Improved Performance of NiCoFe-LDH Electrocatalyst by Synthesizing on NiCo2O4 with Ni Foam for Effective Oxygen Evolution Reaction

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Abstract:

In water splitting, high-performance electrocatalysts play an essential role in the oxygen evolution reaction (OER). This study focuses on preparing nanoflower-structured electrocatalysts by coating different amounts of Ni in NiCoFe double hydroxide (LDH) onto the NiCo2O4 surface on Ni foam (NF) using a hydrothermal method. The NiCoFe-LDH@NiCo2O4/NF electrocatalyst demonstrates excellent activity for OER, exhibiting low overpotential and good stability. The exceptional performance is attributed to the high electrochemically active surface area of ​​NiCoFe-LDH when combined with NiCo2O4. The optimal Ni0.75CoFe-LDH@NiCo2O4/NF electrocatalyst demonstrates exceptional oxygen evolution reaction (OER) performance, with a low overpotential of 254mV at a current density of 50mA·cm−2. It also shows excellent durability, with minimal overshot during overall water splitting stability tests. This study suggests developing highly efficient OER catalysts using ternary transition metals in the future.

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Solid State Phenomena (Volume 379)

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31-37

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November 2025

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© 2025 Trans Tech Publications Ltd. All Rights Reserved

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[1] Information on https://www.iea.org/reports/the-future-of-hydrogen

Google Scholar

[2] D. Yao, L. Gu, B. Zuo, S. Weng, W. Hao, A strategy for preparing high-efficiency and economical catalytic electrodes toward overall water splitting, Nanoscale. 13 (2021) 10624-10648.

DOI: 10.1039/d1nr02307a

Google Scholar

[3] Y. Jiao, Y. Zheng, M. Jaroniec, S. Qiao, Design of electrocatalysts for oxygen and hydrogen involving energy conversion reactions, Chem Soc Rev. 44 (2015) 2060-2086.

DOI: 10.1039/c4cs00470a

Google Scholar

[4] Z. Wang, S. Zeng, W. Liu, X. Wang, Q. Li, Z. Zhao, F. Geng, Coupling molecularly ultrathin sheets of NiFe-layered double hydroxide on NiCo2O4 nanowire arrays for highly efficient overall water-splitting activity, ACS Appl. Mater. Interfaces. 9 (2017) 1488-1495.

DOI: 10.1021/acsami.6b13075.s001

Google Scholar

[5] H. Xia, G. Li, H. Cai, X. Li, P. Sun, P. Wang, J. Huang, L. Wang, D. Zhang, Y. Yang, J. Xiong, Interlaced NiMn-LDH nanosheet decorated NiCo2O4 nanowire arrays on carbon cloth as advanced electrodes for high-performance flexible solid-state hybrid supercapacitors, Dalton Trans. 48 (2019) 12168-12176.

DOI: 10.1039/c9dt02227a

Google Scholar

[6] S. Wang, J. Li, H. Fang, B. Li, G. Wang, Y. Gao, 3D core-shell structured NiFe layered double hydroxide with NiCo2O4 as an efficient electrocatalysts for oxygen evolution reaction, Journal of Physics and Chemistry of Solids. 166 (2022) 110730.

DOI: 10.1016/j.jpcs.2022.110730

Google Scholar

[7] R. Yang, Y. Zhou, Y. Xing, D. Li, D. Jiang, M. Chen, W. Shi, S. Yuan, Synergistic coupling of CoFe-LDH arrays with NiFe-LDH nanosheet for highly efficient overall water splitting in alkaline media, Applied Catalysis B: Environmental. 253 (2019) 131-139.

DOI: 10.1016/j.apcatb.2019.04.054

Google Scholar

[8] X. Wang, Y. He, Y. Zhou, R. Li, W. Lu, K. Wang, W. Liu, In situ growth of NiCoFe-layered double hydroxide through etching Ni foam matrix for highly enhanced oxygen evolution reaction, International Journal of Hydrogen Energy. 47 (2022) 23644-23652.

DOI: 10.1016/j.ijhydene.2022.05.198

Google Scholar

[9] Q. Ma, B. Li, F. Huang, Q. Pang, Y. Chen, J. Zhang, Incorporating iron in nickel cobalt layered double hydroxide nanosheet arrays as efficient oxygen evolution electrocatalyst, Electrochimica Acta. 317 (2019) 684-693.

DOI: 10.1016/j.electacta.2019.06.019

Google Scholar

[10] Y. Yang, M. Luo, W. Zhang, Y. Sun, X. Chen, S. Guo, Metal Surface and Interface Energy Electrocatalysis: Fundamentals, Performance Engineering, and Opportunities, Chem. 4 (2018) 2054-2083.

DOI: 10.1016/j.chempr.2018.05.019

Google Scholar