Enhanced Gas Sensing Properties of Different ZnO 3D Hierarchical Structures

Article Preview

Abstract:

Six different ZnO nanomorphologies were synthesized trough wet chemical routes starting from a water solution of zinc nitrate hexahydrate, obtaining two types of morphologies: bidimensional nanocrystals and nanoparticles aggregates. Powders and films characterizations have been carried out by means of TG–DTA, SEM, and X-ray diffraction analysis. Finally, electrical measurements were performed with the aim to compare conductive properties of the thick films, surface barrier heights and gas sensing features, mainly versus acetone and other VOCs related to the breath gas analysis. Among the different morphologies tested, it turned out that the samples constituted by nanoparticle aggregates exhibited the best performances versus all gases, but especially toward acetone at sub-ppm level.

You might also be interested in these eBooks

Info:

Periodical:

Pages:

48-53

Citation:

Online since:

October 2016

Export:

Price:

Permissions CCC:

Permissions PLS:

Сopyright:

© 2017 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

* - Corresponding Author

[1] Jon s. Wilson (Ed. ), Sensor technology Handbook, Elsevier Inc., (2005).

Google Scholar

[2] M.C. Carotta, M. Benetti, E. Ferrari, A. Giberti, C. Malagù, M. Nagliati, B. Vendemiati, G. Martinelli, Basic interpretation of thick film gas sensors for atmospheric application, Sens. Actuators B 126 (2007) 672–677.

DOI: 10.1016/j.snb.2007.04.016

Google Scholar

[3] Sheng Xu and Zhong Lin Wang, One-Dimensional ZnO Nanostructures: Solution Growth and Functional Properties, Nano Res. (2011) DOI 10. 1007/s12274-011-0160-7.

Google Scholar

[4] P.K. Clifford, D.T. Tuma, Characteristics of semiconductor gas sensors – II. Transient response to temperature change, Sens. Actuators 3 (83) (1982) 255–282.

DOI: 10.1016/0250-6874(82)80027-9

Google Scholar

[5] K. -H. Kim, Shamin Ara Jahan, Ehsanul Kabir, A review of breath analysis for diagnosis of human health, Trends in Analytical Chemistry 33 (2012) 1-8.

Google Scholar

[6] Il-Doo Kim, Seon-Jin Choi, Sang-Joon Kim and Ji-Su Jang (2015): Exhaled Breath Sensors. In: C. -M. Kyung (ed. ), Smart Sensors for Health and Environment Monitoring, KAIST Research Series, DOI 10. 1007/978-94-017-9981-2_2.

DOI: 10.1007/978-94-017-9981-2_2

Google Scholar

[7] M.C. Carotta, A. Cervi, V. di Natale, S. Gherardi, A. Giberti, V. Guidi, D. Puzzovio, B. Vendemiati, G. Martinelli, M. Sacerdoti, D. Calestani, A. Zappettini, M. Zha, L. Zanotti, ZnO gas sensors: A comparison between nanoparticles and nanotetrapodes-based thick films, Sensors and Actuators B 137 (2009).

DOI: 10.1016/j.snb.2008.11.007

Google Scholar