Synthesis of Calixarene Derivatives in One Reaction System

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Abstract:

This paper presents a effective approach for one new supermolecule function materia preparation, 25-(thioalkyl-alkoxy)-p-tertbutylcalix [4] arene with self-assembled monolayers character was synthesized by two-step nucleophilic substitute reaction in NaH-THF phase with p-tertbutylcalix [4] arene and dibromodecne . The structure of product was characterized by FT-IR, 1H NMR, 13C NMR and MALDI-TOF-MS. The self-assembly molecular imprinted film as the sensitive film was coated on the gold delay line of SAW sensors to detect for detecting organophosphorus compounds such as sarin, had important reference value in counter-terrorism.

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594-597

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August 2014

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© 2014 Trans Tech Publications Ltd. All Rights Reserved

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[1] A. Dondoni and A. Marra, Chem. Rev., 110, 9 (2012), 4949-4977.

Google Scholar

[2] F. F. Yang, Y. Y. Chen,S. Lin, Chin. J. Org. Chem., 22, 10 (2002 ), 746-749.

Google Scholar

[3] B. Gao, Y. Q. Feng, L. S. Zhou, X. Ma, , Chin. J. Org. Chem., 24, 7(2004), 713-721.

Google Scholar

[4] U. T. J. Eggo, F.J.E. Johan, N.R. David, J. Am. Soc., 116 (1994), 3597-98.

Google Scholar

[5] K.D. Schierbaum, T. Weiss, Thoden E.U., Science, 116, 2, (1994), 1413-1415.

Google Scholar

[6] B. T. Zhao, H. Y. Zhang, Y. Lui, Chin.J. Org. Chem., 25, 8, (2005), 913-925.

Google Scholar

[7] Nathaniel H., Sherden, Douglas C., Behenna, Angewandte Chemie, 121, 37, (2009), 6972-6975.

Google Scholar

[8] J. Gutiérrez, M.C. Horrillo, Talanta, 124 (2014), 95-10.

Google Scholar