Preparation and Thermodynamics Adsorption Performance of Cobalt Ions on the Crosslinked Starch Microspheres

Li Yan Yang; Yi Hui Guo; Li Li Yu

doi:10.4028/www.scientific.net/AMR.726-731.435

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HomeAdvanced Materials ResearchAdvanced Materials Research Vols. 726-731Preparation and Thermodynamics Adsorption...

Preparation and Thermodynamics Adsorption Performance of Cobalt Ions on the Crosslinked Starch Microspheres

Abstract:

A type of cross-linking starch microspheres (CSMs) has been synthesized by reversed phase suspension method using soluble starch as raw material. Crosslinked starch microsphere has good adsorption performance to metal ions in water. The static adsorption behaviors of Co²⁺ on the cross-linked starch microspheresand were investigated. The CSMs and its adsorption product were comparatively characterized by Fourier Transform Infrared Spectroscopy (FTIR). The adsorption behaviour of CSMs in different temperatures is in agreement with the Freundlich isothermal equation and isothermal equation of Langmiur. The thermodynamic parameters of adsorption process indicate that entropy is the main adsorption driving force, and physical adsorption is main about the adsorption behaviors of CSMs on Co²⁺.These data are helpful for the adsorption separation of metal ions and the treatment of the wastewater containing Co²⁺. Keywords: cross-linked starch microspheres;cobalt ions;adsorption mechanism;thermodynamics adsorption