A Numerical Simulation of Proton Exchange Membrane Fuel Cell Performance

Abstract:

A composite three-dimensional mathematical model of proton exchange membrane fuel cell is proposed, the corresponding finite element method and numerical simulation are given as well, where fluid flow, proton transport, and electrochemical reaction are addressed. Some factors that probably affect the performance of the cell are analyzed by using the model. The computational results show that the reactant concentration decreases along the flow direction, the water concentration increases in the cathode side of membrane, membrane resistance decreases, conductivity increases and proton concentration increases. The fuel cell performance is better when the porosity increases, as well as the operating pressure.

• Periodical: Advanced Materials Research (Volumes 347-353)
• Pages: 376-385
• DOI: https://doi.org/10.4028/www.scientific.net/AMR.347-353.376
• Online since: October 2011
• Authors: Shi Gang Yu, Hui He, You Sheng Xu
• Keywords: Fuel Cell (FC), Numerical Analysis, Proton Exchange Membrane Fuel Cell, Transfer Behavior

References

[1] G.L.He. The research of the two-phase trans transport behavior in Proton Exchange Membrane Fuel cells, PhD thesis. Dalian University of Technology ,1-131,(2006).

[2] Y.H. Cai, J Hu, B.L.Yi et al. Analysis of Different Types of Model for Proton Exchange Membrane Fuel Cell Stacks,J. Chemistry Progress,17(3):544-548,（2005）.

[3] V Gurau, H Liu, S Kakac. Two-Dimensional Model for Proton Exchange Membrane Fuel Cell.J AICHE ,44(11):2410-2422,(1998).

DOI: 10.1002/aic.690441109

[4] Y. Zhou, G. Lin, A.J. Shih, S.J. Hu, J. Power Sources 163: 777–783, (2007).

[5] D.M Bernardi M.W. Verbrugge A mathematical model of the solid polymer-electrolyte fuel cell, J. Electrochem. Soc; 139:2477–2491, (1992).

DOI: 10.1149/1.2221251

[6] T.E Springer，T.A Zawodinski. Polymer electrolyte fuel cell model J.Electrochem. Soc, 138: 2334–2342,(1991).

[7] G.L Hu， J.R Fan，S Chen，et al. Three-dimensional numerical analysis of proton exchange membrane fuel cells (PEMFCs) with conventional and interdigitated flow fields,J. Power Sources,136(1)：1–9, (2004).

DOI: 10.1016/j.jpowsour.2004.05.010

[8] S Dutta，S Shimpalee,Van J. w Zee. Three-Dimensional numerical Simulation of Straight Channel PEM Fuel Cells J.Appl.Electrochem,； 30(2):135-146,(2000).

[9] T Berning, D. M Lu, Djilali N. Three-Dimensional Computational Analysis of Transport Phenomena in a PEM Fuel Cell. J.Power Sources, 106(2):284-294, (2002).

DOI: 10.1016/s0378-7753(01)01057-6

[10] G.L Hu,S Chen，J.R Fan .et al. Three-dimensional numerical simulation of two-phase flow and transport phenomena in proton exchange membrane fuel cell Journal of Chemical Industry and Engineering 56(7)：1305-1310,(2005).

[11] C.J Xu, G.S Zhang, H.T Liu. MODELLINGOFV TERTRANSPORTINPEMFUELCELL Journal of engineerging thermophysics 31(9):1504-1507,(2010).

[12] G.L Hu，Y.J Liu. Three-dimensional numerical analysis of proton exchange membrane fuel cells J. Progress in Natural Science 13(4): 388-392,(2003).

[13] Sun P, Xue G , Wang C. Y, Xu J. New numerical techniques for a three-dimensional liquid-feed direct methanol fuel cell model. Appl.Math,70(2):600-620,(2009).

DOI: 10.1137/08071942x

[14] You L, Liu H. A two-phase flow and transport model for PEM Fuel cells,J.Power Sources. 155:219-230,(2006).

DOI: 10.1016/j.jpowsour.2005.04.025

[15] Bernardi D .M，Verbrugge M. W. A Mathematieal Model of the Solid-Polymer-Electrolyte Fuel Cell,J. Electrochem. Soe,139(9):2477—2491(1992).

DOI: 10.1149/1.2221251

[16] J.R Fan，S Chen，et al. Three-dimensional numerical analysis of proton exchange membranefuel cells (PEMFCs) with conventional and interdigitated flow fields,136(1):1–9, (2004).

DOI: 10.1016/j.jpowsour.2004.05.010

[17] Amphlett J. C, Baumert R. M. J. Electrochem. Soc,142(1): 1—8,(1995).

[18] Amphlett J. C, Baumert R. M. J. Electrochem. Soc,142(1): 9—15(1995).

[19] Journal of Chemical Industry and Engineering (China), 2002, 53(8): 865-870