Thermodynamic Study on the Sulfidation-Magnetic Roasting of the Hematite Type of Tin-Bearing Iron Ore

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Sulfidation-magnetic roasting process was used to treat tin-bearing iron ore of hematite to recovery iron resources. The results of thermodynamics analysis of the roasting reaction trait showed that, when CO concentration was lower than 11.43% at temperature higher than 873K, SnO2 and Fe2O3 could be selectively reduced to SnO and Fe3O4, respectively. FeS2 would be decomposed into FeS and S2 during the roasting process, and the S2 sulfidation effect was stronger than FeS. After roasting, the main iron phase of the minerals was changed into magnetite from hematite and then the iron could be recovered through the magnetic separation. This method provides a new method for the recovery of iron from tin-bearing iron ore of hematite.

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596-602

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January 2014

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© 2014 Trans Tech Publications Ltd. All Rights Reserved

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[1] L.J. Wang, J.B. Wang, Y.W. Wang, et al. Fluid-melt Inclusions in Fluorite of the Huanggangliang Skarn Iron-tin Deposit and Their Significance to Mineralization[J]. Acta Geologica Sinica,2001,75(2):204-211. (in Chinese).

DOI: 10.1111/j.1755-6724.2001.tb00522.x

Google Scholar

[2] C.J. Xie. Study on the Beneficiation-smelting Process of Skarn Fe-Sn Ores[J]. Huanan Nonferrous Metals,1996,12(6):13-17,39. (in Chinese).

Google Scholar

[3] Y.B. Zhang, L. Y Chen G.H. Li, et al. Mineralogical Features and Comprehensive Utilization Technology of Tin, zinc-bearing Iron Concentrates[J]. Journal of Central South University(Science and Technology), 2011, 42(6): 1501-1508. (in Chinese).

Google Scholar

[4] G. Zhao. Applicable Study on Chlorination Volatilization Oxidizing Roasting of Difficultly Separable Tin Middling [D]. Chang Sha: Central South University, 2000, 1-4. (in Chinese).

Google Scholar

[5] T. Jiang, Y.B. Zhang, Z.C. Huang, et al. Fundamental Study on Utilization of Tin and Zinc-bearing Iron Concentrate by Selective Chlorination[J]. Trans. Nonferrous Met. Soc. China,2005,15(4):902-907.

Google Scholar

[6] Z.W. Wang, C.Y. Wang, H.M. Lu. Investigation on Removal of Tin from Sn-bearing Iron Concentrates by Reduction Roasting [J]. Mining & Metallurgy, 2005,6(2):63-66. (in Chinese).

Google Scholar

[7] Y.B. Zhang, T. Jiang, G.H. Li, et al. Tin and Zinc Separation from Tin, Zinc Bearing Complex Iron Ores by Selective Reduction Process [J]. Ironmaking & Steelmaking, 2011, 38(8): 617-619.

DOI: 10.1179/1743281211y.0000000036

Google Scholar

[8] M. Jiang, T.C. Sun, X.M. Qin, et al. Study on Removing Arsenic and Tin from As-Sn Bearing Iron Concentrates by Direct Reduction Roasting of Coal [J]. Mining and Metallurgical Engineering, 2011,31(2):86-89. (in Chinese).

Google Scholar

[9] P. Ning, P. Bing, Y.C. Li. Recovery of Iron from Zinc Calcines by Reduction Roasting and Magnetic Separation[J]. Minerals Engineering,2012,35:57-60.

DOI: 10.1016/j.mineng.2012.05.014

Google Scholar

[10] Z.J. Qiu, L. Li, H. Wang, et al. Reaction Characteristics Study on the Removal of Tin from Tin-bearing Iron Concentrates by Sulfidation Roasting[J]. The Chinese Journal of Process Engineering, 2012, 12(6): 86-90. (in Chinese).

Google Scholar

[11] L.Y. Chen. Foundation Study on Separating Tin and Iron from Tin-bearing Iron Ores with Reduction Roasting[D]. Chang Sha: Central South University, 2010. 8-9. (in Chinese).

Google Scholar

[12] R.J. Liao, X.H. Liu, S.G. Zhang. Mineral Phase and Occurrence Status of Tin Minerals in Huangshaping Skarn Rock Type Lead-Zinc Polymetallic Ores[J]. Conservation and utilization of mineral resources, 2010, 2, 36-40. (in Chinese).

Google Scholar

[13] X.C. Song. Tin Metallurgy [M]. Beijing: Metallurgical Industry Press, 2011. 135-138. (in Chinese).

Google Scholar

[14] S. Cahcn, N. David, J.M. Fiorani, et al. Thermodynamic Modeling of the O-Sn System[J]. Thermochimica Acta,2003,403(2):275-285.

Google Scholar

[15] Y.B. Zhang, G.H. Li, T. Jiang, et al. Reduction Behavior of Tin-bearing Iron Concentrate Pellets Using Diverse Coals as Reducers [J]. International Journal of Mineral Processing, 2012, 110-111(18): 109-116.

DOI: 10.1016/j.minpro.2012.04.003

Google Scholar

[16] Y.B. Zhang, Z.C. Huang, T. Jiang, et al. Researches on New Process of Comprehensive Utilization of Complex Tin, Zinc-bearing Iron Concentrate Pellets (∏) [J]. Gui Yang: The Tenth National Academic Conference of Ironmaking raw,2007. (in Chinese).

Google Scholar