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Online since: October 2007
Authors: Mónica Campos, José Manuel Torralba, Elena Gordo Odériz, Elisa Maria Ruiz-Navas, D. Ruiz-Amador, Antonia Jiménez-Morales, María Eugenia Rabanal
Introduction
The Powder Technology Group (PTG) in the University Carlos III of Madrid is a multidisciplinary
working group formed by doctors from different disciplines (such as Physics, Chemistry and
Engineering).
The nanoparticle morphology, crystalline and chemical structure were studied by XRD, SEM and EDS, and TEM.
The low magnification bright field images permit to identify the structure and the growth "small primary nanoparticles" through the collision/coalescence mechanisms.
Figure 10a is a low magnification bright field image that permits to identify the structure of primary nanoparticles through the collision/coalescence mechanisms.
The nanoparticle morphology, crystalline and chemical structure were studied by XRD, SEM and EDS, and TEM.
The low magnification bright field images permit to identify the structure and the growth "small primary nanoparticles" through the collision/coalescence mechanisms.
Figure 10a is a low magnification bright field image that permits to identify the structure of primary nanoparticles through the collision/coalescence mechanisms.
Online since: June 2010
Authors: S. Buddhudu, B. Sudhakar Reddy
In the structure of
borate glasses, there are random network of BO3 triangles with certain fraction of boroxol (sixmembered)
rings [40].
Earlier, neutron scattering experiments and Raman spectral studies [47] on TeO2 glasses containing different modifiers have revealed that basic building blocks of TeO2 structure could be a triogonal bipyramid commonly called TeO4E, where one of three equatorial directions is occupied by the 5s2 electronic pair (E) of the tellurium atom with two equatorial bonds of lengths 1.91 Å and the two axial bonds of lengths 2.08 Å [48,49].
N.A.Choneun, Proceedings of Egyptian Conference of Chemistry,Cairo, Egypt, (1996) 162. 44.
Excited state phenomenon in vitreous materials, in hand book on the physics and chemistry of rare earths., North Holland, Asterdam, 1987 55.
Earlier, neutron scattering experiments and Raman spectral studies [47] on TeO2 glasses containing different modifiers have revealed that basic building blocks of TeO2 structure could be a triogonal bipyramid commonly called TeO4E, where one of three equatorial directions is occupied by the 5s2 electronic pair (E) of the tellurium atom with two equatorial bonds of lengths 1.91 Å and the two axial bonds of lengths 2.08 Å [48,49].
N.A.Choneun, Proceedings of Egyptian Conference of Chemistry,Cairo, Egypt, (1996) 162. 44.
Excited state phenomenon in vitreous materials, in hand book on the physics and chemistry of rare earths., North Holland, Asterdam, 1987 55.
Online since: October 2015
Authors: Robert C. Pullar
The structure, solid state chemistry and magnetic properties of the relevant hexaferrites will be briefly covered in section 3, and we will look at the potential of aligned hexaferrite fibres, nanofibres and nanowires, composites and magnetoelectric materials in sections 2.3 and 2.4.
2.
For a comprehensive review of all hexaferrites ceramics, their solid state chemistry and their properties, see reference [2].
A perspective view of the structure is shown in fig. 12b, while fig. 12c depicts the stacking of the R and S blocks in the M structure.
(b) Perspective view of the Z structure [61]. 3.1.6.
As BaM is the most commercially important hexagonal ferrite, its solid state chemistry has been studied in much greater detail than that of the other hexagonal ferrites.
For a comprehensive review of all hexaferrites ceramics, their solid state chemistry and their properties, see reference [2].
A perspective view of the structure is shown in fig. 12b, while fig. 12c depicts the stacking of the R and S blocks in the M structure.
(b) Perspective view of the Z structure [61]. 3.1.6.
As BaM is the most commercially important hexagonal ferrite, its solid state chemistry has been studied in much greater detail than that of the other hexagonal ferrites.
Online since: March 2025
Authors: A. Kandasamy, B. Ramesh
This network structure gives GMB their characteristic strength and durability[10].
Additionally, the fine particles in clay contribute to the mechanical strength of the GMB by enabling a dense packing structure.
Acoustic Insulation: (a) Dense Packing and Solid Structure: Beyond thermal insulation, GMB also excel in acoustic insulation.
Davidovits, Geopolymer chemistry and applications.
Han et al., “Smart concretes and structures: A review,” J.
Additionally, the fine particles in clay contribute to the mechanical strength of the GMB by enabling a dense packing structure.
Acoustic Insulation: (a) Dense Packing and Solid Structure: Beyond thermal insulation, GMB also excel in acoustic insulation.
Davidovits, Geopolymer chemistry and applications.
Han et al., “Smart concretes and structures: A review,” J.
Online since: November 2018
Authors: Dinesh Shinde, Kishore N. Mistry, Suyog Jhavar, Sunil Pathak
This is because, the filler with crystalline structure gives more strength, resistance to rupture, etc.
Compression pressure must increase gradually to reduce the formation of the porous structure of the terminal material.
Royal Society of Chemistry Advances, 4 (2014) 36777–36783
Quantitative analysis of heavy metals in automotive brake linings: A comparison between wet-chemistry based analysis and in-situ screening with a handheld X-ray fluorescence spectrometer.
Compression pressure must increase gradually to reduce the formation of the porous structure of the terminal material.
Royal Society of Chemistry Advances, 4 (2014) 36777–36783
Quantitative analysis of heavy metals in automotive brake linings: A comparison between wet-chemistry based analysis and in-situ screening with a handheld X-ray fluorescence spectrometer.
Online since: October 2010
Authors: Tatsuya Kodama, Nobuyuki Gokon
Two-Step Thermochemical Cycles for High-Temperature Solar Hydrogen Production
Tatsuya Kodama 1, a and Nobuyuki Gokon2,b
1Department of Chemistry & Chemical Engineering, Faculty of Engineering, Niigata University, 8050 Ikarashi 2-nocho, Nishi-ku, Niigata 950-2181, Japan
2Center for Transdisciplinary Research, Niigata University, 8050 Ikarashi 2-nocho, Nishi-ku, Niigata 950-2181, Japan
atkodama@eng.niigata-u.ac.jp, bngokon@eng.niigata-u.ac.jp
Keywords: Thermochemical cycle, High-temperature solar heat, Hydrogen, Water-splitting, Solar reactor.
The structure of the reactor is illustrated in Fig. 3a.
The SNL researchers first produced prototypes of the ferrite fins using a SNL-developed rapid prototyping technique called “Robocasting” that is capable of manufacturing monolithic ceramic structures with complex three-dimensional geometries [18].
A small three-dimensional monolithic lattice structure comprised of a Co-ferrite/zirconia mixture was produced and tested in the water splitting cycle involving thermal reduction at 1400˚C (heating rate = 50˚C/min) and subsequent hydrolysis at 1100˚C using an electric furnace.
The structure of the reactor is illustrated in Fig. 3a.
The SNL researchers first produced prototypes of the ferrite fins using a SNL-developed rapid prototyping technique called “Robocasting” that is capable of manufacturing monolithic ceramic structures with complex three-dimensional geometries [18].
A small three-dimensional monolithic lattice structure comprised of a Co-ferrite/zirconia mixture was produced and tested in the water splitting cycle involving thermal reduction at 1400˚C (heating rate = 50˚C/min) and subsequent hydrolysis at 1100˚C using an electric furnace.
Online since: November 2025
Authors: Denis Andrei Predu, Cristian State
The thermoplasticity of the thin filament, or its ability to form inter-layer bonds during printing and subsequently solidify at ambient temperature post-printing, is a critical factor in FDM, as the structures are constructed from layers of the filament.
It is utilized in applications such as wearable technology and energy-absorbing structures that require high flexibility.
Chemical structure of Thermoplastic Polyurethane [21].
[19] Naba Kumar Kalita, Minna Hakkarainen, Integrating biodegradable polyesters in a circular economy, Current Opinion in Green and Sustainable Chemistry Volume 40, 2023, 100751, ISSN 2452-2236
It is utilized in applications such as wearable technology and energy-absorbing structures that require high flexibility.
Chemical structure of Thermoplastic Polyurethane [21].
[19] Naba Kumar Kalita, Minna Hakkarainen, Integrating biodegradable polyesters in a circular economy, Current Opinion in Green and Sustainable Chemistry Volume 40, 2023, 100751, ISSN 2452-2236
Online since: June 2022
Authors: Sujan Debnath, Dominick Wong, Izman Sudin, Abdul Hamid, Alokesh Pramani, Mahmood Anwar, A.K. Basak
Petousis, “Effect of stacking sequence on the performance of hybrid natural/synthetic fiber reinforced polymer composite laminates,” Composite Structures, vol. 276, pp. 114525, 2021
Jawaid, “Mechanical, morphological, structural and dynamic mechanical properties of alkali treated Ensete stem fibers reinforced unsaturated polyester composites,” Composite Structures, vol. 207, pp. 589-597, 2019
Ng, “The effect of alkaline treatments soaking time on oil palm empty fruit bunch (OPEFB) fibre structure,” Journal of Physics: Conference Series, vol. 908, pp. 012033, 2017
Kausch, "Fracture behaviour of epoxy resins," Chemistry and Technology of Epoxy Resins, B.
Jawaid, “Mechanical, morphological, structural and dynamic mechanical properties of alkali treated Ensete stem fibers reinforced unsaturated polyester composites,” Composite Structures, vol. 207, pp. 589-597, 2019
Ng, “The effect of alkaline treatments soaking time on oil palm empty fruit bunch (OPEFB) fibre structure,” Journal of Physics: Conference Series, vol. 908, pp. 012033, 2017
Kausch, "Fracture behaviour of epoxy resins," Chemistry and Technology of Epoxy Resins, B.
Online since: February 2008
Authors: Graeme E. Murch, Manfred Martin, D. Samuelis, Irina V. Belova
Martin
2,d
1Diffusion in Solids Group
Centre for Geotechnical and Materials Modelling
School of Engineering, University of Newcastle
Callaghan NSW 2308 Australia
2Institute of Physical Chemistry
RWTH Aachen University
Landoltweg 2, 52056 Aachen Germany
a Irina.Belova@newcastle.edu.au,
b Graeme.Murch@newcastle.edu.au,
csamuelis@pc.rwthaachen.de,
dmartin@rwth-aachen.de
Keywords: cation diffusion, tracer diffusion, solid electrolytes, demixing, LSGM, YSZ
Abstract.
Four different cluster mechanisms are possible in the lanthanum gallate structure.
Schematic representation of the possible jumps of the vacancies in the cluster in the cubic perovskite structure.
It is seen that the maximum of this ratio is slightly under fourteen (this is analogous to the behaviour of the vacancy-pair mechanism in the B2 structure), whereas the maximum of DB* /DA * is likely to be well under ten. 0.2 0.5 1 2 5 10 20 1 10 100 1/wA Ratios of tracer diffusivities (b) 0.5 1 2 5 10 20 1 10 100 1/wB Ratios of tracer diffusivities (a) Figure 4.
Four different cluster mechanisms are possible in the lanthanum gallate structure.
Schematic representation of the possible jumps of the vacancies in the cluster in the cubic perovskite structure.
It is seen that the maximum of this ratio is slightly under fourteen (this is analogous to the behaviour of the vacancy-pair mechanism in the B2 structure), whereas the maximum of DB* /DA * is likely to be well under ten. 0.2 0.5 1 2 5 10 20 1 10 100 1/wA Ratios of tracer diffusivities (b) 0.5 1 2 5 10 20 1 10 100 1/wB Ratios of tracer diffusivities (a) Figure 4.
Online since: June 2013
Authors: Carmen Brinzila, Lurdes Ciríaco, Maria Jose Pacheco, Ana Lopes, Romeo Cristian Ciobanu
Professor Dimitrie Mangeron, no21-23, 700050, Iasi, Romania
2UMTP and Department of Chemistry, University of Beira Interior, 6200-001 Covilhã, Portugal
aemail, carmenbrinzila@gmail.com (corresponding author)
Keywords: Antibiotics, Boron Doped Diamond, Electrochemical degradation.
Pharmaceuticals named antibiotics are potent bioactive chemicals that can be grouped by either their chemical structure or mechanism of action, and can be divided into different subgroups such as β-lactams, quinolones, tetracyclines, macrolides, sulphonamides and others [1].
Tetracyclines (TC) are a group of natural and semisynthetic products characterized by four rings structure with a carboxylamide functional group and as side chains, several other ionizable functional groups which are responsible for their charge (Fig. 1).
Tetracycline chemical structure Several studies on degradation of tetracycline, using different technologies were conducted: using activated sludge processes [9], TiO2 nanopore arrays electrode [10], TiO2 and ZnO aqueous suspensions were also used in the photocatalytic oxidation of tetracycline, under simulated solar light [11], photocatalysis of TC with C–N–S tridoped TiO2 material [12], electron pulse radiolysis [14-17], using Pt plates as anode [14], with Ti/RuO2 anode [15].
Pharmaceuticals named antibiotics are potent bioactive chemicals that can be grouped by either their chemical structure or mechanism of action, and can be divided into different subgroups such as β-lactams, quinolones, tetracyclines, macrolides, sulphonamides and others [1].
Tetracyclines (TC) are a group of natural and semisynthetic products characterized by four rings structure with a carboxylamide functional group and as side chains, several other ionizable functional groups which are responsible for their charge (Fig. 1).
Tetracycline chemical structure Several studies on degradation of tetracycline, using different technologies were conducted: using activated sludge processes [9], TiO2 nanopore arrays electrode [10], TiO2 and ZnO aqueous suspensions were also used in the photocatalytic oxidation of tetracycline, under simulated solar light [11], photocatalysis of TC with C–N–S tridoped TiO2 material [12], electron pulse radiolysis [14-17], using Pt plates as anode [14], with Ti/RuO2 anode [15].