Synthesis, Characterization and Bioactivity Studies of Calcium Silicate Bioceramics

Article Preview

Abstract:

Wollastonite is one of the most widely used bioceramic due to its biocompatibility and bioactivity. Wollastonite (CaSiO3) was synthesized by sol-gel combustion process using citric acid as a fuel/reductant and nitrate as an oxidant. Calcium nitrate was taken as a source of calcium and tetraethyl orthosilicate was taken as the source of silicate. The obtained product was characterized by powder X-ray diffraction, Fourier - Transform Infrared spectroscopy and Scanning electron microscopy. The XRD pattern shows that the product formed is a pure and single phasic wollastonite. The FT-IR spectra revealed that there is no secondary phase present in the product. The SEM image shows that the product is highly porous. The particle size calculated using Scheerer’s formula shows that the particles are in a nano regime.

You might also be interested in these eBooks

Info:

Periodical:

Pages:

479-483

Citation:

Online since:

October 2012

Export:

Price:

Permissions CCC:

Permissions PLS:

Сopyright:

© 2012 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

[1] M.A Sainz, P.Pena, S.Serena, A. Caballero. Influence of design on bioactivity of novel CaSiO3- CaMg(SiO3)2 bioceramics: in vitro simulated body fluid test and thermodynamic simulation, Acta Biomater 6 (2010) 2797-2807.

DOI: 10.1016/j.actbio.2010.01.003

Google Scholar

[2] Herlian syah, M.K Suyito, Dewo, P. Abdul Shukor, M.H.B. Ide Ektessabi, Ari. Development and characterization of bovine hydroxyapatite porous bone graft for biomedical application, Adv. Mater. Res. 277 (2011) 59-65.

DOI: 10.4028/www.scientific.net/amr.277.59

Google Scholar

[3] Xiang-Hui Huang, Jiang Chang. Synthesis of nanocrystalline Wollastonite powders by citrate-Nitrate gel combustion method, Mater. Chem. Phys. 115 (2009)1-4.

DOI: 10.1016/j.matchemphys.2008.11.066

Google Scholar

[4] Jie Wei, Fangping Chen, Jung Woog Shin, Hua Hong, Chenlong Dai, Jiancan Su, Changsheng Liu. Preparation and characterization of bioactive mesoporous wollatonite- polycaprolactone Composite scaffold, Biomater 30 (2009) 1080-1088.

DOI: 10.1016/j.biomaterials.2008.10.046

Google Scholar

[5] A. Binnaz Yoruc¸ Hazar. Preparation and in vitro bioactivity of CaSiO3 powders. Ceram. Int 33 (2007) 687–692.

DOI: 10.1016/j.ceramint.2006.12.013

Google Scholar

[6] Kaili Lin, Jiang Chang, Jianxi Lu. Synthesis of wollastonite nanowires via hydrothermal microemulsion methods. Mater. Lett. 60 (2006) 3007–3010.

DOI: 10.1016/j.matlet.2006.02.034

Google Scholar

[7] R.P. Sreekanth Chakradhar, B.M. Nagabhushana, G.T. Chandrappa , K.P. Ramesh, J.L. Rao. Solution combustion derived nanocrystalline macroporous wollastonite ceramics. Mater. Chem. Phys. 95 (2006) 169–175.

DOI: 10.1016/j.matchemphys.2005.06.002

Google Scholar

[8] Jie Wei, Fangping Chen, Jung Woog Shin, Hua Hong, Chenlong Dai, Jiancan Su, Changsheng Liu. Preparation and characterization of bioactive mesoporous wollatonite- polycaprolactone Composite scaffold, Biomater 30 (2009) 1080-1088.

DOI: 10.1016/j.biomaterials.2008.10.046

Google Scholar

[9] J.M. Raquez, D.T.J. Barone, Z. Luklinska,O. Persenaire, A. Belayew, J. Eyckmans, J. Schrooten, and Ph. Dubois. Oesteoconductive and bioresorbable composites based on poly-(l,l-lactide) and pseudowollastonite: from synthesis an interfacial compatibilization to in vitro bioactivity and in vivo osseointegration studies, Biomacromolecules 12 (2011) 692-700.

DOI: 10.1021/bm101327r

Google Scholar