Research on Corrosion Resistance of Plasma Nitriding Modified Layer on Stainless Steel Metal Bipolar Plate

Article Preview

Abstract:

The acidic environment and polarization in proton exchange membrane fuel cells (PEMFC) result in severe electrochemical corrosion issues for the bipolar plates of metal-based fuel cells. AISI 304 stainless steel is studied in this paper as the bipolar substrate and treated with plasma nitriding to improve its corrosion resistance performance. The influence of process parameters on the growth pattern of nitrided layers was discussed, and the microstructure and properties of modified layers were systematically studied. Results show that an expanded austenite nitride layer is obtained when the nitriding temperature is under 450°C, which has good corrosion resistance. When CrN precipitates at higher nitriding temperatures, the corrosion resistance of the nitride layer sharply decreases. The presence of valence states of N and Cr atoms in the nitrided layer determines the corrosion resistance of nitrided stainless steel samples.

You might also be interested in these eBooks

Info:

Periodical:

Solid State Phenomena (Volume 367)

Pages:

99-103

Citation:

Online since:

December 2024

Export:

Price:

Permissions CCC:

Permissions PLS:

Сopyright:

© 2024 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

* - Corresponding Author

[1] Xin Gao, Jiayi Chen, Runjing Xu, et al. Research progress and prospect of the materials of bipolar plates for proton exchange membrane fuel cells (PEMFCs), International Journal of Hydrogen Energy, 50 (2024), 711-743.

DOI: 10.1016/j.ijhydene.2023.09.005

Google Scholar

[2] Jun Bi, Jinmeng Yang, Xiaoxiang Liu, et al. Development and evaluation of nitride coated titanium bipolar plates for PEM fuel cells, International Journal of Hydrogen Energy, 46 (2021), 1, 144-1, 154.

DOI: 10.1016/j.ijhydene.2020.09.217

Google Scholar

[3] Ruixuan Liu, Qian Jia, Bin Zhang, et al. Protective coatings for metal bipolar plates of fuel cells: A review, International Journal of Hydrogen Energy, 47 (2022), 22, 915-22, 937.

DOI: 10.1016/j.ijhydene.2022.05.078

Google Scholar

[4] Ji-Hyeok Choi, Ha Eun Kang, Dong-Joo Kim, et al. A Comprehensive Review of Stainless-Steel Bipolar Plate Coatings and Their Role in Mitigating Corrosion in Aggressive Proton-Exchange Membrane Fuel Cells Environments, Chemical Engineering Journal, 493 (2024), 1, 385-8, 947.

DOI: 10.1016/j.cej.2024.152662

Google Scholar

[5] J. Biehler, H. Hoche, and M. Oechsner. Nitriding behavior and corrosion properties of AISI 304L and 316L austenitic stainless steel with deformation-induced martensite, Surface and Coatings Technology, 324 (2017), 121-128.

DOI: 10.1016/j.surfcoat.2017.05.059

Google Scholar

[6] Emile Haye, Fabien Deschamps, Giuseppe Caldarella, et al. Formable chromium nitride coatings for proton exchange membrane fuel cell stainless steel bipolar plates, International Journal of Hydrogen Energy, 45 (2020), 15, 358-15, 365.

DOI: 10.1016/j.ijhydene.2020.03.248

Google Scholar

[7] Baosen Mi, Tianju Chen, Jiacheng Zhang, et al. Effect of N doping on Cr-doped amorphous carbon /CrN /Ti multilayer coatings on 316L stainless steel bipolar plate for PEMFC: First-principles calculation, structure, and performance, International Journal of Hydrogen Energy, 71 (2024), 1, 303-1, 316.

DOI: 10.1016/j.ijhydene.2024.05.294

Google Scholar

[8] Haitao Zhou, Dongling Jiao, Hongzhen Ding, et al. Effect of magnetron sputtering C-doped CrN film on the conductivity and corrosion resistance of 304 stainless steel bipolar plates, Surface and Coatings Technology, 483 (2024), 130, 769.

DOI: 10.1016/j.surfcoat.2024.130769

Google Scholar