Template Sol-Gel Synthesis of Phosphorescent Mesoporous Silica Film Nanocomposites Using an Amphiphilic Gold (I) Pyrazolate Complex

Hendrik O. Lintang; Kazushi Kinbara; Takuzo Aida

doi:10.4028/www.scientific.net/AMR.364.55

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Template Sol-Gel Synthesis of Phosphorescent Mesoporous Silica Film Nanocomposites Using an Amphiphilic Gold (I) Pyrazolate Complex
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HomeAdvanced Materials ResearchAdvanced Materials Research Vol. 364Template Sol-Gel Synthesis of Phosphorescent...

Template Sol-Gel Synthesis of Phosphorescent Mesoporous Silica Film Nanocomposites Using an Amphiphilic Gold (I) Pyrazolate Complex

Abstract:

Herein novel mesoporous silica film nanocomposites are successfully synthesized by using phosphorescent columnar assembly of an amphiphilic trinuclear gold (I) pyrazolate complex [Au₃Pz₃] as a functional template in the sol-gel synthesis. By controlling the molar ratios of silica source tetrabutylorthosilicate (TBOS) to [Au₃Pz₃] in an acidic aqueous alcohol solution from 60:1 to 20:1, highly ordered phosphorescent nanocomposites can be fabricated with hexagonal [Au₃Pz₃]/silica_hex and lamellar [Au₃Pz₃]/silica_lam silicates.

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Advanced Materials Research (Volume 364)

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55-59

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https://doi.org/10.4028/www.scientific.net/AMR.364.55

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October 2011

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Hendrik O. Lintang, Kazushi Kinbara, Takuzo Aida

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Hexagonal, Mesoporous Silica, Sol-Gel Synthesis, Template

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References

[1] C. Sanchez, G.J. deA.A. Soler-Illia, F. Ribot, T. Lalot, C.R. Mayer and V. Cabuil: Chem. Mater. Vol. 13 (2001), p.3061.

DOI: 10.1021/cm011061e

Google Scholar

[2] C. Sanchez, B. Julián, P. Belleville and M. Popall: J. Mater. Chem. Vol. 15 (2005), p.3559.

Google Scholar

[3] T. Aida and K. Tajima: Angew. Chem. Int. Ed. Vol. 40 (2001), p.3803.

Google Scholar

[4] Y. Lu, Y. Yang, A. Sellinger, M. Lu, J. Huang, H. Fan, R. Haddad, G. Lopez, A.R. Burns, D.Y. Sasaki, J. Shelnutt and C.J. Brinker: Nature Vol. 410 (2001), p.913.

DOI: 10.1038/35073544

Google Scholar

[5] M. Ikegame, K. Tajima and T. Aida, Angew. Chem. Int. Ed. Vol. 42 (2003), p.2154.

Google Scholar

[6] G. Li, S. Bhosale, T. Wang, Y. Zhang, H. Zhu and J. -H. Fuhrhop: Angew. Chem. Int. Ed. Vol. 42 (2003), p.3818.

Google Scholar

[7] A. Okabe, T. Fukushima, K. Ariga and T. Aida: Angew. Chem. Int. Ed. Vol. 41 (2002), p.3414.

Google Scholar

[8] M. Kimura, K. Wada, K. Ohta, K. Hanabusa, H. Shirai and N. Kobayashi: J. Am. Chem. Soc. Vol. 123 (2001), p.2438.

Google Scholar

[9] A. Okabe, M. Niki, T. Fukushima, K. Ariga and T. Aida: Chem. Commun. (2004), p.2572.

Google Scholar

[10] W. Otani, K. Kinbara and T. Aida: Faraday Discuss. Vol. 143 (2009), p.335.

Google Scholar

[11] H.O. Lintang, K. Kinbara, K. Tanaka, T. Yamashita and T. Aida: Angew. Chem. Int. Ed. Vol. 49 (2010), p.4241.

Google Scholar

[12] H.O. Lintang, K. Kinbara, K. Tanaka, T. Yamashita and T. Aida, in: 2010 International Conference on Enabling Science and Nanotechnology, ESciNano, ISBN: 978-1-4244-8854-4 (IEEE), Proceedings (2010), Article number 5700970.

DOI: 10.1109/escinano.2010.5700970

Google Scholar

[13] H.O. Lintang, K. Kinbara and T. Aida: J. Fund. Sci. Vol. 7(1) (2011), p.67.

Google Scholar

[14] R.G. Raptis and J.P. Fackler Jr: Inorg. Chem. Vol. 29 (1990), p.5003.

Google Scholar