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Online since: April 2011
Authors: Wei Jun Liu, Shou Zhi Pu, Cong Bin Fan
Photochromic Fluorescence Switching Diarylethene Flanking a Methoxy Group
Congbin Fan, Shouzhi Pu*, Weijun Liu
Jiangxi Key Laboratory of Organic Chemistry, Jiangxi Science and Technology Normal University, Nanchang 330013, P.
Being able to reversibly alter molecular structure and function is equally essential if a molecule’s structure can be reversibly modified in a controllable and predictable manner, their properties can be regulated.
Because light can be easily tuned and long-distance transmitted, it is a particularly appealing stimulus to spatially and temporally trigger changes in the structure of molecules and function of materials [7].
diarylethene 1 and reference may be attribute to the structure and the electron-donating group.
Being able to reversibly alter molecular structure and function is equally essential if a molecule’s structure can be reversibly modified in a controllable and predictable manner, their properties can be regulated.
Because light can be easily tuned and long-distance transmitted, it is a particularly appealing stimulus to spatially and temporally trigger changes in the structure of molecules and function of materials [7].
diarylethene 1 and reference may be attribute to the structure and the electron-donating group.
Online since: May 2017
Authors: Koichi Nakamura, Ahmed Abd El-Moneim, Mohamed Abd El Naser Mansour
Effect of Copper Addition on Mechanical Properties of Nanostructured Pb1-xCuxTe Thermoelectric Alloy Systems by Nanoindentation
Mohamed Abd El-Naser Mansour1,2,a, Ahmed AbdEL-Moneim1,3,b,
and Koichi Nakamura1,4,c
1Materials Science and Engineering Department, Egypt-Japan University of Science and Technology, New Borg El-Arab, Alexandria 21934, Egypt
2Production Engineering & Mechanical Design Department, Faculty of Engineering,
Port-Said University, Port-Said 42111, Egypt
3Physical Chemistry Department, National Research Centre 12622, Cairo, Egypt
4Center for the Promotion of Interdisciplinary Education and Research, Kyoto University,
Kyoto 615-8540, Japan
amohamed.mansour@ejust.edu.eg, bAhmed.abdelmoneim@ejust.edu.eg, ckoichi@cpier.kyoto-u.ac.jp
Keywords: Thermoelectric, PbTe, Cu, nanoindentation, hardness, Young’s modulus.
The crystal structure of all samples was confirmed by X-ray diffraction (XRD, RD-6100; Shimadzu) at room temperature using Cu Kα radiation.
The patterns in Fig. 4 confirm the rock-salt structure with most intense reflection at 2θ of 28.18° (for (200) plane) [1, 17-21].
The absence of diffraction peaks other than those of the rock-salt structure of PbTe discards the possibility of the formation of impurity phases and confirms the Cu doping.
Such peak shift is corresponding to the volume expansion of the alloy structure, which will affect defects like lattice defects as Cu doping increases.
The crystal structure of all samples was confirmed by X-ray diffraction (XRD, RD-6100; Shimadzu) at room temperature using Cu Kα radiation.
The patterns in Fig. 4 confirm the rock-salt structure with most intense reflection at 2θ of 28.18° (for (200) plane) [1, 17-21].
The absence of diffraction peaks other than those of the rock-salt structure of PbTe discards the possibility of the formation of impurity phases and confirms the Cu doping.
Such peak shift is corresponding to the volume expansion of the alloy structure, which will affect defects like lattice defects as Cu doping increases.
Online since: May 2014
Authors: Ai Dong Tang, Mei Long, Lin Tan
The Effects of Electroplating Conditions on the Morphology and Glucose Oxidation Performance of Cu2O/TiO2
Mei LONG1, Lin TAN1, Ai-dong TANG*1, 2
School of Chemistry and Chemical Engineering, Central South University, Changsha, 410083, P.R.China;
tangaidong@126.com
Keywords: Cu2O nanoparticles, TiO2 nanotube arrays, Non-enzymatic glucose oxidation, Electrocatalysis.
As the deposition potential increased, and the preparation time of the samples kept 5 min, it can be observed that some crystals with octahedral shape were uniformly embedded into the TNT structure including both the surface and internal, external walls of TNT ((d) and (e)).
These results indicated that -0.4 V and -0.5 V were too low to deposite Cu2O on TNT at short time; when the deposition potential reached to -0.6 V, there were Cu2O particles that embedded into the TNT structure clearly.
The crystal structure was shown in Fig.3B.
Conclusions (a) The effects of the detail fabricate condition such as deposition potential and CuSO4 concentration on the crystal structure, morphology and property of Cu2O/TNT electrode were investigated.
As the deposition potential increased, and the preparation time of the samples kept 5 min, it can be observed that some crystals with octahedral shape were uniformly embedded into the TNT structure including both the surface and internal, external walls of TNT ((d) and (e)).
These results indicated that -0.4 V and -0.5 V were too low to deposite Cu2O on TNT at short time; when the deposition potential reached to -0.6 V, there were Cu2O particles that embedded into the TNT structure clearly.
The crystal structure was shown in Fig.3B.
Conclusions (a) The effects of the detail fabricate condition such as deposition potential and CuSO4 concentration on the crystal structure, morphology and property of Cu2O/TNT electrode were investigated.
Online since: December 2013
Authors: M. Khairul Zaimy A. Ghani, Anika Zafiah M. Rus, Najibah A. Latif
The other researcher was using liquid moulding techniques to fabricate metal foam composite sandwich structure is gaining recognition for high performance applications in a variety of commercial and defence industries [8,9].
Based on the Table 1, the density of HDB flexible is higher than density of HDB rigid which is 1.408 and 1.300 g/cm3 respectively; due to the porosity structure of both biopolymer samples.
The structure morphologies according to the SEM results were influence the sound damping on HDB.
It can be summarized from the mass, density and characteristic of the HDB structure as shown in SEM are influence the sound absorption of the system.
Frish, Polyurethanes Chemistry and Technology, John Wiley & Sons (1962) [7] H.
Based on the Table 1, the density of HDB flexible is higher than density of HDB rigid which is 1.408 and 1.300 g/cm3 respectively; due to the porosity structure of both biopolymer samples.
The structure morphologies according to the SEM results were influence the sound damping on HDB.
It can be summarized from the mass, density and characteristic of the HDB structure as shown in SEM are influence the sound absorption of the system.
Frish, Polyurethanes Chemistry and Technology, John Wiley & Sons (1962) [7] H.
Online since: January 2013
Authors: Rui Yang, Shi Chao Zhang, Xiao Fang Bi, Lan Zhang
Among the polyelectrolyte materials, PEO is mostly studied as a host for ions because of its flexible macromolecular structure and good ability of the ion dissociation.
Many efforts have been made to suppress the crystallinity and lower the glass transition temperature, such as polymer structure modification, introduction of the inorganic fillers and plasticizers [5–12].On the other hand, lithium ion transference number of the polymer electrolytes is another important factor to be required for practical battery application as well as the ionic conductivity.
Herein, we investigate the influence of LiClO4 concentration on the structure, morphology, and conductivity of the PEO+PLiAA+LiClO4 polymer electrolyte by X-ray diffraction (XRD), differential scanning calorimetry (DSC) and impedance techniques.
Results and discussion The X-ray diffraction analysis is a useful tool to determine the structure and crystallization of the polymer matrices.
The Royal Society of Chemistry, London, 1997 [12] F.
Many efforts have been made to suppress the crystallinity and lower the glass transition temperature, such as polymer structure modification, introduction of the inorganic fillers and plasticizers [5–12].On the other hand, lithium ion transference number of the polymer electrolytes is another important factor to be required for practical battery application as well as the ionic conductivity.
Herein, we investigate the influence of LiClO4 concentration on the structure, morphology, and conductivity of the PEO+PLiAA+LiClO4 polymer electrolyte by X-ray diffraction (XRD), differential scanning calorimetry (DSC) and impedance techniques.
Results and discussion The X-ray diffraction analysis is a useful tool to determine the structure and crystallization of the polymer matrices.
The Royal Society of Chemistry, London, 1997 [12] F.
Online since: July 2018
Authors: Peerapan Dittanet, Paweena Prapainainar, Surapich Loykulnant, Wapoon Tappanawatch, Pongdhorn Sae-Oui
CNC or nanocellulose with rod-like nanosized structures obtained from native cellulose can be synthesized by acid hydrolysis.
In addition, the peak at 1061 cm-1 is characteristic of C-O stretching of cellulose since cellulose is classified as a carbohydrate due to its polysaccharide molecular structure while the peak at 897 cm−1 corresponds to the C-H rock vibrations of the cellulose [5].
All samples possess similar XRD diffraction peaks at 16˚ and 22.6˚, which are characteristic of crystal structure of cellulose I.
Altered CNC structures were obtained by acid hydrolysis with 64 wt% sulfuric acid (H2SO4) at different reaction times (30, 45, 60 min) and revealed that the degree of crystallinity of CNC was found to increase with increasing acid hydrolysis time.
[7] Khalil Ahmed, Shaikh Sirajuddin Nizami, Nudrat Zahid Raza and Khalid Mahmood, International Journal of Industrial Chemistry Vol. 3 (2012), p.21
In addition, the peak at 1061 cm-1 is characteristic of C-O stretching of cellulose since cellulose is classified as a carbohydrate due to its polysaccharide molecular structure while the peak at 897 cm−1 corresponds to the C-H rock vibrations of the cellulose [5].
All samples possess similar XRD diffraction peaks at 16˚ and 22.6˚, which are characteristic of crystal structure of cellulose I.
Altered CNC structures were obtained by acid hydrolysis with 64 wt% sulfuric acid (H2SO4) at different reaction times (30, 45, 60 min) and revealed that the degree of crystallinity of CNC was found to increase with increasing acid hydrolysis time.
[7] Khalil Ahmed, Shaikh Sirajuddin Nizami, Nudrat Zahid Raza and Khalid Mahmood, International Journal of Industrial Chemistry Vol. 3 (2012), p.21
Online since: September 2020
Authors: Mikhail N. Palatnikov, Sofia M. Masloboeva, Larisa G. Arutyunyan
Arutyunyanc
Tananaev Institute of Chemistry – Subdivision of the Federal Research Centre
«Kola Science Centre of the Russian Academy of Sciences»,
184209, Murmansk region, Apatity, Akademgorodok 26a, Russia
asofia_masloboeva@mail.ru, bm.palatnikov@ksc.ru, clarisa7500@bk.ru
Keywords: lithium tantalate, charge, doping, rare-earth elements, synthesis, crystals, ceramics.
With the beginning of the practical use of optical devices based on periodically polarized structures [3, 4], interest towards technology and the study of the properties of LiTaO3 single crystals has significantly increased.
This allows manufacture of optical radiation converters on periodically polarized structures on the base of lithium tantalate crystals.
Lisjikh, As-grown domain structure in lithium tantalate with spatially nonuniform composition, Ferroelectrics 525 (2018) 47‒53
Asaka Crystal structures and enhancement of photoluminescence intensities by effective doping for lithium tantalate phosphors, Powder Diffraction 30 (2015) 326‒332
With the beginning of the practical use of optical devices based on periodically polarized structures [3, 4], interest towards technology and the study of the properties of LiTaO3 single crystals has significantly increased.
This allows manufacture of optical radiation converters on periodically polarized structures on the base of lithium tantalate crystals.
Lisjikh, As-grown domain structure in lithium tantalate with spatially nonuniform composition, Ferroelectrics 525 (2018) 47‒53
Asaka Crystal structures and enhancement of photoluminescence intensities by effective doping for lithium tantalate phosphors, Powder Diffraction 30 (2015) 326‒332
Introduction to High-Throughput Sequencing Technologies and Review of its Application in Bioleaching
Online since: August 2017
Authors: Pang Lei, Shuang Bo Yang, Shuang Zhou, Bao Jun Yang, Min Gan, Xue Duan Liu
Therefore, understanding the microbial structure and function in bioleaching relies on innovation of the detection method.
Next generation sequencing technology for microbial structure analysis.
It was founded that leaching efficiency showed a positive and significant relationship with microbial diversity, and the compositions of substrates could alter the microbial community structure and diversity.
The usage of high-throughput sequencing approaches will enable gene surveys to show the variation of community structure under different bioleaching conditions.
Piel, Cultivation-independent approaches to investigate the chemistry of marine symbiotic bacteria, Phytochem.
Next generation sequencing technology for microbial structure analysis.
It was founded that leaching efficiency showed a positive and significant relationship with microbial diversity, and the compositions of substrates could alter the microbial community structure and diversity.
The usage of high-throughput sequencing approaches will enable gene surveys to show the variation of community structure under different bioleaching conditions.
Piel, Cultivation-independent approaches to investigate the chemistry of marine symbiotic bacteria, Phytochem.
Online since: May 2015
Authors: Mohammed Gamil, Sahour Sayed, Ahmed Abd El Moneim Abd Elmoneim, Ahmed M.R. Fath El-Bab
The use of strain gauges is the most common way to detect dimensional changes in large structures as well as in delicate electronic applications.
Graphene has excellent electrical and mechanical properties, in addition to the merit of planar structure which makes it easily patterned if compared to CNTs [2].
Therefore; graphene-based flexible devices are attracting great attention due to the excellent properties of graphene regarding its planar structure, flexibility and high electron mobility as well as high strength [11, 12].
The images illustrate the overlapped flakes structure of the graphene film; the continuity of the flakes is held together by electrostatic forces (Van der Waals forces).
Saito: Physical Chemistry Chemical Physics Vol. 9 (2007), p. 1276 [22] Z.
Graphene has excellent electrical and mechanical properties, in addition to the merit of planar structure which makes it easily patterned if compared to CNTs [2].
Therefore; graphene-based flexible devices are attracting great attention due to the excellent properties of graphene regarding its planar structure, flexibility and high electron mobility as well as high strength [11, 12].
The images illustrate the overlapped flakes structure of the graphene film; the continuity of the flakes is held together by electrostatic forces (Van der Waals forces).
Saito: Physical Chemistry Chemical Physics Vol. 9 (2007), p. 1276 [22] Z.
Online since: August 2018
Authors: Da Ming Du, Fang Wang, Rui Hua Wang, Ai Xia Chen, Jie Guang Song, Cai Wen Li, Cheng Wei Hao, Lin Chen, Qiu Min Zou
Preparation and Characterization of Al2O3-Al Cermet with Coated Microstructure Using Powder Metallurgy Method
Ruihua Wang1, Aixia Chen1,a, Daming Du1, Fang Wang1, Caiwen Li1,
Qiumin Zou1, Jieguang Song2,b, Lin Chen2, Chengwei Hao3
1Engineering & Technology Research Center for Materials Surface Remanufacturing of Jiangxi Province, Jiujiang University, Jiujiang 332005 China
2Key Laboratory for Industrial Ceramics of Jiangxi Province, School of Materials and Chemistry Engineering, Pingxiang University, Pingxiang 337055 China
3School of Architecture and Civil Engineering, West Anhui University, Luan 237012, China
a93618054@qq.com, bsongjieguang@163.com
Keywords: Cermet; Al2O3; Al; coated microstructure; powder metallurgy method.
In this paper, the composite were prepared via the powder metallurgy method, because the powder metallurgy method is the first to manufacture metal matrix composite method, it can be prepared to enhance the volume fraction of very high levels of metal matrix composites, and is not the type of alloy matrix and reinforcing the type of restriction and attention[7-9].While the Al2O3 and Al combined to form a composite material having a special coated structure, the effectively improve the interface performance between the Al2O3 and Al is few studied, Al2O3-Al cermet with an coated microstructure are prepared by adjusting the preparing process in the paper, which provides the reference basis for the development to get good wear resistance, low thermal conductivity of the metal ceramic material.
The reasons for this phenomenon that the beginning of the sintering temperature is relatively low as the sample in the sintering process, when the sintering temperature is gradually increased, the sample porosity will be with the internal temperature increases as the declining, So that the internal structure of the sample also become more dense.
Because the melting point of Al is 660℃, the melting point of Al2O3 is 2050℃, the sintering temperature of sample is 900℃, Al powder is completely melted, while the Al2O3 powder is not, the combination type is mechanical bonding, the microstructure shows non-sintering densification and loose structure, Al is a dense phase with respect to Al2O3, and Al2O3 is non-dense phase.
And the prepared Al2O3-Al cermet adding sintering aids has a coated structure, which indicates that the large number of particles is migrated on the grain boundary during the sintering process, it improves to form the coated particles, the particles and particles effectively bonded to enhance the sample all aspects of performance.
In this paper, the composite were prepared via the powder metallurgy method, because the powder metallurgy method is the first to manufacture metal matrix composite method, it can be prepared to enhance the volume fraction of very high levels of metal matrix composites, and is not the type of alloy matrix and reinforcing the type of restriction and attention[7-9].While the Al2O3 and Al combined to form a composite material having a special coated structure, the effectively improve the interface performance between the Al2O3 and Al is few studied, Al2O3-Al cermet with an coated microstructure are prepared by adjusting the preparing process in the paper, which provides the reference basis for the development to get good wear resistance, low thermal conductivity of the metal ceramic material.
The reasons for this phenomenon that the beginning of the sintering temperature is relatively low as the sample in the sintering process, when the sintering temperature is gradually increased, the sample porosity will be with the internal temperature increases as the declining, So that the internal structure of the sample also become more dense.
Because the melting point of Al is 660℃, the melting point of Al2O3 is 2050℃, the sintering temperature of sample is 900℃, Al powder is completely melted, while the Al2O3 powder is not, the combination type is mechanical bonding, the microstructure shows non-sintering densification and loose structure, Al is a dense phase with respect to Al2O3, and Al2O3 is non-dense phase.
And the prepared Al2O3-Al cermet adding sintering aids has a coated structure, which indicates that the large number of particles is migrated on the grain boundary during the sintering process, it improves to form the coated particles, the particles and particles effectively bonded to enhance the sample all aspects of performance.