Molecular and Crystal Structure Analysis of an Oxalate-Bridged Sodium 2D Polymer: [Na(μ1,1,2,3-Oxalato)(di-μ1,1-H2O)]N

Jia Ming Li; Shu Qing Xu; Zhong Feng Shi

doi:10.4028/www.scientific.net/AMR.399-401.916

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HomeAdvanced Materials ResearchAdvanced Materials Research Vols. 399-401Molecular and Crystal Structure Analysis of an...

Molecular and Crystal Structure Analysis of an Oxalate-Bridged Sodium 2D Polymer: [Na(μ_1,1,2,3-Oxalato)(di-μ_1,1-H₂O)]_N

Abstract:

The title compound, [Na(μ_1,1,2,3-oxalato)(di-μ_{belongs to triclinic, space group P-1 with a = 5.6982 (11), b = 6.5040 (12), c = 6.6647 (13) Å, α = 75.040 (2), β = 84.990 (3), γ = 70.072 (3), V = 224.34 (7) Å³, C₂H₃NaO₅, Mr = 130.03, Z = 2, Dc = 1.925 g/cm³, μ = 0.270 mm^–1 and F(000) = 132. Each sodium ions is located on crystallographic inversion symmetry centre and surrounded by six oxygen donors from three oxalate ligands and two di-μ_1,1-waters in a distorted octahedron geometry. Two planar 4-member cyclβes crystallographic inversion are found in alternate repeated Na₂O₂ subunit, which is further extended to two dimensional supermolecular fragment via μ_1,1,2,3-oxalato-bridged. The crystal structure is aggregated to a 3D network through O-H…O hydrogen bonding involving the water molecules and oxalate oxygen atoms.}

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Advanced Materials Research (Volumes 399-401)

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916-920

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https://doi.org/10.4028/www.scientific.net/AMR.399-401.916

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November 2011

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Jia Ming Li, Shu Qing Xu, Zhong Feng Shi

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Crystal Structure, Oxalate-Bridged, Sodium Polymer

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References

[1] R.D. Willet, D. Gatteschi and O. Kahn: NATO ASI Series C, vol. 140, D. Reidel, Dordrecht, The Netherlands (1985)

Google Scholar

[2] D. Gatteschi, O. Kahn, J. S. Miller and F. Palacio: Magnetic Molecular Materials, Kluwer Academic Publishers, Dordrecht, The Netherlands (1991)

Google Scholar

[3] O. Kahn: Molecular Magnetism, VCH, New York (1993)

Google Scholar

[4] S. Triki, F. Bérézovsky, J.S. Pala, E. Coronado, C.J. Gómez-García, J.M. Clemente, A. Riou and P. Molinié: Inorg. Chem. Vol. 39 (2000), p.3771

DOI: 10.1021/ic990439w

Google Scholar

[5] O. Castillo, A. Luque, J. Sertucha, P. Román and F. Lloret: Inorg. Chem. Vol. 39 (2000), p.6142

Google Scholar

[6] H.Y. Shen, W.M. Bu, D.Z. Liao, Z.Hui. Jiang, S.P. Yan and G.L. Wang: Inorg. Chem. Vol. 39 (2000), p.2239

Google Scholar

[7] O. Castillo, A. Luque, S. Iglesias, C. Guzmán-Miralles and P. Román: chem. commu. Vol. 4 (2001), p.640

Google Scholar

[8] G. M. Sheldrick: Acta Cryst. Vol 64A (2008), p.112

Google Scholar

[9] S. Youngme, G. A. Albada, N. Chaichit, P. Gunnasoot, P. Kongsaeree, I. Mutikainen, O. Roubeau, J. Reedijk and U. Turpeinen: Inorganica Chimica Acta Vol. 353 (2003), p.119

DOI: 10.1016/s0020-1693(03)00207-x

Google Scholar

[10] F. H. Allen, O. Kennard, D. G. Watson, L. Brammer, A. G. Orpen and R. Taylor: J. Chem. Soc. Perkin Trans. Vol. 2 (1987), p.1

Google Scholar

[11] Y. Akhriff, J. Server-Carrió, A. Sancho, J. García-Lozano, E. Escrivá, J. V. Folgado and L. Soto: Inorganic Chem. Vol. 38 (1999), p.1174

DOI: 10.1021/ic980982x

Google Scholar

[12] P. Román, C. Guzmán-Miralles, A. Luque, J.I. Beitia, J. Cano, F. Lloret, M. Julve and S. Alvarez: Inorganic Chem. Vol. 35 (1996), p.3741

Google Scholar