PZT Thin Films Deposited by RF Magnetron Sputtering

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PZT thin film was fabricated by using RF-sputtering process, and platinum was used as bottom electrodes. The sputtering gases were Ar:O2=25:0 sccm, Ar:O2=20:5 sccm, or Ar:O2=15:10 sccm. After sputtering, the PZT film was annealed for 5 minutes under O2 gas environment and at the temperature of 600 0C, 650 0C, 700 0C or 750 0C. To judge the quality of the deposited PZT film, its physical properties and electric properties were evaluated. The results indicate that the best crystallization temperature of PZT thin film is about 700 0C. Also, the roughness of the PZT thin film becomes larger with the increasing of annealing temperature. By adding more oxygen in the sputtering gas, one could have better crystallization of the PZT film. As for the electrical properties, the leakage current of PZT thin film increases with the increasing of annealing temperature. Furthermore, the ferroelectric property is affected by the crystallization amount of perovskite, the thickness of PZT thin film, and the diffusion situation between the bottom electrode and the PZT film.

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8-13

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February 2013

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© 2013 Trans Tech Publications Ltd. All Rights Reserved

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[1] C.H. Cheng, S.C. Chen, S.W. Young, Y.C. Lin, Effect of poling conditions on out-of-plane displacement for a shear mode PZT actuator, Sens. Actuators A. 126 (2006) 386-395.

DOI: 10.1016/j.sna.2005.10.036

Google Scholar

[2] Y.B. Jeon, R. Sood, J.H. Jeong, S.G. Kim, MEMS power generator with transverse mode thin film PZT, Sens. Actuators A. 122 (2005) 16-22.

DOI: 10.1016/j.sna.2004.12.032

Google Scholar

[3] L. Weng, X. Bao, S.C. Kwe, Effect of acetyl acetone on the preparation of PZT materials in Sol-gel processing, Mater. Sci. Eng. B. 96 (2002) 307-312.

Google Scholar

[4] C. Scmidi, E.P. Burte, MOCVD of ferroelectric thin films, Microelectron. Reliab. 39 (1999) 257-260.

Google Scholar

[5] H. Kurogi, Y. Yamagata, K. Ebihara, N. Inoue, Preparation of PZT thin films on YBCO electrodes by KrF excimer laser ablation technique, Surf. Coat. Technol. 100-101 (1998) 424-427.

DOI: 10.1016/s0257-8972(97)00663-4

Google Scholar

[6] K. Ebihara, F. Mitsugi, M. Yamazato, Y. Yamagata, Diamond-like carbon film deposition on PZT ferroelectrics and YBCO superconducting films using KrF excimer laser deposition, Composites Part B. 30 (1999) 685-689.

DOI: 10.1016/s1359-8368(99)00033-5

Google Scholar

[7] X.S. Li, K. Yamashita, T. Tanaka, Y. Souzki, M. Okuyama, Structural and electrical properties of highly oriented Pb(Zr, Ti)O3 thin film deposited by facing target sputtering, Sens. Actuators A. 82 (2000) 265-269.

DOI: 10.1016/s0924-4247(99)00307-6

Google Scholar

[8] Y. Jeong, H. Lee, S. Lee, J. Kim, H. Kim, S. Jeong, C. Cho, Annealing effect of platinum-based electrodes on physical properties of PZT thin films, Curr. Appl. Phys. 9 (2009) 115-119.

DOI: 10.1016/j.cap.2007.12.006

Google Scholar

[9] G. Velu, G. Remiens, Dielectric and ferroelectric properties of perovskite Pb(Zr, Ti)O3 films deposited by sputtering on Si substrate, Microelectron. Reliab. 39 (1999) 241-250.

DOI: 10.1016/s0026-2714(98)00216-9

Google Scholar

[10] K. Tsuchiya, T. Kitagawa, E. Nakamachi, Development of RF magnetron sputtering method to fabricate PZT thin film actuator, Precis. Eng. 27 (2003) 258-264.

DOI: 10.1016/s0141-6359(03)00006-0

Google Scholar

[11] C.H. Park, Y. Son, M. Won, Microstructure and ferroelectric properties of R. F. magnetron sputtering derived PZT thin films deposited on interlayer (PbO/TiO2), Microchem. J. 80 (2005) 201-206.

DOI: 10.1016/j.microc.2004.07.012

Google Scholar