxygen meniscus effective curvature radius calculation at the phase equilibrium in mesoporous silica MCM-41, on the basis of the capillary evaporation and condensation experimental data.

You might also be interested in these eBooks

Materials Engineering and Technologies for Production and Processing V

Info:

Periodical:

Solid State Phenomena (Volume 299)

Pages:

270-274

DOI:

https://doi.org/10.4028/www.scientific.net/SSP.299.270

Citation:

Cite this paper

Online since:

January 2020

Authors:

Anton A. Valeev*, Elena V. Morozova

Keywords:

Capillary Condensation, Capillary Evaporation, Kelvin Equation, Mesoporous Materials, Phase Transition

Export:

RIS, BibTeX

Price:

Permissions CCC:

Request Permissions

Permissions PLS:

Request Permissions

Сopyright:

© 2020 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

* - Corresponding Author

[1] E. Barsotti, S. P. Tan, S. Saraji, M. Piri, J.-H. Chen, A review on capillary condensation in nanoporous media: Implications for hydrocarbon recovery from tight reservoirs, Fuel, 184 (2016) 344-361.

DOI: 10.1016/j.fuel.2016.06.123

[2] V.G. Arakcheev, A.A. Valeev, V.B. Morozov, A.N. Olenin, CARS diagnostics of molecular media under nanoporous confinement, Laser Physics, 18 (2008) 1451-1458.

DOI: 10.1134/s1054660x08120128

[3] V.G. Arakcheev, S.A. Dubyanskiy, V.B. Morozov, A.N. Olenin, V.G. Tunkin, A.A. Valeev, D.V. Yakovlev, V.N. Bagratashvili, V.K. Popov, Vibrational line shapes of liquid and subcritical carbon dioxide in nano-pores, Journal Of Raman Spectroscopy, 39 (2008) 750-755.

DOI: 10.1002/jrs.1974

[4] V.G. Arakcheev, A.A. Valeev, V.B. Morozov, A.N. Olenin, D.V. Yakovlev, V.N. Bagratashvili, V.K. Popov, Spectral characteristics of subcritical carbon dioxide in nanopores, Russian Journal of Physical Chemistry B, 3 (2009) 1062-1066.

DOI: 10.1134/s1990793109070045

[5] V. Arakcheev, V. Morozov, A. Valeev, CARS diagnostics of phase transitions of molecular media confined in nanopores, CLEO/Europe - EQEC 2009 - European Conference on Lasers and Electro-Optics and the European Quantum Electronics Conference, 2009, Article number 5196584.

DOI: 10.1109/cleoe-eqec.2009.5196584

[6] V.G. Arakcheev, A.A. Valeev, V.B. Morozov, I.R. Farizanov, Phase behavior of the molecular medium in nanopores and vibrational spectra structure transformation, Moscow University Physics Bulletin, 66 (2011) 147-154.

DOI: 10.3103/s0027134911020032

[7] O.V. Andreeva, V.G. Arakcheev, V.B. Morozov, A.A. Valeev, V.N. Bagratashvili, V.K. Popov, CARS diagnostics of fluid adsorption and condensation in small mesopores, Journal of Raman Spectroscopy, 42 (2011) 1747-1753.

DOI: 10.1002/jrs.2979

[8] V.G. Arakcheev, A.N. Bekin, V.B. Morozov, CARS detection of liquid-like phase appearance in small mesopores, Laser Physics, 27 (2017) 115701.

DOI: 10.1088/1555-6611/aa8cd8

[9] V.G. Arakcheev, A.N. Bekin, V.B. Morozov, Spectroscopic characterization of adsorbate confined in small mesopores: Distinction of first surface-adsorbed layer, polymolecular layers, and liquid clusters, Journal Of Raman Spectroscopy, 49 (2018) 1945-1952.

DOI: 10.1002/jrs.5491

[10] H. Omi, B. Nagasaka, K. Miyakubo, T. Ueda, T. Eguchi, High-pressure 129Xe NMR study of supercritical xenon confined in the mesopores of FSM-16, Phys. Chem. Chem. Phys., 6 (2004) 1299-1303.

DOI: 10.1039/b314841f

[11] M.A. Alam, A.P. Clarke, J.A. Duffy, Langmuir, 16 (2000) 7551-7553.

[12] K. Morishige, Y. Nakamura, Nature of adsorption and desorption branches in cylindrical pores, Langmuir, 20 (2004) 4503-4506.

DOI: 10.1021/la030414g

[13] A.A. Valeev, E.V. Morozova, Simple Universal Kelvin Equation Valid in Critical Point Vicinity and its Application to Carbon Dioxide Capillary Condensation in Mesoporous Silica, Solid State Phenomena, 265 (2017) 392-397.

DOI: 10.4028/www.scientific.net/ssp.265.392

[14] A.A. Valeev, Simple Universal Kelvin Equation Valid in the Critical Point Vicinity, External-Internal State Correction, and their Application to Nitrogen Capillary Condensation in Mesoporous Silica MCM-41: submitted to Surface Review and Letters (2017).

DOI: 10.4028/www.scientific.net/ssp.299.270

[15] A.A. Valeev, E.V. Morozova, Simple Universal Kelvin Equation Valid in the Critical Point Vicinity, External-Internal State Correction, and their Application to Nitrogen Capillary Condensation in Mesoporous Silica SBA-15, Solid State Phenomena, 284 (2018) 801-806.

DOI: 10.4028/www.scientific.net/ssp.284.801

[16] A.A. Valeev, E.V. Morozova, Simple Universal Kelvin Equation Valid in Critical Point Vicinity, External-Internal State Correction, and their Application in Argon Capillary Condensation in Mesoporous Silica MCM-41, IOP Conf. Series: Earth and Environmental Science, 194 (2018) 042025.

DOI: 10.1088/1755-1315/194/4/042025

[17] A.A. Valeev, Simple Kelvin equation applicable in the critical point vicinity, European Journal of Natural History, 5 (2014) 13-14.

DOI: 10.17513/ejnh.506-33335

[18] R.C. Tolman, The effect of droplet size on surface tension, J. Chem. Phys., 17 (1949) 333-337.

[19] S.P. Tan, M. Piri, Equation-of-state modeling of confined-fluid phase equilibria in nanopores, Fluid Phase Equilibr., 393 (2015) 48-63.

DOI: 10.1016/j.fluid.2015.02.028

[20] R.B. Stewart, R.T. Jacobsen, W. Wagner, Thermodynamic Properties of Oxygen from the Triple Point to 300 K with Pressures to 80 MPa, J. Phys. Chem. Ref. Data, 20 (1991) 917-1021.

DOI: 10.1063/1.555897

[21] R. Span, W. Wagner, Equations of State for Technical Applications. II. Results for Nonpolar Fluids, Int. J. Thermophys., 24 (2003) 41-109.

[22] B.E. Poling, J.M. Prausnitz, J.P. O'Connell, The Properties of Gases and Liquids, fifth ed., McGraw-Hill, New York, (2001).

[23] F. Cuadros, I. Cachadiña, W. Ahumada, Determination of Lennard-Jones Interaction Parameters Using a New Procedure, Molecular Engineering, 6 (1996) 319-325.

DOI: 10.1007/bf01886380

[24] K. Morishige, M. Ito, Capillary condensation of nitrogen in MCM-41 and SBA-15, J. Chem. Phys., 117 (2002) 8036-8041.

DOI: 10.1063/1.1510440

[25] R. Evans, U. Marini Bettolo Marconi, P. Tarazona, J. Chem. Phys., 84 (1986) 2376-2399.

[26] R. Evans, U. Marini Bettolo Marconi, P. Tarazona, J. Chem. Soc. Faraday Trans., 82 (1986) 1763-1787.

[27] P.I. Ravikovitch, S.C.Ó. Domhnail, A.V. Neimark, F. Schüth, K.K. Unger, Capillary Hysteresis in Nanopores: Theoretical and Experimental Studies of Nitrogen Adsorption on MCM-41, Langmuir, 11 (1995) 4765-4772.

DOI: 10.1021/la00012a030

[28] A.V. Neimark, P.I. Ravikovitch, A. Vishnyakov, Adsorption Hysteresis in Nanopores, Phys. Rev. E, 62 (2000) R1493-R1496.

DOI: 10.1103/physreve.62.r1493

[29] A. Vishnyakov, A.V. Neimark, Studies of Liquid-Vapor Equilibrium, Criticality and Spinodal Transitions in Nanopores by the Gauge Cell Monte Carlo Simulation Method, J. Phys. Chem. B, 105 (2001) 7009-7020.

DOI: 10.1021/jp003994o

[30] G.S. Heffelfinger, F. van Swol, K.E. Gubbins, Adsorption hysteresis in narrow pores, J. Chem. Phys., 89 (1988) 5202-5205.

DOI: 10.1063/1.455610

[31] U. Marini Bettolo Marconi, F. van Swol, Microscopic model for hysteresis and phase equilibria of fluids confined between parallel plates, Phys. Rev. A, 39 (1989) 4109-4116.

DOI: 10.1103/physreva.39.4109

[32] A. Papandopulu, F. van Swol, U. Marini Bettolo Marconi, Pore-end effects on adsorption hysteresis in cylindrical and slitlike pores, J. Chem. Phys., 97 (1992) 6942-6952.

DOI: 10.1063/1.463648