Associative Behaviors of a Novel Series of Amphiphilic Statistical Tripolymers

Xu Wu; Hong Hua Xiao; Ji Juan Wang; Xiao Xuan Xie; Jia Wei Lin; Xiao Min Rong

doi:10.4028/www.scientific.net/AMM.472.603

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HomeApplied Mechanics and MaterialsApplied Mechanics and Materials Vol. 472Associative Behaviors of a Novel Series of...

Associative Behaviors of a Novel Series of Amphiphilic Statistical Tripolymers

Abstract:

A novel series of brush-like amphiphilic statistical tripolymers were designed and prepared by polymerization of amphiphilic macromonomer 2-(acrylamido)-dodecane sulfonic acid (AMC₁₂S, 10 to 90 mol %), with hindrance units sodium p-styrenesulfonate (SSS, 0 to 5 mol %), and 2-(acrylamido)- 2-methylpro-panesulfonic acid (AMPS). The self-assembly behaviors of these tripolymers were investigated using steady-state fluorescence, and the increase of amphiphilic units results in a decrease of microdomain polarity and polymer concentrations for assembly, while the increase of hindrance units leads little change of microdomain polarity.