FTIR Spectrum Investigation of Thionine-Graphene Nanocomposite

Article Preview

Abstract:

Graphene is a material that has been heavily investigated in many researches due to its beneficial characteristics such as large surface area, low manufacturing cost, high electro conductivity and incredible mechanical strength. Applying the graphene in water-based solvents however can cause agglomeration due to its hydrophobic properties. Researchers have composited the graphene with other materials in overcoming its hydrophobicity. In this research, graphene was nanocomposited with thionine to make it disperse well in water-based solvents while preserving its intrinsic properties. The nanocomposition process involves mixing of both graphene oxide with thionine and were reduced by hydrazine hydrate while reflux heating. The produced mixture was then filtered to obtain the Thionine-Graphene nanocomposite. The obtained sample was then characterized to confirm the composition of both graphene and thionine. Fourier transfer infrared spectroscopy was operated to investigate the chemical bonds and hence concluding the presence of both graphene and thionine in the sample. The preservation of the intrinsic properties of graphene was also investigated through observing the absence of functionalized graphene bonds. Post-investigation reports that the chemical bonds from both of the materials, graphene and thionine were detected confirming the successfulness of the nanocomposition.

You might also be interested in these eBooks

Info:

Periodical:

Pages:

42-47

Citation:

Online since:

April 2017

Export:

Price:

Permissions CCC:

Permissions PLS:

Сopyright:

© 2017 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

* - Corresponding Author

[1] X. Kang, J. Wang, H. Wu, J. Liu, I. A. Aksay, Y. Lin, A graphene-based electrochemical sensor for sensitive detection of paracetamol, Talanta, 81(3) (2010) 754–759.

DOI: 10.1016/j.talanta.2010.01.009

Google Scholar

[2] Z. Yang, Z. Ye, B. Zhao, X. Zong, P. Wang, A rapid response time and highly sensitive amperometric glucose biosensor based on ZnO nanorod via citric acid-assisted annealing route, Phys. E Low-dimensional Syst. Nanostruct. 42(6) (2010) 1830-1833.

DOI: 10.1016/j.physe.2010.02.001

Google Scholar

[3] K. S. Novoselov, A. K. Geim, S. V. Morozov, D. Jiang, Y. Zhang, S. V. Dubonos, I. V. Grigorieva, A. A. Firsov, Electric Field Effect in Atomically Thin Carbon Films, Science, 306 (2004) 666.

DOI: 10.1126/science.1102896

Google Scholar

[4] K. H. Kim, H. J. Park, B. C. Woo, K. J. Kim, G. T. Kim, W. S. Yun, Electric Property Evolution of Structurally Defected Multilayer Graphene, Nano Lett, 8 (2008) 3092–3096.

DOI: 10.1021/nl8010337

Google Scholar

[5] M. Segal, Selling graphene by the ton, Nat. Nanotechnol. 4 (2009) 612–614.

Google Scholar

[6] N. Ruecha, R. Rangkupan, N. Rodthongkum, O. Chailapakul, Novel paper-based cholesterol biosensor using graphene/polyvinylpyrrolidone/polyaniline nanocomposite, Biosens. Bioelectron, 52 (2014) 13–19.

DOI: 10.1016/j.bios.2013.08.018

Google Scholar

[7] G. G. Wallace, R. B. Kaner, M. Muller, S. Gilje, D. Li, D. Li, Processable aqueous dispersions of graphene nanosheets Publication Details Processable aqueous dispersions of graphene nanosheets, Nat. Nanotechnol, 3(2) (2008) 101–105.

DOI: 10.1038/nnano.2007.451

Google Scholar

[8] M. J. McAllister, J. L. Li, D. H. Adamson, H. C. Schniepp, A. A. Abdala, J. Liu, M. Herrera-Alonso, D. L. Milius, R. Car, A. Robert K. Prud'homme, Ilhan A. Aksay, Single Sheet Functionalized Graphene by Oxidation and Thermal Expansion of Graphite, Chem. Mater, 19(18) (2007).

DOI: 10.1021/cm0630800

Google Scholar

[9] J. I. Paredes, S. Villar-Rodil, A. Martínez-Alonso, J. M. D. Tascón, Graphene Oxide Dispersions in Organic Solvents, Langmuir, 24(19) (2008) 10560–10564.

DOI: 10.1021/la801744a

Google Scholar

[10] Y. Zou, X. Wang, Y. Ai, Y. Liu, J. Li, Y. Ji, X. Wang, Coagulation Behavior of Graphene Oxide on Nanocrystallined Mg/Al Layered Double Hydroxides: Batch Experimental and Theoretical Calculation Study, Environ. Sci. Technol, 50(7) (2016).

DOI: 10.1021/acs.est.6b00255

Google Scholar

[11] D. W. Boukhvalov, M. I. Katsnelson, A. I. Lichtenstein, Hydrogen on graphene: Electronic structure, total energy, structural distortions and magnetism from first-principles calculations, Phys. Rev. B, 77(3) (2008) 35427.

DOI: 10.1103/physrevb.77.035427

Google Scholar

[12] L. Zhu, L. Luo, Z. Wang, DNA electrochemical biosensor based on thionine-graphene nanocomposite, Biosens. Bioelectron, 35(1) (2012) 507–511.

DOI: 10.1016/j.bios.2012.03.026

Google Scholar

[13] J. R. Anusha, C. J. Raj, B. B. Cho, A. T. Fleming, K. H. Yu, B. C. Kim, Amperometric glucose biosensor based on glucose oxidase immobilized over chitosan nanoparticles from gladius of Uroteuthis duvauceli, Sens. Actuat. B Chem. 215 (2015).

DOI: 10.1016/j.snb.2015.03.110

Google Scholar

[14] S. T. Yang, Y. Chang, H. Wang, G. Liu, S. Chen, Y. Wang, Y. Liu, A. Cao, Folding/aggregation of graphene oxide and its application in Cu2+ removal, J. Coll. Interf. Sci. 351(1) (2010) 122–127.

DOI: 10.1016/j.jcis.2010.07.042

Google Scholar

[15] N. C. D. Nath, S. Sarker, M. M. Rahman, H. J. Lee, Y. J. Kim, J. J. Lee, A facile template-free chemical synthesis of poly(thionine) nanowires, Chem. Phys. Lett. 559 (2013) 56–60.

DOI: 10.1016/j.cplett.2012.12.047

Google Scholar

[16] J. Ciriza, B. S. L. del, M. Virumbrales-Muñoz, I. Ochoa, L. Fernandez, G. Orive, M. Hernández, J. Pedraz, Graphene Oxide Increases the Viability of C2C12 Myoblasts Microencapsulated in Alginate, Int. J. Pharm, 493(1-2) (2015) 260-270.

DOI: 10.1016/j.ijpharm.2015.07.062

Google Scholar

[17] J. D. Patel, F. Mighri, A. Ajji, S. Elkoun, Room Temperature Synthesis of Aminocaproic Acid-Capped Lead Sulphide Nanoparticles, Mater. Sci. Appl. 3(2) (2012) 125–130.

DOI: 10.4236/msa.2012.32020

Google Scholar

[18] G. Wang, X. Shen, B. Wang, J. Yao, J. Park, Synthesis and characterisation of hydrophilic and organophilic graphene nanosheets, Carbon N. Y, 47(5) (2009) 1359–1364.

DOI: 10.1016/j.carbon.2009.01.027

Google Scholar