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Online since: January 2016
Authors: Yun Hin Taufiq-Yap, Maratun Najiha Abu Tahari, Azizul Hakim, Mohd Ambar Yarmo, Tengku Sharifah Marliza Tengku Azmi
Tetraethylorthosilicate (TEOS) was purchased from Aldrich Chemistry and used as a silica source.
Fig. 1 shows the structure of [BMIm][Tf2N] and [EMIm][HSO4] and the suggestion immobilization of ILs on silica via anion or cation.
(a) (b) (c) (d) Fig. 1 The structure of (a) 1-butyl-3-methylimidazolium bis(trifluromethylsulfonyl)imide [BMIm][Tf2N] (b) 1-ethyl-3-methylimidazolium hydrogensulfate [EMIm][HSO4] and immobilization of ionic liquid via (c) anion (d) cation Characterization of supported imidazolium-based ILs.
This probably due to the additional of basic site at supported materials obtained from ILs structure which resulting in increasing of the total CO2 adsorbed.
Gomez, Imidazolium-based ionic liquids immobilized on solid supports: effect on the structure and thermostability, Dalton Trans 39 (2010) 7565-7568
Online since: July 2008
Authors: Na Li, Wei Qiang Wang, Ji Zhong Zhang
For MnAs films grown by molecular beam epitaxy on GaAs, the phase separation process leads to a self-organized structure on the sub-micron scale with alternating ferromagnetic and non-ferromagnetic stripes [2].
Using spontaneous self-organization effects is an efficient way to produce nano-structures, as for instance quantum wires and quantum dots [6].
They were crystal clusters, linear structures, and circular-shaped aggregates.
Crystal Growth, 251 (2003) 297 [3] W.H.Yeom: Journal of Electron Spectroscopy and Related Phenomena, 114116 (2001) 283 [4] M.V.Chubynsky and M.F.Thorpe: Current Opinion in Solid State and Materials Science, 5 (2001) 525 [5] G.Springholz, M.Pinczolits and V.Holy et al.: Surface Science, 454-456 (2000) 657 [6] W.Seifert, N.Carlsson, J.Johansson, M.Pistol and L.Samuelson: Journal of Crystal Growth, 170 (1997) 39 [7] M.P.Pileni, J.Tanori and A.Filankembo: Colloids and Surfaces, 123-124 (1997) 561 [8] M.Muthukumar, C.K.Ober and E.L.Thomas: Science, 277 (1997) 1225 [9] S.Clar, B.Drossel and F.Schwabl: Physical Review Letters, 75 (1995) 2722 [10] A.Rinaldo, I.Rodriguez-Iturbe, R.Rigon, E.Ijjasz-Vasquez and R.L.Bras: Physical Review Letters, 70 (1993) 822 [11] G.Nicolis and I.Prigogine: Self-Organization in Nonequilibrium Systems, Wiley, New York, 1977 [12] M.G.Velarde and C.Normand: Scientific American, 243 (1980) 93 [13] A.M.Zhabotinsky and B.Bunsenges: Physical Chemistry
, 84 (1980) 295 [14] F.Cramer: Chaos and Order -The Complex Structure of Living Systems, VCH Verlagsgesellschaft, Weinheim, and VCH Publisher, New York, 1993 [15] J.Z.Zhang: Physical Review B, 41 (1990) 9614 [16] J.Z.Zhang, Y.H.Shen and A.J.Xie: Journal of Physics - Condensed Matter, 15 (2003) 1943 [17] J.Z.Zhang, X.Y.Ye and X.D.Yang: Physica Status Solidi B, 215 (1999) 1025 [18] J.Z.Zhang, X.Y.Ye, X.J.Yang and D.L.Liu: Physical Review E, 55 (1997) 5796 [19] L.F.Giles, A.Nejim, P.L.F.Hemment: Materials Chemistry and Physics, 35 (1993) 129 [20] P.Nozières: in Solids Far From Equilibrium, edited by C.Godrèche, Cambridge University Press, Cambridge, 1991 [21] B.Caroli, C.Caroli and B.Roulet: in Solids Far From Equilibrium, edited by C.Godrèche, Cambridge University Press, Cambridge, 1991 [22] J.D.Gunton, M.S.Miguel and P.S.Sahni: Phase Transitions and Critical Phenomena, edited by C.Domb and J.Lebowitz, Academic Press, New York, 1983
Online since: December 2014
Authors: Xiao Jing Li, Yun Zhe Ji, Xiao Jie Wang
As shown in the structures of steroid compounds (Figure 1), steroid molecules contain multiple asymmetric centers, which, thus, renders their total artificial synthesis difficult.
Fig 1 Fundamental structure of steroid compounds Steroid Microbial Transformation Reaction Mechanism There are many transformation reactions that microbes are able to perform through whole-cell enzyme catalysis of steroid substrates.
When a certain dose of ultrasound is transmitted into a biological system, the interaction between them induces the generation of ultrasound biological effects, resulting in the changes of biological structures or functions.
[13]Sh.L.Kuang,Ch.Sh.Gong.Sound chemistry and its application.
Chinese Journal of Chemistry,1999,6:23-27(in Chinese)
Online since: June 2011
Authors: Xian Jin Yu, Dang Gang Li, Ya Li Zhang, Li Peng Zhang, Zhi Wei Ge, Yun Hui Dong
The structure of SiC determines its a series of fine property: high degree of hardness, thermostable, oxidation resistance, the decomposition temperature until 2500℃, the high thermal conductivity, the low heat expansion rate, the fine heat-resistant knocking, and good chemical stability.
For the present cell structure anode plunges the electrolyte molten salt in large measure, the electrolysis temperature is 950~970℃, small parts of anode which connect with steel rod are above electrolyte molten salt.
Because of special structure of silicon carbide coating material, high conductive carbon material as base, silicon carbide ceramic coating as surface, therefore it has the electric conductivity property of the ceramic.
QIU: aluminium metallurgical physical chemistry.
SU: introduction to solid chemistry, Peking University Press, BeiJing, (1987) [13] M.A.
Online since: September 2011
Authors: Peng Yan, Xiang Li, Hai Fu Guo, Xiang Ying Hao
The Preparation and Characterization of Solid Superacid S2O82-/SnO2-SiO2 XiangYing Hao a, Hai-Fu Guob ,Peng Yanc and Xiang Lid College of Chemistry and Chemical Engineering, Zhaoqing University, Zhaoqing 526061, China axyinghao@zqu.edu.cn, bguohaifui@zqu.edu.cn, cpeng507@163.com,dlix@zqu.edu.cn Keywords: solid superacid, tin oxide, ammonium persulfate, esterification Abstract.
However, the researches on SO42-/SnO2, not only in its structure but also in applications, are relatively few [11-16], this is mainly because the preparation of Sn-based super acids is more difficult than that of Zr- or Ti-based super acids.
According to literature[17], there will be peaks near 997, 1060, 1130, 1211 cm-1 when sulfate and metal ion, such as Zr4+, Al3+ form bidentate structure.
In Figure 3, there is an obvious peak near 1410cm-1 in Curve a, maybe arisen by S=O vibration from sulfate and Sn of the bidentate structure.
Journal of Photochemistry and Photobiology A: Chemistry 179(2006) 339
Online since: June 2014
Authors: Sheng Wen, Shu Zhong Wang, Li Li Qian, Yan Hui Li
But there are still a certain degree of defects, such as salts deposition and corrosion on the upper hot zone walls, the lack of cooling structures leading to reactors wall overtemperature, the poor ignition and flame stability due to without enough heat storage spaces and so on.
The effects of mixer structure on the hydrothermal flame ignition characteristics of isopropyl alcohol were also researched, which indicated that optimization and design of the mixer could effectively lower the ignition temperatures of isopropyl alcohol.
Although existing SCHC reactors can be used for studying the ignition and extinction characteristics of various fuels, also show their effectiveness for the pollutant disposals, but there are still a certain degree of defects, such as the lack of cooling structures and enough heat storage spaces and so on.
Martinez de la Ossa: Industrial & Engineering Chemistry Research 52(2013), p.7617
Franck: Berichte Der Bunsen-Gesellschaft-Physical Chemistry Chemical Physics 97(1993),p.1091
Online since: March 2011
Authors: Jian Ting Zhou, Jian Xi Yang
Meanwhile, with the evolution of time, the index of chaos is sensitive with status of structure system and varies in different key sections of bridge structure.
This information and the analysis of time sequence play a great role in the research of some fields like mathematics, physics, chemistry, biology, medicine, information-sciences, and economics[2,3].
The above experiments demonstrate that correlation dimension analysis of BHM is effective to reflect the chaos of a bridge structure.
Meanwhile, with the evolution of time, the index of chaos is sensitive with status of structure system and varies in different key sections of bridge structure.
International Journal of Solids and Structures, 2004, 41:5677-5695
Online since: January 2016
Authors: Jun Wang, Manickam Sivakumar
The dimensions of structures range from hundreds of nanometres to a few microns.
Surface structuring on materials with lasers has been demonstrated by the generation of periodic ripple-like structures on the irradiated surfaces [9].
The orientation of nano-structures is greatly influenced by laser polarization.
Bauerle, Laser Processing and Chemistry. 4th ed, New York: Springer, 2011
Sipe, Laser-induced periodic surface structure.
Online since: January 2012
Authors: Knut Marthinsen, Sverre Gulbrandsen-Dahl, Calin D. Marioara, Ketill Olav Pedersen
HARDENING OF AL-MG-SI ALLOYS AND EFFECT OF PARTICLE STRUCTURE Sverre Gulbrandsen-Dahl1,2,a, C.D.
The grain structure is recrystallised in all four alloys analyzed in this work.
Figure 2 shows a typical TEM bright field micrograph of the particle structure of analyzed materials.
The morphology of the precipitation structure described in Table 2 is published earlier [12].
The spherical model in Eq.2 has been used for various conditions, and with knowledge about the fact that the precipitate structures is far from spherical [5].
Online since: May 2021
Authors: Joon Hoong Lim
Ferrites are ferrimagnetic materials having the modified structure of iron.
Fig. 4 shows the electronic band structure of Ni(x)Zn(1-x)Fe2O4.
Fig. 4: Electronic band structure of (a) ZnFe2O4 and (b) NiFe2O4.
Tripathi, Effect of gradual ordering of Ge/Sb atoms on chemical bonding: A proposed mechanism for the formation of crystalline Ge2Sb2Te5, Journal of Solid State Chemistry 260 (2018) 124-131
Electronic structure and transport properties of doped PbSe, Phys.