Pyro-Metallurgical Processing of Ilmenite Concentrate with Production of Iron and Titanium Oxides

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The main problem of processing of ores with a high content of titanium oxides is refractory slag based on TiO2, which makes it difficult to melt. The methods of processing of titanomagnetite and ilmenite ores were analyzed. It is shown that the existing scheme of processing does not meet the requirements of complex use of materials. The paper presents the results of laboratory studies on reduction of ilmenite concentrate and subsequent pyrometallurgical separation of reduction products without addition of flux or slag-forming materials. Solid-phase reduction of iron enabled to extract iron selectively from the ilmenite crystal lattice, not diluting the oxide phase with the reducing agent ash. Using the advantages of solid-phase reduction, the possibility of obtaining pure iron and slag with a high content of titanium oxides was shown.

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Solid State Phenomena (Volume 316)

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385-389

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April 2021

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© 2021 Trans Tech Publications Ltd. All Rights Reserved

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[1] K. Li, Ni Q., Zhu W., Zheng M., J. M., Y. Li. Iron extraction from oolitic iron ore by a deep reduction process. Journal of iron and steel research international. 18(8) (2011) 9-13.

DOI: 10.1016/s1006-706x(11)60096-4

Google Scholar

[2] Y. Kapelyushin, X. Xing, J. Zhang, S. Jeong, Y. Sasaki, O. Ostrovski. Effect of alumina on the gaseous reduction of magnetite in CO/CO 2 gas mixtures. Metallurgical and Materials Transactions B. 46(3) (2015) 1175-1185.

DOI: 10.1007/s11663-015-0316-z

Google Scholar

[3] Y. Kapelyushin, Y. Sasaki, J. Zhang, S. Jeong, O. Ostrovski. In-Situ study of gaseous reduction of magnetite doped with alumina using high-temperature XRD analysis. Metallurgical and Materials Transactions B. 46(6) (2015) 2564-2572.

DOI: 10.1007/s11663-015-0437-4

Google Scholar

[4] S. Cullough, N. A. Barcza, S. Hockaday, C. Johnson. Pre-reduction and smelting characteristics of Kazakhstan ore samples. The Twelfth international Ferro-Alloys Congress Substainable Future. Helsinki, Finland. (2010) 249-262.

Google Scholar

[5] N. M. Anacleto, I. Solheim, B. Sorensen, E. Ringdalen, O. Ostrovski. Reduction of chromium oxide and ore by methane-containing gas mixtures. Authors' Revised Draft Infacon XV: International Ferro-Alloys Congress, Southern African Institute of Mining and Metallurgy, Cape Town. (2018) 71-78.

Google Scholar

[6] M. Leikola, P. Taskinen, R. H. Eric. Reduction of Kemi chromite with methane. Journal of the Southern African Institute of Mining and Metallurgy. 118(6) (2018) 575-580.

DOI: 10.17159/2411-9717/2018/v118n6a3

Google Scholar

[7] S. Sokhanvaran, D. Paktunc, A. Barnes. NaOH-assisted direct reduction of Ring of Fire chromite ores, and the associated implications for processing. Journal of the Southern African Institute of Mining and Metallurgy. 118(6) (2018) 581-588.

DOI: 10.17159/2411-9717/2018/v118n6a4

Google Scholar

[8] A. Bhalla, R. H. Eric. Mechanism and kinetic modelling of methane-based reduction of Mamatwan manganese ore. Authors' Revised Draft Infacon XV: International Ferro-Alloys Congress, Southern African Institute of Mining and Metallurgy, Cape Town. (2018) 143-156.

Google Scholar

[9] A. Cheraghi, H. Yoozbashizadeh, J. Safarian. Chemical, microstructural, and phase changes of manganese ores in calcination and pre-reduction by natural gas. Authors' Revised Draft Infacon XV: International Ferro-Alloys Congress, Southern African Institute of Mining and Metallurgy, Cape Town. (2018) 157-167.

Google Scholar

[10] R. Huang, X.W. Lv, C.G. Bai, Q.Y. Deng, S.W. Ma. Solid state and smelting reduction of Panzhihua ilmenite concentrate with coke. Canadian Metallurgical Quarterly. 51(4) (2012) 434-439.

DOI: 10.1179/1879139512y.0000000008

Google Scholar

[11] H.P. Gou, G.H. Zhang, X.J. Hu, K.C. Chou. Kinetic study on carbothermic reduction of ilmenite with activated carbon. Transactions of Nonferrous Metals Society of China. 27(8) (2017) 1856-1861.

DOI: 10.1016/s1003-6326(17)60209-7

Google Scholar

[12] K. I. Smirnov. Involvement of high-titanium titanomagnetites in non-waste pyrometallurgical processing. Problems of geology and subsoil development: Proceedings of the International Symposium XXI Academician MA Usov students and young scientists, dedicated to the 130th birthday of Professor MI Kuchin, Tomsk, 3-7 april 2017 y. Vol 2.—Tomsk, 2017. 2 (2017) 415-417.

Google Scholar

[13] V.E. Roshchin, A.V. Asanov, A.V. Roshchin. Possibilities of two-stage processing oftitanomagnetite ore concentrates. Russian metallurgy (Metally). 6 (2011) 499-508.

DOI: 10.1134/s0036029511060206

Google Scholar

[14] V.E. Roshchin, A.V. Asanov, A.V. Roshchin. Solid-phase prereduction of iron-vanadium concentrates and liquid-phase separation of the products of their reduction. Russian metallurgy (Metally). 11 (2010) 1001-1008.

DOI: 10.1134/s0036029510110029

Google Scholar

[15] L.I. Leontev, N.A. Vatolin, S.V. Shavrin, N.S. Shumakov. Pyrometallurgical processing of complex ores. Moscow. Metallurgy. 1997. (In Russ.).

Google Scholar

[16] N.V. Gudima, Ja. P. Shejn. A quick reference to the metallurgy of non-ferrous metals. Metallurgy. (1975) 536.

Google Scholar

[17] N. I. Utkin. Non-ferrous metal production. Intermet Inzhiniring. (2004) 442.

Google Scholar

[18] N.V. Panishev, V.F. Rashnikov, B.A. Dubrovsky, E.V. Redin. Metallization of feldspar iron ore and titanomagnetites of the Chelyabinsk region. Proceedings of the Eighth International Industrial Forum Reconstruction of Industrial Enterprises - Breakthrough Technologies in Metallurgy and Mechanical Engineering,. (2016) 48-49.

Google Scholar

[19] M. A. Pourabdoli, D. I. H., S. Raygan, H. Abdizadeh, K. Hanaei. Production of high titania slag by Electro-Slag Crucible Melting (ESCM) process. International Journal of Mineral Processing. 78(3) (2006) 175-181.

DOI: 10.1016/j.minpro.2005.10.005

Google Scholar

[20] V.E. Roshchin, A.V. Roshchin, P.A. Gamov, A.S. Bilgenov. Electric and mass transfer during the reduction of metals with solid carbon in solid complex oxides. Metals. 1 (2020) 59–71.

DOI: 10.1134/s0036029520010103

Google Scholar

[21] V.E. Roshchin, A.V. Roshchin. Electron mechanism of reduction processes in blast and ferroalloy furnaces. CIS Iron and Steel Review. 17 (2019) 14–24.

DOI: 10.17580/cisisr.2019.01.03

Google Scholar