Effect of the Environment on the Characteristics of a Polymer

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Abstract:

The polycarbonate (PC) is a highly valued polymeric material for its various characteristics and low cost. Its transparency and impact resistance justify its use in a severe radiation and temperature environment. The aim of this article is to subject this material to aging under ultraviolet (UV) radiation with a wavelength of 253 nm and a temperature of 80°C for various times. The physicochemical and mechanical characterizations of the virgin and aged material have allowed the revelation of the aging effects on the properties. The Fourier Transform Infrared Spectroscopy (FTIR) technique highlight breaks in chemical bonds in the molecular chains of the PC subjected to the combined effects of UV and heat. X-ray analysis have showed a reduction in crystallites and a tendency towards an amorphous state at short times, but the degree of crystallinity increases again at long exposure times of the material. As a result, the microhardness of the aged material is strongly affected on the exposed surface with less effect depending on the depth.

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Solid State Phenomena (Volume 324)

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139-144

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September 2021

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© 2021 Trans Tech Publications Ltd. All Rights Reserved

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[1] S. Eve, J. Mohr, Study of the surface modification of the PMMA by UV-radiation, Procedia Engineering, Study Procedia Engineering (2009) 237–240.

DOI: 10.1016/j.proeng.2009.06.056

Google Scholar

[2] J. Jagielski, A. Turos, D. Bielinski, M. Abdul-Kader, A. Piatkowska, A. Nucl, Ion-beam modified polymers for biomedical applications, Instruments Methods Phys. Res. Sect. B: Beam Interact. with Mater. Atoms 261 (2007) 690–3.

DOI: 10.1016/j.nimb.2007.03.021

Google Scholar

[3] Collin S2013 PhD thesis (France: Blaise Pascal University).

Google Scholar

[4] Quatremer1996 Précis de matièresplastiques 063097 (Nathan).

Google Scholar

[5] E. Ghorbel, I. Hadriche, G. Casalino, N. Masmoudi,2014 Effect of Silicon Carbide (SiC) Nanoparticles on the Spectroscopic Properties and Performance of PMMA/PC Polymer Blend Materials (Basel) (2014) 7375–98.

Google Scholar

[6] K. Hareesh, A. Pandey, Y. Sangappa, R. Bhat, A. Venkataraman, A.Sanjeev, G. Nucl., Changes in the properties of Lexan polycarbonate by UV irradiation, Instruments Methods Phys. Res. Sect. B: Beam Interact. with Mater. Atoms vol. 295 (2013) 61–8.

DOI: 10.1016/j.nimb.2012.10.011

Google Scholar

[7] A. Rivato, Recent advances in bisphenol-A polycarbonate photodegradation, Polym. Degrad. Stab (1995).49 163–79.

Google Scholar

[8] G. Tjandraatmadja, F. Burn L, S. andJollands, Evaluation of commercial polycarbonate optical properties after QUV-A radiation the role of humidity in photodegradation, Polym.Degrad. Stab., (2002) 78435–48.

DOI: 10.1016/s0141-3910(02)00179-9

Google Scholar

[9] B. Claud, L. Gonon, J. Duchet V. Verney JL. Gardette, Surface cross-linking of polycarbonate under irradiation at long wavelengths, Polym. Degrad. Stab., (2002) Vol. 8 3237-40.

DOI: 10.1016/s0141-3910(03)00267-2

Google Scholar

[10] L. Jiang, M. Zhou, Y. Ding, Y. Zhou Yand Dan, aging induced ductile-brittle-ductile transition in bisphenol A polycarbonate, J. Polym. Res. (2018) Vol.25 25-39.

DOI: 10.1007/s10965-018-1443-4

Google Scholar