Effects of Oxygen Flow Rate on Nanostructured ZnO Thin Films

Article Preview

Abstract:

Zinc Oxide (ZnO) thin films were deposited on thermally oxidized SiO2 by varying the oxygen flow rate. The deposition process were done using radio frequency (RF) magnetron sputtering at various oxygen flow rate ranging from 0 to 40 sccm. The surface morphology and crystallinity were analyzed by field emission scanning electron microscopy (FESEM) and X-Ray Diffractometer (XRD) respectively. The average thickness and deposition rate decreases with an increase of oxygen content. The grain size was measured by FESEM and it was found that it is also decreasing with the increased of oxygen flow rate. The films grown with 10 sccm oxygen shows the highest (002) peak however it is expected that the sample deposited with 40 sccm oxygen exhibit the highest sensitivity toward NH3 gas due to the highest surface to volume ratio.

You might also be interested in these eBooks

Info:

Periodical:

Pages:

333-337

Citation:

Online since:

March 2013

Export:

Price:

Permissions CCC:

Permissions PLS:

Сopyright:

© 2013 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

[1] Ping-Feng Yang, Hua-Chiang Wen, Sheng-Rui Jian, Yi-Shao Lai, Sean Wu, Rong-Sheng Chen, Characteristics of ZnO thin films prepared by radio frequency magnetron sputtering, Microelectronics Reliability 48 (2008) 389-394.

DOI: 10.1109/impact.2007.4433597

Google Scholar

[2] R. Ondo-Ndong, F. Pascal-Delannoy, A. Boyer, A. Giani, A. Foucaran, Structural properties of zinc oxide thin films prepared by r. f. magnetron sputtering, Materials Science and Engineering: B 97 (2003) 68-73.

DOI: 10.1016/s0921-5107(02)00406-3

Google Scholar

[3] Sukhvinder Singh, R. S. Srinivasa, S. S. Major, Effect of substrate temperature on the structure and optical properties of ZnO thin films deposited by reactive rf magnetron sputtering, Thin Solid Films 515 (2007) 8718-8722.

DOI: 10.1016/j.tsf.2007.03.168

Google Scholar

[4] P. Nunes, E. Fortunato, R. Martins, Influence of the post-treatment on the properties of ZnO thin films, Thin Solid Films 383 (2001) 277-280.

DOI: 10.1016/s0040-6090(00)01577-7

Google Scholar

[5] M. Suchea, S. Christoulakis, K. Moschovis, N. Katsarakis, G. Kiriakidis, ZnO transparent thin films for gas sensor applications, Thin Solid Films 515 (2006) 551-554.

DOI: 10.1016/j.tsf.2005.12.295

Google Scholar

[6] M.K. Hossain, S.C. Ghosh, Y. Boontongkong, C. Thanachayanont, J. Dutta, Growth of zinc oxide nanowires and nanobelts for gas sensing applications, Journal of Metastable and Nanocrystalline Materials 23 (2005) 27-30.

DOI: 10.4028/www.scientific.net/jmnm.23.27

Google Scholar

[7] S. H. Jeong, S. Kho, D. Jung, S. B. Lee, and J. H. Boo, Deposition of aluminum-doped zinc oxide films by RF magnetron sputtering and study of their surface characteristics, Surface and Coatings Technology 174–175 (2003) 187-192.

DOI: 10.1016/s0257-8972(03)00600-5

Google Scholar

[8] M. Hafiz Mamat, S.W.A. Wan, M.Z. Musa, Z. Khusaimi, M.F. Malek, S. Muhamad, D.M. Sin, B. Mahmood, M. Rusop, Effect of Oxygen Flow Rate on the Properties of Nanocolumnar ZnO Thin Films Prepared Using Radio Frequency Magnetron Sputtering System for Ultraviolet Sensor Applications, Advanced Materials Research 364 (2012).

DOI: 10.4028/www.scientific.net/amr.364.1

Google Scholar

[9] J. H. H. Zhu, E. Bunte, S. M Huang, Oxygen influence on sputtered high rate ZnO: Al films from dual rotatable ceramic targets, Applied Surface Science 256 (2010) 4601-4605.

DOI: 10.1016/j.apsusc.2010.02.057

Google Scholar

[10] I. Sayago, M. Aleixandre,L. Ares, M.J. Fernandez, J.P. Santos, J. Gutierrez, M.C. Horrillo, The effect of the oxygen concentration and the rf power on the zinc oxide films properties deposited by magnetron sputtering, Applied Surface Science 245 (2005).

DOI: 10.1016/j.apsusc.2004.10.035

Google Scholar

[11] T. Ghosh, D. Basak, Effect of oxygen flow rate and radio-frequency power on the photoconductivity of highly ultraviolet sensitive ZnO thin films grown by magnetron sputtering technique, Materials Research Bulletin 46 (2011) 1975–(1979).

DOI: 10.1016/j.materresbull.2011.07.019

Google Scholar

[12] P. T. Hsieh, Y. C. Chen, K. S. Kao, C. M. Wang, Structural effect on UV emission properties of high-quality ZnO thin films deposited by RF magnetron sputtering, Physica B: Condensed Matter 392 (2007) 332-336.

DOI: 10.1016/j.physb.2006.11.043

Google Scholar