Preparation Method of a Metal Carrier for a Catalyst for the Recovery of Exhaust Gases from Nitrogen Oxides

Abstract:

The article shows the process of preparing an oxide layer on the surface of titanium for use in industrial catalysis. Data from physical and chemical studies are presented, namely microhardness, porosity, thickness, specific surface area, adhesion and thermal stability of the active layer.To determine the physicochemical characteristics of the resulting oxide layer, the following analysis methods were used: X-ray diffraction analysis (XRD), X-ray diffraction phase analysis (XPA), X-ray absorption analysis (XRA), and X-ray fluorescence analysis. The thickness of the oxide layer depending on the duration of anodization was estimated by optical microscopy.

• Periodical: Solid State Phenomena (Volume 364)
• Pages: 57-71
• DOI: https://doi.org/10.4028/p-3SMHgF
• Online since: September 2024
• Authors: Vitalii Vekshyn, Volodymyr Koloskov*, Hanna Koloskova, Olexandr Sincheskul
• Keywords: Absorption, Acids, Anodization, Carrier, Catalyst, Gases, Purification, Reduction, Technology

References

[1] A.F. Kiselov, V.O. Ziuzin, O.I. Tsebrzhynskyi, A.O. Rudenko, V.S. Yermilov, T.M. Zinchenko, Sotsialno-ekonomichni ta ekolohichni aspekty hromadskoho zdorovia naselennia Mykolaivshchyny. Ekolohiia. 167 (2012) 103–106.

[2] M.P. Bashtannik, N.S. Zhemera, Ye.M. Kiptenko, T.V. Kozlenko, Stan zabrudnennia atmosfernoho povitria nad terytoriieiu Ukrainy. Naukovi pratsi Ukrainskoho naukovo-doslidnoho hidrometeorolohichnoho instytutu. 266 (2014) 70–93.

[3] B. Paton, V. Bariakhtar, O. Bakai, I. Nekliudov, Maibutnie atomnoi enerhetyky. Visn. NAN Ukrainy. 4 (2006) 3–13.

[4] R. Bohovic, M. Hrnčiar, M. Muroň, J. Chytrý, M. Skalský, M. Černochová, O. Angurets, J. Labohý, Air Pollution in Ukraine as seen from Space: The Effects of the War, World from Space. (2023) 28.

[5] Ye.O. Mykhailova, Mozhlyvi sposoby ochyshchennia hazovykh vykydiv vid oksydiv nitrohenu v umovakh vyrobnytstva kaltsynovanoi sody, Ekolohichna bezpeka: problemy i shliakhy vyrishennia: XV mizhnar. nauk.-prakt. konf., 9–13 ver. 2019 r.: zb. nauk. st. (2019) 227–231.

[6] K.P. Shrestha, L. Seidel, T. Zeuch, F. Mauß, Detailed kinetic mechanism for the oxidation of ammonia including the formation and reduction of nitrogen oxides. Energy & Fuels. 32 (2018) 10202–10217.

DOI: 10.1021/acs.energyfuels.8b01056

[7] K.A. Pedersen, M.T. Lewandowski, C. Schulze-Netzer, M. Pasternak, T. Løvås, Ammonia in Dual-Fueled Internal Combustion Engines: Impact on NOx, N2O, and Soot Formation. Energy & Fuels. 37 (2023) 17585–17604.

DOI: 10.1021/acs.energyfuels.3c02549

[8] R.M. Choueiri, S. W. Tatarchuk, A. Klinkova, L.D. Chen, Mechanism of ammonia oxidation to dinitrogen, nitrite, and nitrate on β-Ni(OH)2 from first-principles simulations. Electrochem Sci Adv. 2 (2022) 1–10.

DOI: 10.33774/chemrxiv-2021-7z76q

[9] A.V. Shapka, M.I. Vorozhbiian, O.V. Kobzev, Mekhanizm homohenno-heterohennoho okyslennia monooksydu azotu kysnem. Informatsiino-keruiuchi systemy na zaliznychnomu transporti. 5 (2001) 115.

[10] A.D. Tiulpynov, T.P. Kliachenko, Snyzhenye zahriaznenyia atmosfery hazovymy vybrosamy promyshlennykh predpryiatyi, Khimichna promyslovist Ukrainy. 1–2 (2000) 100–103.

[11] M.F. Sheikh, P. Wang, Z. Chen, J.-J. Yin, Innovative catalysts for the selective catalytic reduction of NOx with H2: A systematic review. Fuel. 355 (2024) 129364.

DOI: 10.1016/j.fuel.2023.129364

[12] M. Schwefer, R. Maurer, T. Turek, M. Kögel (Krupp Uhde GmbH), DE Patent WO2001051182A1. (2001).

[13] G. D. Grab, S.W. Dean, U.S. Patent 4562052A. (2004).

[14] N.S. Mosyna, T.Y. Obushenko, Yu.V. Kniazev, Tonkoplenochnye setchatye katalyzatory dlia ochystky otkhodiashchykh hazov. Trudy Odeskoho polytekhnycheskoho unyversyteta. 3 (2001) 288–291.

[15] M.S. Souza, A.J. Martins, J.A.S. Ribeiro, A. Campos, A.C. Oliveira, R.F. Jucá, G.D. Saraiva, M.A.M. Torres, E. Rodríguez-Castellón, R.S. Araujo, Selective Catalytic Reduction of NOx by CO over Cu(Fe)/SBA-15 Catalysts: Effects of the Metal Loading on the Catalytic Activity. Catalysts. 13 (2023) 1–23.

DOI: 10.3390/catal13030527

[16] J.-H. Choi, J. Hwang, G. Kim, J.-J. Choi, C.-W. Ahn, J.-W. Kim, B.-D. Hahn, W.-H. Yoon, Y. Min, Catalyst adhesion enhancement by porous TiO2 layer formed on anodized titanium honeycomb substrate. Ceramics International. 47 (2020) 7241–7247.

DOI: 10.1016/j.ceramint.2020.10.173

[17] H. Zhou, B. Gabbitas, S. Mathews, D. Zhang, Titanium and titanium alloy coatings for corrosion protection. Ti 2011 - Proceedings of the 12th World Conference on Titanium. 3 (2012) 1906–1910.

[18] A.Ia. Loboiko, V.A. Vekshyn, N.B. Markova, M.Y. Vorozhbyian, L.P. Shapareva, Yssledovanye vlyianyia tekhnolohyy pryhotovlenyia katalyzatora na raspredelenye katalytychesky aktyvnoho veshchestva po poverkhnosty nosytelia. Suchasni problemy tekhnolohii neorhanichnykh rechovyn: zbirnyk naukovykh prats DDTU. 2 (2008) 59–62.

[19] J. Yang, A.D. Salman, P. Blanco-García, A review of measurement techniques of mechanical properties of the catalyst layer in catalytic converters. Johnson Matthey Technology Review. 63 (2019) 177–190.

DOI: 10.1595/205651319x15475632460410

[20] C. Couroyer, M. Ghadiri, P. Laval, N. Brunard, F. Kolenda, Methodology for Investigating the Mechanical Strength of Reforming Catalyst Beads. Oil & Gas Science and Technology. Rev. IFP. 55 (2000) 67–85.

DOI: 10.2516/ogst:2000004

[21] M. Fujita, K. Kuki, An Evaluation of Mechanical Properties with the Hardness of Building Steel Structural Members for Reuse by NDT. Metals. 6 (2016) 247.

DOI: 10.3390/met6100247

[22] L. Liu, A. Corma, Metal Catalysts for Heterogeneous Catalysis: From Single Atoms to Nanoclusters and Nanoparticles. Chemical Reviews. 118 (2018) 4981–5079.

DOI: 10.1021/acs.chemrev.7b00776

[23] M.M. Shyshkov. Marochnyk stalei i splaviv. Dovidnyk. Vyd. 3-ye, dopovnene, Donetsk, 2000.

[24] M.V. Ved, M.D. Sakhnenko, Katalitychni ta zakhysni pokryttia splavamy i skladnymy oksydamy: elektrokhimichnyi syntez, prohnozuvannia vlastyvostei, NTU «KhPI», Kharkiv, 2010.

[25] N.B. Markova, M.Y. Vorozhbyian, Y.V. Bahrova, V.A. Vekshyn, Razrabotka metallycheskoho nosytelia katalytycheskoi systemi s zadannymy kharakterystykamy. Vestnyk natsyonalnoho tekhnycheskoho unyversyteta «KhPI». 17 (2002) 49–52.

[26] D.J. Campbell, M.S. Baliss, J.J. Hinman, J.W. Ziegenhorn, M.J. Andrews, K.J. Stevenson, Simple Methods for Production of Nanoscale Metal Oxide Films from Household Sources. J. Chem. Educ. 90 (2013) 629–632.

DOI: 10.1021/ed300245e

[27] G. Shevchenko, A. Pilipenko, T. Shkolnikova, S. Gura, O. Smirnova, Production of Nanosize Interference-colored Oxide Films on the Ti6Al4V Alloy Surface Using the Method of Electrochemical Oxydation in Succinate Eletrolytes, 2020 IEEE 40th International Conference on Electronics and Nanotechnology (ELNANO), Kyiv, Ukraine. (2020) 216–219.

DOI: 10.1109/elnano50318.2020.9088771

[28] V.Y. Toshynskyi, M.Y. Vorozhbyian, V.A. Vekshyn, N.B. Markova, S.L. Chepurnoy, Prymenenye metallycheskoho tytana dlia pryhotovlenyia nosytelia katalyzatora ochystky vykhlopnykh nytroznykh hazov, Sovremennye problemy khymycheskoi tekhnolohyy neorhanycheskykh veshchestv: mezhdunar. nauchn.-tekhn. konf., 2001 h.: tezy dokl. (2001) 235–238.

[29] V.A. Vekshyn, V.Y. Toshynskyi, M.Y. Vorozhbyian, S.L. Chepurnoy, Razrabotka y yssledovanye aktyvnosty katalyzatora ochystky hazovykh vybrosov ot oksydov azota. Vestnyk Natsyonalnoho tekhnycheskoho unyversyteta «KhPI». 3 (2001) 25–27.

[30] N.Z.W. Wang, J. Xu, B. Ma, Z. Zhang, Q. Jin, E. Bunte, J. Hüpkes, H. Bochem, Initial stage of pore formation process in anodic aluminum oxide template. Journal of Solid State Electrochemistry. 14 (2010) 1377–1382.

DOI: 10.1007/s10008-009-0959-2

[31] M. Liao, H. Ma, D. Yu, H. Han, X. Xu, X. Zhu, Formation mechanism of anodic titanium oxide in mixed electrolytes. Materials Research Bulletin. 95 (2017) 539–545.

DOI: 10.1016/j.materresbull.2017.08.041

[32] C.W. Ng, A.S. Mahmud, M.N. Ahmad, M.F. Razali, Y. Liu, Estimation of titanium oxide layer thickness on thermally oxidized NiTi alloy based on color variations. Materialwiss, Werkstofftech. 53 (2022) 47.

DOI: 10.1002/mawe.202100084

[33] Y.A. Tokareva, B.Y. Bairachnyi, Nanostrukturyrovannye anodnye oksydnye pokrytyia na ventylnykh metallakh – zadachy y vozmozhnosty. Nanosystemy, nanomaterialy, nanotekhnolohii. 15 (2017) 713–740.

[34] W. Junshi, X. Peng, H. Wenbin, L. Dong, Q. Ye, M. Yongli, Ionic liquids as electrolytes in aluminum electrolysis. Front. Chem. 3 (2022) 1–17.

[35] E. Amine, J. El Fallah, A. El Ballouti, A. Hajjaji, S. Touhtouh, Y. Boughaleb, Quantitative and qualitative analysis for a better understanding of the aging and degradation mechanisms of electrolytes used in supercapacitors. Journal of Materials Science: Materials in Electronics. 33 (2022) 4568–4578.

DOI: 10.1007/s10854-021-07648-x