Removal of Cr(VI) from Aqueous Solution Using Activated Carbon Prepared from Several Agriculture By-Products

Article Preview

Abstract:

The adsorption characteristics of Cr(VI) on activated carbon prepared from several agriculture by-products via sulphuric acid-treatment were compared and the best concentration of sulphuric acid for carbonization were evaluated. It is confirmed that peanut shell is best material for the absorption of Cr(VI) ion from aqueous solution among hybrid giant napier straw, rice husk and commercial activated carbon in this study. The effects of agitation time, solution pH, temperature and Cr(VI) initial concentration on Cr(VI) adsorption were investigated. The 3:1 volume ratio of sulphuric acid : deionized water is the optimal concentration for Cr(VI) biosorption for peanut shell carbonization. Cr(VI) adsorption is highly dependent on solution pH. Initial solution pH =1.5 was the most favorable pH for Cr(VI) removal. Cr(VI) biosorption increases with increasing initial concentration, agitation time and solution temperature. The adsorption kinetics is found well fitted to the pseudo-second-order kinetic model. The adsorption equilibrium data are best represented by Langmuir model.The maximum adsorption capacity of carbonized peanut shell for Cr(VI) reached 26.22 mg/g.

You might also be interested in these eBooks

Info:

Periodical:

Advanced Materials Research (Volumes 807-809)

Pages:

582-590

Citation:

Online since:

September 2013

Export:

Price:

Permissions CCC:

Permissions PLS:

Сopyright:

© 2013 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

[1] D. Mohan and Jr C.U. Pittman: Journal of Hazardous Materials Vol. 137 (2006), p.762.

Google Scholar

[2] X.S. Wang, L.F. Chen, F.Y. Li, K.L. Chen, W.Y. Wan and Y.J. Tang: Journal of Hazardous Materials Vol. 175 (2010), p.816.

Google Scholar

[3] F. Asadi, H. Shariatmadari and N. Mirghaffari: Journal of Hazardous Materials Vol. 154 (2008), p.451.

Google Scholar

[4] I.A. Tan, A.L. Ahmad and B.H. Hameed: Journal of Hazardous Materials Vol. 164 (2009), p.473.

Google Scholar

[5] J. Moreno-Piraján and L. Giraldo: Journal of Analytical and Applied Pyrolysis Vol. 90 (2011), p.42.

Google Scholar

[6] C.S. Zhu, L.P. Wang and W.B. Chen: Journal of Hazardous Materials Vol. 168 (2009), p.739.

Google Scholar

[7] Z.L. Zhang, Q. Kuang and X.S. Jia: Ecology and Environmental Sciences Vol. 19 (2010), p.2973. (in Chinese).

Google Scholar

[8] K. Wilson, H. Yang, C.W. Seo and W.E. Marshall: Bioresource Technology Vol. 97 (2006), p.2266.

Google Scholar

[9] E.I. El-Shafey: Journal of Environmental Management Vol. 84 (2007), p.620.

Google Scholar

[10] W. Lochananon and D. Chatsiriwech: Journal of Industrial and Engineering Chemistry Vol. 14 (2008), p.84.

Google Scholar

[11] M. Koroki, S. Saito, H. Hashimoto, Yamada and M. Aoyama: Environmental Chemistry Letters Vol. 8 (2010), p.59.

Google Scholar

[12] B. Royer, N.F. Cardoso, E.C. Lima, J.C.P. Vaghetti, N.M. Simon, T. Calvete and R.C. Veses: Journal of Hazardous Materials Vol. 164 (2009), p.1213.

DOI: 10.1016/j.jhazmat.2008.09.028

Google Scholar

[13] C.K. Singh, J.N. Sahu, K.K. Mahalik, C.R. Mohanty, B.R. Mohan and B.C. Meikap: Journal of Hazardous Materials Vol. 153 (2008), p.221.

Google Scholar

[14] D.Y. Kim, Y. Nishiyama, M. Wada and S. Kuga: Cellulose Vol. 8 (2001), p.29.

Google Scholar

[15] S.N. Hong, M.H. Liu, J. Fan and H.Y. Zhan : Paper Science & Technology Vol. 23 (2004), p.38. (in Chinese).

Google Scholar

[16] Y.S. Ho and G. McKay: Water Research Vol. 34 (2000), p.735.

Google Scholar

[17] C. Chen and J.L. Wang: Journal of Tsinghua University, Vol. 46(2006), (2069).

Google Scholar

[18] E.A. Deliyanni, L. Nalbandian and K.A. Matis: Colloid Interface Sci. Vol. 302 (2006), p.458.

Google Scholar

[19] R. Djeribi and O. Hamdaoui: Desalination, Vol. 225 (2008), p.85.

Google Scholar

[20] S. Azizina: Journal of Colloid and Interface Science, Vol. 276 (2004), p.4.

Google Scholar

[21] H. Gao, Y.G. Liu, G.M. Zeng, W.H. Xu, T. Li and W.B. Xia: Journal of Hazardous Materials, Vol. 150 (2008), p.446.

Google Scholar

[22] K.R. Hall, L.C. Eagleton, A. Acrivos and T. Vermeulen: Chemistry Fundamentals Vol. 5 (1966), p.212.

Google Scholar