Optical Emission Spectroscopy Measurement of Ar\H2\CH4 RF Plasma for Nano-Crystal Diamond Film Deposition

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Abstract:

Ar\H2\CH4 gas mixture was utilized to grow nanocrystal diamond films in a RF plasma enhanced CVD system. CH4\ H2 ratios were changed to study the effect of plasma radicals on the deposit, in which optical emission spectroscopy (OES) was applied to analyze the plasma radicals. It was found that Hα, Hβ, Hγ, CH, C2 were the main radicals in the plasma. Among them, the CH intensity of OES was usually quite strong and increased sharply when the ratio of CH4/H2 was greater than 3%. The intensity of C2 was weak and basically unchanged with the addition of methane. This study can provide a new possible technical application for depositing NCD films.

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373-378

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October 2014

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© 2014 Trans Tech Publications Ltd. All Rights Reserved

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[1] Williams, O.A., Nanocrystalline diamond, Diam. Relat. Mat. 20(2011) 621-640.

Google Scholar

[2] Cicala, G., P. Bruno, F. Benedic, F. Silva, K. Hassouni, and G.S. Senesi, Nucleation, growth and characterization of nanocrystalline diamond films, Diam. Relat. Mat. 14(2005) 421-425.

DOI: 10.1016/j.diamond.2004.12.025

Google Scholar

[3] Zhou, H.Y., J. Watanabe, M. Miyake, A. Ogino, M. Nagatsu, and R.J. Zhan, Optical and mass spectroscopy measurements of Ar/CH4/H-2 microwave plasma for nano-crystalline diamond film deposition, Diam. Relat. Mat. 16(2007) 675-678.

DOI: 10.1016/j.diamond.2006.11.074

Google Scholar

[4] Tang, W., C. Zhu, W. Yao, Q. Wang, C. Li, and F. Lu, Nanocrystalline diamond films produced by direct current arc plasma jet process, Thin Solid Films 429(2003) 63-70.

DOI: 10.1016/s0040-6090(03)00056-7

Google Scholar

[5] Zhang, Y.F., F. Zhang, Q.J. Gao, X.F. Peng, and Z.D. Lin, The roles of argon addition in the hot filament chemical vapor deposition system, Diam. Relat. Mat. 10(2001) 1523-1527.

DOI: 10.1016/s0925-9635(01)00383-1

Google Scholar

[6] May, P.W., J.N. Harvey, J.A. Smith, and Y.A. Mankelevich, Reevaluation of the mechanism for ultrananocrystalline diamond deposition from Ar/CH4/H-2 gas mixtures, J. Appl. Phys. 99(2006).

DOI: 10.1063/1.2195347

Google Scholar

[7] May, P.W., J.A. Smith, and Y.A. Mankelevich, Deposition of NCD films using hot filament CVD and Ar/CH(4)/H(2) gas mixtures, Diam. Relat. Mat. 15(2006) 345-352.

DOI: 10.1016/j.diamond.2005.06.044

Google Scholar

[8] Rabeau, J.R., P. John, J.I.B. Wilson, and Y. Fan, The role of C-2 in nanocrystalline diamond growth, J. Appl. Phys. 96(2004) 6724-6732.

DOI: 10.1063/1.1810637

Google Scholar

[9] Lin, T., G.Y. Yu, A.T.S. Wee, Z.X. Shen, and K.P. Loh, Compositional mapping of the argon-methane-hydrogen system for polycrystalline to nanocrystalline diamond film growth in a hot-filament chemical vapor deposition system, Appl. Phys. Lett. 77(2000).

DOI: 10.1063/1.1320039

Google Scholar

[10] Gruen, D.M., C.D. Zuiker, A.R. Krauss, and X.Z. Pan, CARBON DIMER, C-2 AS A GROWTH SPECIES FOR DIAMOND FILMS FROM METHANE/HYDROGEN/ARGON MICROWAVE PLASMAS, J. Vac. Sci. Technol. A. 13(1995) 1628-1632.

DOI: 10.1116/1.579742

Google Scholar

[11] Chen, G.C., B. Li, H. Lan, F.W. Dai, Z.Y. Zhou, J. Askari, J.H. Song, L.F. Hei, C.M. Li, W.Z. Tang, and F.X. Lu, Gas phase study and oriented self-standing diamond film fabrication in high power DC arc plasma jet CVD, Diam. Relat. Mat. 16(2007).

DOI: 10.1016/j.diamond.2006.09.023

Google Scholar

[12] Liao, Y., C.H. Li, Z.Y. Ye, C. Chang, G.Z. Wang, and R.C. Fang, Analysis of optical emission spectroscopy in diamond chemical vapor deposition, Diam. Relat. Mat. 9(2000) 1716-1721.

DOI: 10.1016/s0925-9635(00)00283-1

Google Scholar

[13] Vandevelde, T., M. Nesladek, C. Quaeyhaegens, and L. Stals, Optical emission spectroscopy of the plasma during CVD diamond growth with nitrogen addition, Thin Solid Films 290(1996) 143-147.

DOI: 10.1016/s0040-6090(96)09189-4

Google Scholar

[14] Grill, A., B.S. Meyerson, and V.V. Patel, DIAMOND-LIKE CARBON-FILMS BY RF PLASMA-ASSISTED CHEMICAL VAPOR-DEPOSITION FROM ACETYLENE, IBM J. Res. Dev. 34(1990) 849-857.

DOI: 10.1147/rd.346.0849

Google Scholar

[15] Tomasella, E., C. Meunier, and S. Mikhailov, a-C : H thin films deposited by radio-frequency plasma: influence of gas composition on structure, optical properties and stress levels, Surf. Coat. Technol. 141(2001) 286-296.

DOI: 10.1016/s0257-8972(01)01271-3

Google Scholar

[16] Silva, S.R.P. and G.A.J. Amaratunga, Doping of rf plasma deposited diamond-like carbon films, Thin Solid Films 270(1995) 194-199.

DOI: 10.1016/0040-6090(95)06915-1

Google Scholar

[17] Lee, K.R., M.G. Kim, S.J. Cho, K.Y. Eun, and T.Y. Seong, Structural dependence of mechanical properties of Si incorporated diamond-like carbon films deposited by RF plasma-assisted chemical vapour deposition, Thin Solid Films 308(1997) 263-267.

DOI: 10.1016/s0040-6090(97)00411-2

Google Scholar

[18] Cui, J.B. and R.C. Fang, Characterization of the diamond growth process using optical emission spectroscopy, J. Appl. Phys. 81(1997) 2856-2862.

DOI: 10.1063/1.363944

Google Scholar

[19] Linnik, S.A. and A.V. Gaydaychuk, Application of optical emission spectroscopy for the determination of optimal CVD diamond growth parameters in abnormal glow discharge plasma, Vacuum 103(2014) 28-32.

DOI: 10.1016/j.vacuum.2013.12.001

Google Scholar

[20] Ma, J., M.N.R. Ashfold, and Y.A. Mankelevich, Validating optical emission spectroscopy as a diagnostic of microwave activated CH4/Ar/H-2 plasmas used for diamond chemical vapor deposition, J. Appl. Phys. 105(2009) 12.

DOI: 10.1063/1.3078032

Google Scholar

[21] Chen, G.C., B. Li, H. Li, H. Lan, F.W. Dai, Q.J. Xue, X.Q. Han, L.F. Hei, J.H. Song, C.M. Li, W.Z. Tang, and F.X. Lu, Growth of diamond by DC Arcjet Plasma CVD: From nano-sized poly-crystal films to millimeter-sized single crystal grain, Diam. Relat. Mat. 19(2010).

DOI: 10.1016/j.diamond.2010.03.012

Google Scholar

[22] Kulisch, W., C. Popov, S. Boycheva, L. Buforn, G. Favaro, and N. Conte, Mechanical properties of nanocrystalline diamond/amorphous carbon composite films prepared by microwave plasma chemical vapour deposition, Diam. Relat. Mat. 13(2004).

DOI: 10.1016/j.diamond.2004.04.002

Google Scholar

[23] Askari, S.J., G.C. Chen, F. Akhtar, and F.X. Lu, Adherent and low friction nano-crystalline diamond film grown on titanium using microwave CVD plasma, Diam. Relat. Mat. 17(2008) 294-299.

DOI: 10.1016/j.diamond.2007.12.045

Google Scholar

[24] Miyake, M., A. Ogino, and M. Nagatsu, Characteristics of nano-crystalline diamond films prepared in Ar/H2/CH4 microwave plasma, Thin Solid Films 515(2007) 4258-4261.

DOI: 10.1016/j.tsf.2006.02.048

Google Scholar