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Online since: December 2014
Authors: Shan Shan Zhang, Guang Chen, Chang Ming Li, Da Hu
The design principle of chromium alloy tube is that: alloys can form and preserve the protective oxide layer which is formed by dense Fe-Cr spinel and the complete Cr2O3 rich chromium layer in the Fe-Cr spinel grain , under the conditions of the design temperature of tube and the inside and outside diffusion of alloy elements, thus the tube can achieve good anticorrosion performance.
The inner layer of this oxide layer was formed by dense Fe-Cr spinel and the complete Cr2O3 rich chromium layer in the Fe-Cr spinel grain.
These large number of oxygen atoms will satisfy the needs of the reaction of oxygen oxidation.
There were a large number of gaps and microcracks in the middle layer.
The investigation on countermeasures against massive exfoliation of oxidation scale formed on the internal surface of the coarse grained 18-8 type S.S boiler tubes [J].
The inner layer of this oxide layer was formed by dense Fe-Cr spinel and the complete Cr2O3 rich chromium layer in the Fe-Cr spinel grain.
These large number of oxygen atoms will satisfy the needs of the reaction of oxygen oxidation.
There were a large number of gaps and microcracks in the middle layer.
The investigation on countermeasures against massive exfoliation of oxidation scale formed on the internal surface of the coarse grained 18-8 type S.S boiler tubes [J].
Online since: October 2016
Authors: Maria Cristina Carotta, Ambra Fioravanti, Michele Sacerdoti, Mauro Mazzocchi, Antonino Bonanno
Actually, despite of a very large number of papers published on this specific subject, only few authors investigated ZnO 3D hierarchical structures in comparison with two-dimensional ones.
The same situation is offered by the bisphenoids which z axis is about 10 µm and the fine structure is constituted by nanoparticles only slightly lower than those of the NS powders, while NF sample showed grains about 30 nm in size in a flower structure which diameter is about 1 µm.
In particular, in most films, the SEM analysis highlighted only a very modest coalescence of the grains except the case of NF films, for which an appreciable grain growth occurred.
It is no easy to understand such differences due to possible variations in the thickness of the samples, but also to a lower number of contacts between the particles in the bidimensional structures, with a consequent lower number of percolation paths.
The same situation is offered by the bisphenoids which z axis is about 10 µm and the fine structure is constituted by nanoparticles only slightly lower than those of the NS powders, while NF sample showed grains about 30 nm in size in a flower structure which diameter is about 1 µm.
In particular, in most films, the SEM analysis highlighted only a very modest coalescence of the grains except the case of NF films, for which an appreciable grain growth occurred.
It is no easy to understand such differences due to possible variations in the thickness of the samples, but also to a lower number of contacts between the particles in the bidimensional structures, with a consequent lower number of percolation paths.
Online since: November 2015
Authors: Tomáš Brestovič, Natália Jasminská, Marián Lázár, Mária Čarnogurská
Due to the evacuated space between MH grains, a sharp pressure decrease occurs after the opening of the valve, which due to rapid pressure changes is only shown with a dashed line in the diagram.
The model consists of seven cylindrical domains representing MH, which are located in the same number of cylindrical steel containers.
Due to a slow rate and low Reynolds number, the character of the cooling water flow is laminar.
Thermal conductivity of the powdered metal hydride depends on grain size, which changes during operation due to cracking of individual grains in the absorption desorption process.
Department of Energy (DOE) established a number of parameters that represent technological objectives for efficient use of mobile hydrogen storage tanks achieved in 2020.
The model consists of seven cylindrical domains representing MH, which are located in the same number of cylindrical steel containers.
Due to a slow rate and low Reynolds number, the character of the cooling water flow is laminar.
Thermal conductivity of the powdered metal hydride depends on grain size, which changes during operation due to cracking of individual grains in the absorption desorption process.
Department of Energy (DOE) established a number of parameters that represent technological objectives for efficient use of mobile hydrogen storage tanks achieved in 2020.
Online since: October 2018
Authors: I.A. Savin, A.V. Shaparev
The ratio of the thickness of the layers [1], the pressure in the deformation zone [2], the preparation of the surfaces [1, 3] and a number of other technological factors affect the value of the required deformation of the grasping during cladding.
In addition to the high adhesion strength of the layers, a number of requirements are imposed on the bimetallic strips of brass-steel-brass in terms of dimensional accuracy, mechanical properties and microstructure [16].
The relative reduction during cladding affects the bonding strength of bimetal layers, the nature of the microstructure, the size of the recrystallized grains, the mechanical properties of the strip, the dimensional accuracy [4].
Large values of the joint degree of deformation lead to excessive grinding of grains after the recrystallization process and an increase in the anisotropy of the mechanical properties of the material, while smaller values contribute to an excessive growth of the ferrite grain during annealing and deterioration of the surface after stamping [5].
The roughness parameters were the average arithmetic deviation of the profile Ra, the number of protrusions n, the relative reference length of the profile tp, the maximum deviation of the profile Rmax.
In addition to the high adhesion strength of the layers, a number of requirements are imposed on the bimetallic strips of brass-steel-brass in terms of dimensional accuracy, mechanical properties and microstructure [16].
The relative reduction during cladding affects the bonding strength of bimetal layers, the nature of the microstructure, the size of the recrystallized grains, the mechanical properties of the strip, the dimensional accuracy [4].
Large values of the joint degree of deformation lead to excessive grinding of grains after the recrystallization process and an increase in the anisotropy of the mechanical properties of the material, while smaller values contribute to an excessive growth of the ferrite grain during annealing and deterioration of the surface after stamping [5].
The roughness parameters were the average arithmetic deviation of the profile Ra, the number of protrusions n, the relative reference length of the profile tp, the maximum deviation of the profile Rmax.
Online since: February 2014
Authors: Xiao Pin Wang, Yi Hui Li, Cou Hua Zhu
Then the roughness of the activated carbon increases and the size of graphite crystallite of GAC is also greatly reduced, showing obvious trend of fine grains.
On the one hand, the activated carbon could utilize the iron oxide and manganese oxide to increase the amount of oxygen-containing groups; on the other hand, the acid pretreatment and mixing are used to enhance its fine grains.
It means that the number of carboxyl groups on the surface of the activated carbon is represented by the consumption of sodium bicarbonate; the number of lactone groups is represented by the consumption of sodium bicarbonate and sodium carbonate; the number of phenolic hydroxyl groups is represented by the consumption of sodium carbonate and sodium hydroxide.
The large number of micropores is huge and the consistent luster at many locations reveals that there are no obvious loading substances on the surface of the activated carbon.
On the one hand, the activated carbon could utilize the iron oxide and manganese oxide to increase the amount of oxygen-containing groups; on the other hand, the acid pretreatment and mixing are used to enhance its fine grains.
It means that the number of carboxyl groups on the surface of the activated carbon is represented by the consumption of sodium bicarbonate; the number of lactone groups is represented by the consumption of sodium bicarbonate and sodium carbonate; the number of phenolic hydroxyl groups is represented by the consumption of sodium carbonate and sodium hydroxide.
The large number of micropores is huge and the consistent luster at many locations reveals that there are no obvious loading substances on the surface of the activated carbon.
Online since: March 2015
Authors: Petre Badica, Dan Batalu, Mihail Burdusel, Gheorghe Aldica
In bulk samples, oxygen can form nanometer-sized coherent precipitates of MgB2-xOx or MgO particles inside the MgB2 grains.
MgO or BOx layers are also present at the grain boundaries [9].
The MgO layers decrease the grain connectivity, and the Jc, respectively.
This is perhaps because in the Bean model, for the determination of Jc, the grain size was used instead of the sample size.
This is important to avoid the coarsening of the particles (of both MgB2 and the impurity phases) and the decrease of the number of grain boundaries that are well known to provide excellent pinning centers in MgB2.
MgO or BOx layers are also present at the grain boundaries [9].
The MgO layers decrease the grain connectivity, and the Jc, respectively.
This is perhaps because in the Bean model, for the determination of Jc, the grain size was used instead of the sample size.
This is important to avoid the coarsening of the particles (of both MgB2 and the impurity phases) and the decrease of the number of grain boundaries that are well known to provide excellent pinning centers in MgB2.
Online since: March 2019
Authors: Ojiyed Tegus, Zhan Quan Yao, Li Juan Zhao, Xiao Tian, Xuan Zhao
Moreover, the decrease in lattice parameters of A2 phase in the ternary alloys may be attributed to the decrease of the number of Ga atoms dissolved in the A2 matrix.
As shown in Fig.2(b), the grains display a columnar structure with fine grains and the grain boundary morphology becomes thick.
It can be seen from Fig.2(c) and (d) that the grain size tends to be smaller and the morphology of the crystal presents dendritic structure.
Additionally, there is a deep color contrast of the structure at the grain boundaries of Y-doped alloys, which can be achieved by doping excessive doping of rare earth element yttrium.
At the grain boundary the ratio of the total amount of Fe and Ga to Y is nearly this value.
As shown in Fig.2(b), the grains display a columnar structure with fine grains and the grain boundary morphology becomes thick.
It can be seen from Fig.2(c) and (d) that the grain size tends to be smaller and the morphology of the crystal presents dendritic structure.
Additionally, there is a deep color contrast of the structure at the grain boundaries of Y-doped alloys, which can be achieved by doping excessive doping of rare earth element yttrium.
At the grain boundary the ratio of the total amount of Fe and Ga to Y is nearly this value.
Online since: September 2020
Authors: Ivan Petryshynets, Roman Kussa, Ihor Kushchenko, Volodymyr Andilakhai, Vadym Zurnadzhy, Vasily Efremenko
After holding up to 600 s the microstructure consisted of polygonal ferrite and lath martensite situated along the grain boundaries.
More coarse precipitates (shown by the double arrow in Fig. 3f) were preferentially found within the martensite areas to be associated with grain boundaries while fine nano-scaled carbides were mostly revealed inside the grains (shown by the single arrow).
The only difference was the higher number of fine carbide precipitates within ferrite grains and martensite areas (Figs. 4 (b, d, f)).
(4) The grain boundary strengthening was calculated by the Hall-Petch equation [28]: Dsgb=Kyd–1/2, (5) where Ky is a Petch slope (0.63 МPа×m–1/2), d is a grain diameter.
The average diameter of ferrite grain and the distance between the carbide precipitates were derived from high-magnification SEM images (Fig. 3) to be 140±12 nm and 6.7±0.3 mm accordingly.
More coarse precipitates (shown by the double arrow in Fig. 3f) were preferentially found within the martensite areas to be associated with grain boundaries while fine nano-scaled carbides were mostly revealed inside the grains (shown by the single arrow).
The only difference was the higher number of fine carbide precipitates within ferrite grains and martensite areas (Figs. 4 (b, d, f)).
(4) The grain boundary strengthening was calculated by the Hall-Petch equation [28]: Dsgb=Kyd–1/2, (5) where Ky is a Petch slope (0.63 МPа×m–1/2), d is a grain diameter.
The average diameter of ferrite grain and the distance between the carbide precipitates were derived from high-magnification SEM images (Fig. 3) to be 140±12 nm and 6.7±0.3 mm accordingly.
Online since: January 2010
Authors: D.V. Edmonds
Foremost amongst these must surely be the
extended application of carbon steels, achieved principally through ferrite grain refinement by the
practice of microalloying coupled with controlled thermomechanical processing.
Limitations to strengthening ferrite/pearlite structures further by grain refinement or precipitation, however, has focused attention back to acicular forms of microstructure.
However, despite these commendable successes in steel development approaching the 21 st century, it has always been realized that further developments in strength, ductility and toughness combinations based upon precipitation-hardened fine-grained ferritic microstructures would be limited.
The term "acicular ferrite" deployed here refers to a non-polygonal ferrite component formed above the Bs temperature, dependent upon the Mo concentration, conferring effective grain refinement and introducing dislocation sub-structure to achieve strength and processing characteristics, e.g.
Multi-Phase, Duplex or Dual Phase Steels A number of interesting mixed microstructures combining, generally, ferrite with either martensite or bainite, or both, have been developed over recent decades.
Limitations to strengthening ferrite/pearlite structures further by grain refinement or precipitation, however, has focused attention back to acicular forms of microstructure.
However, despite these commendable successes in steel development approaching the 21 st century, it has always been realized that further developments in strength, ductility and toughness combinations based upon precipitation-hardened fine-grained ferritic microstructures would be limited.
The term "acicular ferrite" deployed here refers to a non-polygonal ferrite component formed above the Bs temperature, dependent upon the Mo concentration, conferring effective grain refinement and introducing dislocation sub-structure to achieve strength and processing characteristics, e.g.
Multi-Phase, Duplex or Dual Phase Steels A number of interesting mixed microstructures combining, generally, ferrite with either martensite or bainite, or both, have been developed over recent decades.
Online since: June 2005
Authors: Mattison K. Ferber, Hua Tay Lin
ABSTRACT
Over the last 30 years, a number of programs in Russia, Europe, Japan, and the United
States have sought to introduce monolithic ceramic components into gas turbines with
the goals of increasing efficiency and lowering emissions.
INTRODUCTION Over the last 30 years, a number of programs in the United States have sought to introduce monolithic ceramic components into gas turbines with the goals of increasing operating temperature and hence increasing efficiency [1] and lowering emissions.
For lean burn conditions, k for a number of SiC based materials is found to be well described by the expression, k (mg/cm2 h) = 2.04 exp(-108 kJ/mole/RT) v 1/2 Ptotal 3/2 (2) where T is the absolute temperature (K), Ptotal is the total pressure (atm), and v is the velocity (m/s).
Instead, extensive degradation of the silicon nitride grains was observed.
Specifically many of the elongated grains were found to fragmented into small particles.
INTRODUCTION Over the last 30 years, a number of programs in the United States have sought to introduce monolithic ceramic components into gas turbines with the goals of increasing operating temperature and hence increasing efficiency [1] and lowering emissions.
For lean burn conditions, k for a number of SiC based materials is found to be well described by the expression, k (mg/cm2 h) = 2.04 exp(-108 kJ/mole/RT) v 1/2 Ptotal 3/2 (2) where T is the absolute temperature (K), Ptotal is the total pressure (atm), and v is the velocity (m/s).
Instead, extensive degradation of the silicon nitride grains was observed.
Specifically many of the elongated grains were found to fragmented into small particles.